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http://dx.doi.org/10.5012/bkcs.2012.33.9.2917

Hydrothermal Synthesis, Crystal Structure of Four Novel Complexes Based on Thiabendazole Ligand  

Wei, Shui-Qiang (College of Chemistry and Chemical Engineering, Guangxi University)
Lin, Cui-Wu (College of Chemistry and Chemical Engineering, Guangxi University)
Yin, Xian-Hong (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Huang, Yue-Jiao (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Luo, Pei-Qi (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.9, 2012 , pp. 2917-2924 More about this Journal
Abstract
Four novel metal-organic complexes $[Cd_2(IP)_2(TBZ)_2(H_2O)_2]{\cdot}(H_2O)$ (1), $[Zn_4(IP)_4(TBZ)_4]{\cdot}2(H_2O)$ (2), $[Zn_2(BTC)(TBZ)_2(CO_2H)]$ (3), [Co(PDC)(TBZ)] (4) (where IP = isophthalate; TBZ = thiabendazole; BTC = 1,3,5-benzenetricarboxylate; PDC = pyridine-3,4-dicarboxylate) have been prepared and characterized by IR spectrum, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. X-ray structure analysis reveals that 1, 2, and 3 are one-dimensional chain polymers, while 4 is a two-dimensional network polymer. The TBZ acts as a typical chelating ligand coordinated to the metal center in all complexes. The 1D chain architecture of 1 is constructed from isophthalates and cadmium atoms. A simultaneous presence of chelating, monodentate and bidentate coordination modes of IP ligands is observed in complex 2. In complex 3, the 16-membered rings are alternately arranged forming an infinite 1D double-chain structure. The 2D skeleton of 4 is formed by cobalt ions as nodes and PDC dianions as spacers, through coordination bonds. The hydrogen bonds and ${\pi}-{\pi}$ stacking play important roles in affecting the final structure where complexes 1 and 3 have 2D supramolecular networks, while complexes 2 and 4 have 3D supramolecular architectures.
Keywords
Thiabendazole; Carboxylate group; Single-crystal structure;
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1 Pachfule, P.; Dey, C.; Panda, T. Cryst. Growth Des. 2010, 10, 1351-1361.   DOI
2 Pruchnik, F. P.; Dawid, U.; Kochel, A. Polyhedron 2006, 25, 3647-3652.   DOI
3 Ye, B.-H.; Tong, M.-L.; Chen, X.-M. Coordin. Chem. Rew. 2005, 249, 545-565.   DOI
4 Xu, Y.-Q.; Zhou, Y.-F.; Yuan, D.-Q.; Hong, M.-C. Chinese J. Struct. Chem. 2006, 25, 1161-1166.
5 Devereux, M.; McCann, M.; Shea, D. O.; Kelly, R.; Egan, D.; Deegan, C.; McKee, V. J. Inorg. Biochem. 2004, 98, 1023-1031.   DOI
6 James, D. M., Gilles, H. M., Eds.; John Wiley & Sons: 1996; p 206.
7 Kaniskan, N.; Ogretir, C. J. Mol. Struct. 2002, 584, 45-52.   DOI
8 Kumar, D. K.; Das, A.; Dastidar, P. Cryst. Growth Des. 2006, 6, 1903.   DOI
9 Lu, W. G.; Jiang, L.; Lu, T. B. Cryst. Growth Des. 2008, 8, 986.   DOI
10 Wang, J.-J.; Lv, M.; Sun, Y.-M.; Cui, Y.-C. Chinese J. Struct. Chem. 2009, 28, 434-438.
11 Wang, J.-J.; Cui, Y.-C.; Liu, L.-H.; Huang, Y.-J. Chinese J. Struct. Chem. 2010, 29, 240-244.
12 Sheldrick, G. M. SADABS. Program for Empirical Absorption Correction of Area Detector; University of Gottingen: Germany, 1996.
13 Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement; University of Gottingen: Germany, 1997.
14 Chen, J.; Ohba, M.; Kitagawa, S. Chem. Lett. 2006, 35, 526.   DOI
15 Li, Z.-X.; Zhao, J.-P.; Sanudo, E. C. Inorg. Chem. 2009, 48, 11601-11607.   DOI
16 Hawxwell, S. M.; Brammer, L. CrystEngComm. 2006, 8, 473.   DOI
17 Burrows, A. D.; Cassar, K.; Friend, R. M. W. CrystEngComm. 2005, 7, 548.   DOI
18 Chen, W.; Wang, J. Y.; Chen, C. Inorg. Chem. 2003, 42, 944.   DOI   ScienceOn
19 Zheng, S. R.; Yang, Q. Y.; Yang, R.; Pan, M.; Cao, R.; Su, C. Y. Cryst. Growth Des. 2009, 9, 2341.   DOI
20 Lin, H. S.; Maggard, P. A. Inorg. Chem. 2007, 46, 1283.   DOI
21 Chapman, M. E.; Ayyappan, P.; Foxman, B. M.; Yee, G. T.; Lin, W. B. Cryst. Growth Des. 2001, 1, 159.   DOI
22 Steel, P. J. Acc. Chem. Res. 2005, 38, 243-250.   DOI
23 Zhang, J.; Lin, W. B.; Chen, Z. F.; Xiong, R. G.; Abrahams, B. F.; Fun, H. K. J. Chem. Soc., Dalton Trans. 2001, 1806.
24 Lin, W. B.; Ma, L.; Evans, O. R. Chem. Commun. 2000, 2263.
25 Ye, B. H.; Tong, M. L.; Chen, X. M. Coord. Chem. Rev. 2005, 249, 545.   DOI
26 Go, Y. B.; Wang, X.; Anokhina, E. V.; Jacobson, A. J. Inorg. Chem. 2005, 44, 8265-8271.   DOI
27 Ye, B.-H.; Williams, I. D.; Li, X.-Y. Inorg. Biochemistry 2002, 128-136.