• Title/Summary/Keyword: Oxygen atmosphere

Search Result 670, Processing Time 0.025 seconds

Analysis of Crystallinity and Electrical Characteristics of Oxide Semiconductor of ZnO in Accordance with Annealing Methods (ZnO의 열처리방법에 따른 전기적인 특성의 변화와 결정성)

  • Oh, Teresa
    • Korean Journal of Materials Research
    • /
    • v.27 no.5
    • /
    • pp.242-247
    • /
    • 2017
  • ZnO film was prepared on a p-type Si wafer and then annealed at various temperatures in air and vacuum conditions to research the electrical properties and bonding structures during the annealing processes. ZnO film annealed in atmosphere formed a crystal structure owing to the suppression of oxygen vacancies: however, ZnO annealed in vacuum had an amorphous structure after annealing because of the increment of the content of oxygen vacancies. Schottky contact was observed for the ZnO annealed in an air. O 1s spectra with amorphous structure was found to have a value of 529 eV; that with a crystal structure was found to have a value of 531.5 eV. However, it was observed in these results that the correlation between the electronic characteristics and the bonding structures was weak.

Surface Modification of Polypropylene Meltblown(PPMB) Nonwovens by Plasma Treatment (초극세형 폴리프로필렌부직포의 플라즈마를 이용한 표면개질)

  • Lee, Youn-Eung;Joo, Chang-Whan
    • Textile Coloration and Finishing
    • /
    • v.18 no.1
    • /
    • pp.20-27
    • /
    • 2006
  • On the purpose of surface modifications of polypropylene meltblown(PPMB) nonwovens, PPMB nonwovens were treated in the plasma system by oxygen atmosphere with different treatment time and discharge power. Dimensional change and physical properties of the treated nonwovens were evaluated. Contact angles onto PPMB nonwovens about water and methyleneiodide were measured and surface energies were calculated by Owen's method. As the results, microcraters were observed on the surface of treated nonwovens. Tenacity and breaking strain of PPMB nonwovens decreased with increasing treatment time and discharge power. Surface energy of PPMB nonwovens increased by plasma treatment. Meanwhile, the friction static voltage and dyeability of PPMB nonwovens have enhanced to some extent by oxygen plasma treatment due to the improvement of surface hydrophilicity.

Studies on the Recycling Technology of the Waste Paper with Wood Degradable Enzyme(I) - Separation of Crude Enzyme from Wood Degradable fungi - (목질분해효소에 의한 고지의 재활용 기술연구 (제1보) -목질분해균으로부터 조효소의 단리)

  • 양재경;이중명;엄태진
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.29 no.1
    • /
    • pp.43-51
    • /
    • 1997
  • The various culture conditions of Trichoderma viride(ATCC 3454) and Phanerochaete chrysosporium(ATCC 26921) with glucose-pepton medium, Mandels medium, YMG medium for wood degradable enzyme were examined. Mycellium of the two species grew profusely on glucose-pepton medium. Maximum fungal growth was observed about 10days. But CMCase, Fpase, laccase activity in the culture medium with glucose-pepton was not detected. When grown in fermenter culture using Mandels medium, Trichoderma viride produced CMCase and Fpase. Its CMCase activity was 0.15 lU/ml and Fpase activity was 0.3 IU/ml within about 4-6days. Phanerochaete chrysosporium grown in a YMG medium gave the best enzyme activity when they were grown under stationary culture with an atmosphere of 100% oxygen. Levels of laccase activity of 3.0 mull were achieved in stationary culture under 100% oxygen. The enzyme condensation by ultrafiltration method caused a 2-fold(cellulase) and 6-fold(laccase) as compared to control activity.

  • PDF

Permeabilities of Korean Earthenware Containers and Their Potential for Packaging Fresh Produce

  • Seo, Gyeong-Hee;Chung, Sun-Kyung;An, Duck-Soon;Lee, Dong-Sun
    • Food Science and Biotechnology
    • /
    • v.14 no.1
    • /
    • pp.82-88
    • /
    • 2005
  • Ethnic Korean onggi earthenwares were fabricated using different clay formulations and glazing treatments. Their permeability properties against oxygen, carbon dioxide, and moisture were measured at $20^{\circ}C$ and examined from the aspect of food preservation. Onggi walls consisted of micropores that offered higher gas and moisture permeation rates when compared with other food packaging materials. Earthenware walls were unique in having $CO_2/O_2$ permeability ratios of 0.60-1.00. Gas and moisture permeabilities were lower, with wall structure having lower porosity and surface glazing. Results revealed onggi jar packages of grape fruits could attain wide range of $O_2$ and $CO_2$ concentrations. Onggi containers present good opportunity to obtain optimum packaging conditions for respiring or ripening products, depending on commodity type.

Study of Laser Ablated Y-Ba-Cu-O Thin Films on $LaAlO_3$(100)Substrates (Laser Ablation에 의하여 $LaAlO_3$(100) 기판 위에 증착된 Y-Ba-Cu-O 박막에 대한 연구)

  • 조윌렴;이규철;고도경;이헌주;노태원;김정구;허필화
    • Journal of the Korean Ceramic Society
    • /
    • v.28 no.12
    • /
    • pp.1005-1011
    • /
    • 1991
  • Y-Ba-Cu-O thin films were in-situ fabricated on LaAlO3(100) substrates using the second harmonics of a pulsed Nd:YAG laser. Thin films were deposited under 200 (mtorr) of oxygen atmosphere, when the substrate temperature was changed between 67$0^{\circ}C$ and 82$0^{\circ}C$. After deposition, the films were in-situ annealed at 50$0^{\circ}C$ under 2/3 bar of oxygen pressure. We showed that the deposition temperature affects the formation of superconducting phase, the resistance, and the surface morphology. The Y-Ba-Cu-O thin films deposited at 76$0^{\circ}C$ show the zero resistance critical temperature of 85 K.

