• Title/Summary/Keyword: PB

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Effect of Annealing on c-axis Orientation of $PbTiO_3$ Thin Films by D.C magnetron Reactive Sputtering (D.C Magnetron Reactive Sputtering 법으로 증착한 $PbTiO_3$ 박막의 열처리에 따른 c-축 배향성의 변화)

  • 이승현;권순용;최한메;최시경
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.802-808
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    • 1996
  • PbTiO3 thin films were fabricated onto MgO(100) single crystal substrate by reactive D. C magnetron sput-tering of Pb and Ti metal in an oxygen and argon gas mixture. The annealing of the thin films resulted in the decrease of both the c-axis orientation ratio and the lattice parameter. It is well known that the c-axis lattice parameter of thin film is dependent on the Pb/(Pb+Ti)ratio and the residual stress in the film The PbTiO3 thin films with a Pb/(Pb+T) ratio ranging from 0.45 to 0.57 were fabricated and annealed. The structure of the film the c-axis orientation ratio and the lattice parameter were not dependent on the Pb/(Pb+Ti) ratio before and after annealing. These experimental results proved that the decrease of the c-axis lattice parameter under the annealing conditions was due to the relaxation of the intrinsic stress in the film. This relaxation of the intrinsic stress caused the decrease of the c-axis orientation ratio and this phenomenon can be explained by c-axis growth lattice model.

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Dielectric and Piezoelectric Characteristics of Ceramics in the $Pb(Mg_{1/2}W_{1/2})O_3-Pb(Ni_{1/3}Nb_{2/3})O_3-PbTiO_3-PbZrO_3$ system ($Pb(Mg_{1/2}W_{1/2})O_3-Pb(Ni_{1/3}Nb_{2/3})O_3-PbTiO_3-PbZrO_3$계 세라믹스의 유전 및 압전 특성)

  • Kim, Woo-Hyun;Yoon, Kwang-Hee;Yoon, Hyun-Sang;Park, Yong-Wook;Park, Chang-Yeop
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.193-195
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    • 1994
  • In this study, the structural, dielectric and piezoelectrical properties of $xPb(Mg_{1/2}W_{1/2})O_3-(1-x)[0.41Pb(Ni_{1/3}Nb_{2/3})O_3-0.36PbTiO_3-0.23P Zr)_3]$ (x=0, 0.01, 0.02, 0.03, 0.04, 0.05) system ceramics were investigated. The dielectric constant ${\varepsilon_{33}}^{\tau}$ at loon temperature increased up to 3mol% PMW and decreased with further PMW content. The specimen with 1mol% $Pb(Mg_{1/2}W_{1/2})O_3$, which has the ${\varepsilon_{33}}^{\tau}=5509$, kp=59[%] and $d_{33}=758{\times}10^{-12}[C/N]$, exhibits good characteristics.

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Improvement of the shieldability and lightweight of a radiation protective apron (방사선 방호용 에이프런의 경량화와 차폐능 개선)

  • Kim, Young-Keun;Jang, Young-Ill;Kim, Jung-Min
    • Journal of radiological science and technology
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    • v.26 no.1
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    • pp.45-50
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    • 2003
  • In this work, we characterized the shieldability and lightweight of radiation protective aprons which were consisted of various metal(Pb, Sn, Ni, Ti and Cu) by measuring the x-ray dose transmitted through the filters. The transmitted ratio and lead equivalent of various metal were obtained by linear interpolation and the lead equivalent of double layered filters contained Pb layer was determined. The transmitted ratio of the apron(0.25 mmPb) specified in KS B 0845 was 5.2%. The transmitted ratio of the filters at the thickness of 0.6 mm was decreased in the other of Ni(32.60%), Ti(17.75%), Cu(13.25%) and Sn(3.84%). From the results of experimental evaluation for combined filter of Pb and Sn, it was founded that in the case of the first Sn layer, the lead equivalent was higher than that of the first Pb layer. The lead equivalent corresponding to apron of 0.25 mmPb was obtained in the double layered filters of Sn(0.19 mm) - Pb(0.1 mm) and Pb(0.1 mm) - Sn(0.37 mm). Thus, the Sn-Pb filter had the lower weight about 13% than apron of 0.25 mmPb.

