• 제목/요약/키워드: Ozone Stress

검색결과 61건 처리시간 0.022초

Trans-octylene rubber(TOR)의 첨가가 NBR/EPDM 고무블렌드의 물성에 미치는 영향 (Effect of trans-octylene rubber(TOR) on the properties of NBR/EPDM rubber blends)

  • 신영식;장영욱
    • Elastomers and Composites
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    • 제35권2호
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    • pp.149-156
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    • 2000
  • trans-octylene rubber(TOR)를 비상용성 블렌드인 NBR/EPDM(70/30)에 첨가하고, 이에 따른 혼합 특성 모폴로지 및 물성의 변화에 관하여 조사하였다. TOR이 첨가됨으로써 블렌드 시 혼합에너지가 감소하였고, 혼합 시 수반되는 온도상승도 저하됨을 볼 수 있었다. 블렌드의 모폴로지를 SEM으로 관찰한 결과, EPDM이 NBR 매트릭스에 분산된 형태인 것을 알았으며, TOR의 첨가에 의해 분산상인 EPDM상이 균일하고 미세해지는 것이 관찰되었다. TOR이 첨가됨으로써 NBR/EPDM의 인장강도, 파단신율 및 모듈러스 둥의 인장물성이 향상되었다. 오존저항성은 임계 응력-변형관계로부터 정량적으로 평가하였으며, TOR이 첨가된 블렌드에서 오존크랙을 일으키는 임계에너지값이 증가됨을 알 수 있었다. TOR의 첨가로 인한 NBR/EPDM 블렌드의 물성 향상은 모폴로지의 미세화와 사슬얽힘으로 인한 가교밀도의 변화 때문인 것으로 판단된다.

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순차 스퍼터법으로 제작한 BiSrCaCuO 박막의 부착 특성 (Sticking Characteristics in BiSrCaCuO Thin Film Fabricated by Layer-by-Layer Sputtering Method)

  • 천민우;박용필;김정호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 제5회 학술대회 논문집 일렉트렛트 및 응용기술연구회
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    • pp.45-48
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    • 2003
  • BiSrCaCuO thin films were fabricated by atomic layer-by-layer deposition using an ion beam sputtering method. 10 wt% and 90 wt% ozone mixed with oxygen were used with ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition, two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit, then three dimensional growth takes place. Since Cu element is the most difficult to oxidize, only Sr and Bi react with each other predominantly, and forms a buffer layer on the substrate in an amorphous-like structure, which is changed to $SrBi_2O_4$ by in-situ anneal.

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초전도 박막의 에피택셜 성장에 관한 연구 (A Study on the Epitaxial Growth of Superconducting Thin Film)

  • 이희갑;박용필;김귀열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
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    • pp.208-211
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    • 2002
  • $Bi_2Sr_2CuO_x$(Bi-2201) thin films were fabricated by atomic layer-by-layer deposition using an ion beam sputtering method. 10 wt% and 90 wt% ozone mixed with oxygen were used with ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition, two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit, then three dimensional growth takes place. Since Cu element is the most difficult to oxidize, only Sr and Bi react with each other predominantly, and forms a buffer layer on the substrate in an amorphous-like structure, which is changed to $SrBi_2O_4$ by in-situ anneal.

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순차 스퍼터 법에 의한 BSCCO 박막의 특성 (Characteristics of BSCCO Thin Film by Layer-by-layer Deposition)

  • 이희갑;박용필;김귀열;오금곤;최운식;조춘남
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.281-283
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    • 2001
  • $Bi_{2}Sr_{2}CuO_{x}$(Bi-2201) thin films were fabricated by atomic layer-by-layer deposition using an ion bearn sputtering method. 10 wt% and 90 wt% ozone mixed with oxygen were used with ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition. two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit. then three dimensional growth takes place. Since Cu element is the most difficult to oxidize. only Sr and Bi react with each other predominantly. and forms a buffer layer on the substrate in an amorphous-like structure. which is changed to $SrBi_{2}O_{4}$ by in-situ anneal.

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교량용 탄성받침의 설계압축응력에 대한 고찰 (The Design Criteria of Elastomeric Bearing for Highway Bridges)

  • 전규식
    • 한국지진공학회:학술대회논문집
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    • 한국지진공학회 1998년도 추계 학술발표회 논문집 Proceedings of EESK Conference-Spring 1998
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    • pp.136-143
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    • 1998
  • Elastomeric bearing is used as one of the most useful way for isolation structures, because the horizontal stiffness is much lower than the vertical stiffness. The quality of Elastomeric bearing depends on the vulcanization procedure to manufacture, which produces the elasticity of the rubber from the compound of rubber and sulphur. The durability of Elastomeric bearing is affected by the deterioration due to ozone and ultra-violet attack. but the durability during the design life of bridges can be assured by the sufficient size of the bearing in spite of the deterioration in surface. In the design criteria of Elastomeric bearing, the stability of the bearings is evaluated by shear strain due to compression, lateral displacement, and rotation. The question how soft rubber can sustain heavy structure is now able to be solved by Ultimate capacity test of Laminated elastomeric Bearings, which results 1,200kg/$\textrm{cm}^2$ of the max. compressive stress and this shows what a sufficient safety factor Elastomeric bearing has!