  • PDF

High Tc Superconductor, YBa2 Cu3 O7-$\delta$; (I) Its Preparation and Physicochemical Characterization (고온 초전도체 YBa2 Cu3 O7-$\delta$;(1) 합성 및 물리화학적 특성 연구)

  • 최진호;변송호;홍승태;정덕영;최석용;김배환;김진태;노동윤;유한일
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.2
    • /
    • pp.154-160
    • /
    • 1988
  • Almost single phase of Y1Ba2Cu3Ox, which exhibits the onset of superconducting transition at 90K, has been prepared via a conventional ceramic processing route followed by an anneal for a period of 10 hours at 45$0^{\circ}C$ in an atmosphere of 100% O2. The mean value for the oxygen content has been determined as x=6.85$\pm$0.02 by an iodometric titration technique. X-ray photoemission spectra are found to be consistent with a mixture of the d8(Cu3+) and d9(Cu2+) as the ground state and reveals that the local concentration of Cu3+ decreases with depth from the surface where x corresponds to 7.0. This is explained as being associated with the intercalation of oxygen during cooling from the annealing temperature.

  • PDF

The Study of Degradation Mechanism as ZnO Varistor with The Ambient Sintering-Process (분위기 소결공정에 의한 ZnO 바리스터의 열화기구 연구)

  • 소순진;김영진;최운식;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.11a
    • /
    • pp.117-120
    • /
    • 1999
  • The relationship between the DC degradation characteristics of the ZnO varistor and the ambient sintering-process is investigated in this study. ZnO varistors made of Matsuoka's composition were fabricated by standard ceramic techniques. The ambient sintering-process is performed at the extraordinary electrical-furnace which is equipped with the vacuum system. The Gas of sintering process was oxygen, nitrogen, argon, air respectively. The microstructure of ZnO varistors be made use of SEM equipment. The condition of DC degradation tests were conducted at $115\pm2^{\circ}C$ for periods up to 13 h. Current-voltage analysis is used to determine nonlinear coefficients($\alpha$). Resistance-frequency and capacitance-frequency analysis are accomplished to the understanding of electrical properties as DC degradation test. From above analysis, it is found that the ZnO varistor sintered in oxygen atmosphere showed superior properties at the DC degradation test.

  • PDF

Resistivity Variation of Nickel Oxide by Substrate Heating in RF Sputter for Microbolometer

  • Lee, Yong Soo
    • Journal of Sensor Science and Technology
    • /
    • v.24 no.5
    • /
    • pp.348-352
    • /
    • 2015
  • Thin nickel oxide films formed on uncooled and cooled $SiO_2/Si$ substrates using a radio frequency (RF) magnetron sputter powered by 200 W in a mixed atmosphere of argon and oxygen. Grazing-incidence X-ray diffraction and field emission scanning electron microscopy are used for the structural analysis of nickel oxide films. The electrical conductivity required for better bolometric performance is estimated by means of a four-point probe system. Columnar and (200) preferred orientations are discovered in both films regardless of substrate cooling. Electric resistivity, however, is greatly influenced by the substrate cooling. Oxygen partial pressure increase during the nickel oxide deposition leads to a rapid decrease in resistivity, and the resistivity is higher in the cooled nickel oxide samples. Even when small microstructure variations are applied, lower resistivity in favor of low noise performance is acquired in the uncooled samples.

Ionic Conductivity of Solid Solution Ceramics in The System of Stabilized ZrO2 Prepared by Self-Propagating High-Temperature Synthesis

  • Soh, Deawha;Korobova, N.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.4
    • /
    • pp.349-355
    • /
    • 2002
  • The ionic conductivity of cubic solid solutions in the systems of CaO-$ZrO_2$, $Y_2O_3-ZrO_2$ prepared by SHS was examined. The higher conductivity appears to be related to a lower activation energy rather than to the number of oxygen vacancies dictated by composition. Conductivity-temperature data was obtained at 1000 $^{\circ}C$ in atmosphere of low oxygen partial pressure (~$10^{-40}$ atm) for $Y_2O_3-ZrO_2$ cubic solid solutions. The data indicated that these materials could be reduced, and the decree of reduction would be related with the measuring electric field.

High Temperature Oxidation of Ti-15Mo-5Zr-3Al Alloy (Ti-15Mo-5Zr-3Al 합금의 고온산화)

  • 우지호;김종성;백종현;이동복
    • Journal of Surface Science and Engineering
    • /
    • v.31 no.5
    • /
    • pp.278-285
    • /
    • 1998
  • Alloys of Ti-15Mo-5Zr-3Al(wt%) were oxidized in air between 700 and $900^{\circ}C$. It was found that the oxidation resistance is much better than that of either commercially available pure Ti-6Al-4V(wt%) alloys. The oxide scales were primarily composed of thick Ti-ox-ides which were formed by the inward diffusion of oxygen from the atmosphere. At higher temperatures a thin $\alpha$-$Al_2O_3$ layer was formed on Ti-oxides owing to the outward diffusion of Al from the base alloys. Molybdenum, the noblest metal among the alloy components, was predominantly present behind the oxide-substrate interface. Zirconium, an oxygen active metal, was present at both the oxide layer and the substrate.

  • PDF