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Correlation among PM10, PM2.5, Cd, and Pb Concentrations in Ambient Air and Asian Dust Storm Event (황사 발생과 대기 중 PM10, PM2.5, Cd, Pb 농도의 상관성)

  • Moon, Chan-Seok
    • Journal of Environmental Health Sciences
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    • v.46 no.5
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    • pp.532-538
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    • 2020
  • Objectives: The study evaluated correlations among monthly PM2.5, PM10, Cd, Pb concentrations and the number of Asian dust days. Methods: Based on data from 'The annual report on air quality in Korea from 1999 to 2017', concentrations of PM10, PM2.5, Cd, Pb, and the number of Asian dust days were recalculated to mean, standard deviation, minimum, and maximum. Correlation coefficients were calculated among PM2.5, PM10, Cd, Pb, and Asian dust days. Results: Asian dust days were correlated only with PM10 among the four factors of PM10, PM2.5, Cd, and Pb. The four factors of PM10, PM2.5, Cd, and Pb were very significantly correlated with each other (p<0.01). Their correlation coefficients for PM10 were 0.800 for PM2.5, 0.823 for Cd, and 0.892 for Pb. PM2.5 was also correlated strongly with Cd (0.845) and Pb (0.830). Cd had a correlation with Pb of 0.971. The maximums of PM2.5, PM10, and Pb were shown to exceed the atmospheric environmental standard of Korea, which necessitates national continuous exposure control. Based on exposure data, Asian dust days were thought to be an exposure factor for Cd and Pb. Conclusion: Asian dust might be a factor in Cd and Pb exposure. National exposure controls are required for exposure to PM2.5, PM10, Cd, and Pb.

Effects of Additives on the Properties of $YBa_2Cu_3O_x$

  • Soh, Dea-Wha;Cho, Yong-Joon;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.341-344
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    • 2004
  • The superconducting properties of $YBa_2Cu_3O_x$ with different content impurities of PbO and $BaPbO_3$ were studied. When the PbO was used as an additive in $YBa_2Cu_3O_x$, although the melting point could be reduced, the superconductivity became poor. From the XRD pattern of the sintered mixture of $YBa_2Cu_3O_x$ and PbO it was known that there is a reaction between $YBa_2Cu_3O_x$ and PbO, and the product is $BaPbO_3$. In the process of the reaction the superconducting phase of $YBa_2Cu_3O_x$ was decreased and $BaPbO_3$ would be the main phase in the sample. Therefore, $BaPbO_3$ was chosen as the impurity additive for the comparative study. The single phase of $BaPbO_3$ was synthesized by the simple way from both mixtures of $BaCO_3$ and PbO, $BaCO_3$ and $PbO_2$. Different contents of $BaPbO_3$ (10%, 20%, 30%) were added in the $YBa_2Cu_3O_x$. By the Phase analysis in the XRD patterns it was proved that there was no reaction between $YBa_2Cu_3O_x$ and $BaPbO_3$. When $BaPbO_3$ was used as impurity in $YBa_2Cu_3O_x$ the superconductivity was much better than PbO as an impurity additive in $YBa_2Cu_3O_x$.

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Electrical Properties of $Pb(Y_{1/2}Ta_{1/2})O_3-PbZrO_3-PbTiO_3$ Ceramic s as a function of $Fe_2O_3$content ($Fe_2O_3$ 첨가에 따른 $Pb(Y_{1/2}Ta_{1/2})O_3-PbZrO_3-PbTiO_3$ 세라믹스의 전기적 특성)

  • 강도원;김태열;김범진;박태곤;김명호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.297-299
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    • 1999
  • Effects of additives on the ceramic and electrical properties of Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$ceramics in a perovskite type structure were investigated. The dielectric and piezoelectric properties of the base composition were improved markedly through selection of Fe$_2$O$_3$ additives in proper amounts. The composition Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$ obtained the dielectric constant ($\varepsilon$$_{r}$=1,425). Also, electromechanical couping factors for planar(k$_{p}$) and piezoelectric constant(d$_{33}$) were obtained 0.50 and 294[pC/N] at the additives 0wt% Fe$_2$O$_3$ respectively. The mechanical quality facor(Q$_{m}$) of Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$+Fe$_2$O$_3$(0.3 wt%) is about 510.510.510.

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Recent Progress in Pb-free Solders and Soldering Technology: Fundamentals, Reliability Issues and Applications

  • Kang Sung Kwon
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2004.09a
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    • pp.1-26
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    • 2004
  • The implementation of Pb-free solder technology is making good progress in electronic industry. Further understanding on fundamental issues on Pb-free solders/processes is required to reduce reliability risk factors of Pb-free solder joints. Several reliability issues including thermal fatigue, impact reliability, IMC growth, spalling, void formation are reviewed for Pb-free solder joints. Several applications of Pb-free technology are discussed, such as Pb-free, CBGA, CuCGA, flip chips, and wafer bumping by IMS.