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카본블랙의 충전량에 따른 NR/HNBR블렌드의 물성과 가교밀도에 관한 연구 (Properties and Crosslink Density of the NR/HNBR Blends Influenced by Carbon Black Loading)

  • 홍석표;최상구;유길상;이범철
    • Elastomers and Composites
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    • 제27권3호
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    • pp.183-193
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    • 1992
  • Compared with NR and HNBR compounds, the blend properties of NR/HNBR were studied. The heat, oil and ozone resistance of NR compounds were improved by blending HNBR, and these effects were more clearly revealed with elevating temperatures. For the overall stabilities of the compounds, it was resonable to use the carbon black under the 60phr. In the EV systems, high-saturated NR/HNBR and HNBR compounds showed similar total crosslink density in comparison with NR compounds. Interaction parameters calculated by stress-strain method showed widely varied value.

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순차 스퍼터 법에 의한 BSCCO 박막의 특성 (Characteristics of BSCCO Thin Film by Layer-by-layer Deposition)

  • 이희갑;박용필;김귀열;오금곤;최운식;조춘남
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.281-283
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    • 2001
  • Bi$_2$Sr$_2$CuO$\_$x/(Bi-2201) thin films were fabricated layer-by-layer deposition using an ion beam sputtering method. 10 wt% and 90 wt% ozone mixed with oxygen were used ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition, two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit, then three dimensional growth takes place. Since Cu element is the most difficult to oxidize, only Sr and Bi react with each other predominantly, and forms a buffer layer on the substrate in an amorphous-like structure, which is changed to SrBi$_2$O$_4$ by in-situ anneal.

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초저속 순차증착으로 제작한 Bi2212 박막의 특성 (Characteristics of Bi2212 Thin Film Fabricated by Layer-by-Layer Deposition at an Ultra Low Growth rate)

  • 이희갑;박용필;천민우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.119-121
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    • 2002
  • $Bi_2Sr_2CuO_x$ thin films were fabricated by atomic layer-by-layer deposition using an ion beam sputtering method, 10 wt% and 90 wt% ozone mixed with oxygen were used with ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition, two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit, then three dimensional growth takes place. Since Cu element is the most difficult to oxidize, only Sr and Bi react with each other predominantly, and forms a buffer layer on the substrate in an amorphous-like structure, which is changed to $SrBi_2O_4$ by in-situ anneal.

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Radiation Biology in Space; DNA Damage and Biological Effects of Space Radiation

  • Ohnishi, Takeo;Takahashi, Akihisa;Ohnishi, Ken
    • Journal of Photoscience
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    • 제9권3호
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    • pp.37-40
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    • 2002
  • Astronauts are constantly exposed to space radiation at a low-dose rate during long-tenn stays in space. Therefore, it is important to determine correctly the biological effects of space radiation on human health. Space radiations contain various kinds of different energy particles, especially high linear energy transfer (LET) particles. Therefore, we have to study the relative biological effectiveness (RBE) of space radiation under microgravity environment which may change RBE from a stress for cells. Furthermore, the research about space radiation might give us useful information about birth and evolution of life on the earth. We also can realize the importance of preventing the ozone layer from depletion by use of exposure equipment to sunlight at International Space Station (ISS).

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Response of Antioxidative Enzymes of Two Rice Cultivars to Ozone Exposure and Nutrient Supply

  • Lee, Sang-Chul;Hwan, Cho-Jeong;Park, Shin-Young;Son, Tae-Kwon
    • 한국작물학회지
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    • 제46권1호
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    • pp.40-46
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    • 2001
  • Ozone ($O_3$)-induced changes in chlorophyll content and specific activities of antioxidant enzymes, such as superoxide dismutase (SOD), ascorbate peroxidase (APX), guaiacol peroxidase (GPX), dehydroascorbate reductase (DHAR) and glutathione reductase (GR) were investigated in two rice cultivars (Oryza sativa L.) grown under variable nutrient treatments. For this study, two rice cultivars of Ilpumbyeo (IL) and Keumobyeo#l (KM), which were known as resistant and susceptible to $O_3$, respectively, were exposed to $O_3$at 0.15ppm for 30 days and investigated with 10 days interval. The available nutrient regimes were varied by doubling the supply of nitrogen (N), phosphorus (P) and potassium (K) Within a basic fertilizer status (N, P, K; 15, 12, 12kg/l0a$^{-1}$ ). In both cultivars and at all nutrient status, chlorophyll content in $O_3$-treated plants decreased with prolonged treatment period, although higher N, P and K supply with $O_3$ treatment alleviated the decrease in chlorophyll content. The activities of almost all enzymes investigated for this study were decreased during initial stages of $O_3$- exposure except GPX which maintained higher activity throughout the exposure period than the non-treated plant. However, the antioxidant enzymes in $O_3$-treated plants showed almost the same or higher activities on 30 days after $O_3$ - exposure. The most significant changes in activities were observed in GR of the $O_3$-treated leaves. With the prolonged treatment period, the activity of GR at 30 days was increased by 3-8 times compared to those in 10 days. Most of the investigated enzymes showed very similar tendency to $O_3$ treatment in all fertilizer status. There was no observed evidence for enhanced detoxification of $O_3$-derived activated oxygen species in plants grown under higher fertilizer status compared with that in plants grown under basic fertilizer status. The increase in the activities of SOD, APX and GR in rice leaves by relatively long-term treatment with $O_3$ at low concentration is considered to indicate that the plant became adapted to the $O_3$ stress and the protection system increased its capacity to scavenge toxic oxygen species. Our results in two rice cultivars indicated that there was little difference in the activities of antioxidant enzymes between IL and KM, which were known as resistant and susceptible cultivar to $O_3$

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