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An Analysis and Control of Pb Pollutions of Soils by Pollens (화분에 의한 납의 오염도 분석과 그 방제에 관한 연구)

  • 장남기;고영현;홍순철
    • Asian Journal of Turfgrass Science
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    • v.12 no.1
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    • pp.31-48
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    • 1998
  • In this paper, pollen types of plants and Pb, N, P, K, Ca and Na in pallens of trees were investigated to control the air and soil pollutions. Morphological types of about 500 species of plants were identified to make the best use of paleontology, medicine and pharmacy. There were the positive correlations between Pb, N, P, K,Ca and Na contents in pollens and soils, respectively. A heavy metal, Pb, contained in pollens was not absorbed by rats. This fact should be utilized to purify air and soils polluted by Pb. Key words: Pb, Pollen, Pollution, puripication, Control.

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Biosorption Characteristics of Pb and Cu by Ca-alginate Immobilized Algae Spirulina platensis (Ca-alginate에 고정한 Spirulina platensis의 납과 구리 흡착 특성)

  • Shin, Taek-Soo;Woo, Byoung-Sung;Lim, Byung-Seo;Kim, Kwang-Yul
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.446-452
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    • 2008
  • This study was conducted to research the biosorption characteristics using algae, Spirulina platensis, for the removal of Pb and Cu ions in wastewater. Both of free algal cell and immobilized algae by Ca-alginate were used as bioadsorbent, and experiment was proceed in batch reactor for Pb and Cu ions removal, respectively. In the biosorption of Pb and Cu ions by free Spirulina platensis cell, the adsorption equilibrium reached within 20 minute. The higher adsorbed amount of Pb and Cu was shown as increasing of initial concentration of Pb and Cu, and pH of solution, respectively, and the optimum pH was 4.5$\sim$5.0. Under the conditions of initial concentration of Pb or Cu are 200 mg/L, the maximum amounts of Pb and Cu adsorbed to the unit weight of Spirulina platensis were 86.43 and 57.02 mg/g, respectively, and these values were 1.94 and 1.48 times higher than those of activated carbon under same conditions, respectively. The biosorption kinetics of Pb and Cu ions by free Spirulina platensis cell fitted very well to the Freundlich and Langmuir isotherm. The maximum amount of Pb or Cu adsorbed to the unit mass of adsorbent by the Langmuir isotherm($q_{max}$) represented as 95.24 and 62.50 mg/g, respectively. The FT-IR results of free Spirulina platensis biomass showed that biomass has different functional groups and these functional groups are able to react with metal ions in aqueous solution. In the biosorption of Pb and Cu ions by Ca-alginate immobilized algae Spirulina platensis, the adsorption equilibrium reached within 40 min. and observed a little diffusion limitation differed from the free algal cell adsorption.

Manufacturing Characteristics of Boards Recycling Waste Wood Particle (폐목재파티클을 이용한 재생보드의 제조특성)

  • Kim, Wae-Jung;Suh, Jin-Suk;Han, Tae-Hyung;Park, Jong-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.120-127
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    • 2006
  • The hammer-milled characteristics of waste wood materials such as lumber, plywood, particleboard(PB), MDF and railroad tic were investigated in this study. The physical and mechanical properties of recycled boards according to types of recycled particle and the mixing ratios were also studied. The hammer-milled, waste wood materials had the dimensional distributions suitable for the core layer panicle. Bending strengths of recycled boards (one layer) were shown in order of plywood, PB(laboratory-fabricated with particles used in the PB factory), lumber, tego film-overlaid plywood, MDF, waste railroad tie, PB(factory-made) and LPL-overlaid PB. Cured resin and creosote containing waste wood contributed to dimensional stability of reconstituted boards. Considering the mixing effects between lumber and plywood with recycled PB particle, lumber particle was contributive to bending strength, MOE and internal bond(IB) strength, whereas plywood particle was contributive to dimensional stability. The bending and IB strength of 3 layer boards composing only recycled waste wood particles in core layer of board were in order of lumber, plywood, PB and MDF. On the other hand, the thickness swelling was in order of PB, lumber, plywood and MDF. Bending strength of the 3 layer boards mixed with recycled PB-particle in the core layer had a decreasing tendency, as the mixing ratios of recycled PB-particles increased. The dimensional stability of 3 layer recycled board was improved as the mixing ratio of recycled PB-particle increased same as in one layer. Formaldehyde emission of boards fabricated with recycled PB-particles in the core layer of the PB was in the range of E2 grade (below 5.0mg/l).

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