• Title/Summary/Keyword: Oxygen Separation

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Separation and Purification of Antioxidant Peptide from Fermented Whey Protein by Lactobacillus rhamnosus B2-1

  • Hao Guo;Lei Fan;Lin Ding;Wenqin Yang;Chuangang Zang;Hong Guan
    • Food Science of Animal Resources
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    • v.43 no.1
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    • pp.10-24
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    • 2023
  • In this study, a antioxidant activity peptide fraction was separated and purified from metabolites of whey protein fermented by Lactobacillus rhamnosus B2-1. The fermentation sample was separated by macroporous resin D101 and Sephadex G-15. The collected fractions were tested for antioxidant and antitumor activities. In order to test the antioxidant activity of fractions, Hydroxyl (·OH), 2,2'-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid (ABTS), and Oxygen Radical Absorbance Capacity (ORAC) were used. The final purified peptide B11 showed highest ABTS and ·OH radical scavenging rate by 84.36±1.89% and 62.43±2.64%, respectively, and had an ORAC activity of 1,726.44±2.76 μM Trolox equivalent/g. Further, the inhibitory effect of B11 on the proliferation of LoVo human colon cancer cells, KB and Cal-27 human oral cancer cells were enhanced with increasing concentrations of B11. B11 contains 51.421% amino acids, with Glu and Asp being the major constituents. In this study, we obtained peptide fraction B11 with antioxidant activity, which is promising for development.

Performance Evaluation of an Oxy-coal-fired Power Generation System - Thermodynamic Evaluation of Power Cycle (순산소 석탄 연소 발전 시스템의 성능 평가 - 동력 사이클의 열역학적 해석)

  • Lee, Kwang-Jin;Choi, Sang-Min;Kim, Tae-Hyung;Seo, Sang-Il
    • Journal of the Korean Society of Combustion
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    • v.15 no.2
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    • pp.1-11
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    • 2010
  • Power generation systems based on the oxy-coal combustion with carbon dioxide capture and storage (CCS) capability are being proposed and discussed lately. Although a large number of lab scale studies for oxy-coal power plant have been made, studies of pilot scale or commercial scale power plant are not enough. Only a few demonstration projects for oxy-coal power plant are publicized recently. The proposed systems are evolving and various alternatives are to be comparatively evaluated. This paper presents a proposed approach for performance evaluation of a commercial 100 MWe class power plant, which is currently being considered for 'retrofitting' for the demonstration of the concept. The system is configurated based on design and operating conditions with proper assumptions. System components to be included in the discussion are listed. Evaluation criteria in terms of performance are summarized based on the system heat and mass balance and simple performance parameters, such as the fuel to power efficiency and brief introduction of the second law analysis. Also, gas composition is identified for additional analysis to impurities in the system including the purity of oxygen and unwanted gaseous components of nitrogen, argon and oxygen in air separation unit and $CO_2$ processing unit.

Effect of volatile matter and oxygen concentration on tar and soot yield depending on low calorific coal in Laminar Flow Reactor (저열량탄의 휘발분과 산소농도가 Tar와 Soot의 발생률에 미치는 영향)

  • Jeong, Tae Yong;Kim, Jin Ho;Lee, Byoung Hwa;Song, Ju Hun;Jeon, Chung-Hwan
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.209-212
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    • 2012
  • This study was performed to analyze coal flames and measure tar and soot yields and structures of chars for two coals depending on the volatile content by the LFR(Laminar Flow Reactor) which can be applied to a variety of coal researches. The results show that volatile contents and oxygen concentration have significant influence on length and width of the soot cloud and it also indicate that the length and width of the cloud in condition of combustion decrease than those of pyrolysis atmosphere. Until the sampling height reach at 50 mm, the tar and soot yields of Berau (Sub-bituminous) coal contained relatively lots of volatile matters are less than those of Glencore A.P. (Bituminous) coal. On the other hand, tar and soot yields of Berau coal are higher than those of Glencore A.P. coal by reacted residual volatile matter. In addition, the images of samples obtained from the particle separation system of the sampling probe support for above results with the yields, and the pore development of char surface by devolatilization.

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A Study on the Development of Noninvasive Tissue-Reflectance Oximeter (Noninvasive Tissue-Reflectance Oximeter의 개발에 관한 연구)

  • Chang, S.Y.;Kim, N.J.;Koo, C.H.;Lee, J.K.;Lim, H.S.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.11
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    • pp.420-423
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    • 1997
  • The oxygen saturation of blood can be measured by sensing the difference absorption in optical spectra of Hb and $HbO_2$, as the well known previous study. [1] In this study we developed the noninvasive tissue reflectance oximeter(TRO) using three kinds of LEDs which produce a peak spectral emission at a wavelength of 565, 660 and 940nm. And we tested the unction of the TR oximeter by comparing the output signals measured on normal tissue to measured on low oxygenated tissue. The results showed that oxygen saturation of blood and biological tissue can be monitored from the separation arrangement light source and detector.

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Effect of Carbon Capture Using Pre-combustion Technology on the Performance of Gas Turbine Combined Cycle (연소전 처리를 이용한 탄소포집이 가스터빈 복합화력 플랜트의 성능에 미치는 영향)

  • YOON, SUKYOUNG;AHN, JIHO;CHOI, BYEONGSEON;KIM, TONGSEOP
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.571-580
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    • 2016
  • In this paper, performance of the gas turbine combined cycle(GTCC) using pre-combustion carbon capture technology was comparatively analysed. Steam reforming and autothermal reforming were used. In the latter, two different methods were adopted to supply oxygen for the reforming process. One is to extract air form gas turbine compressor (air blowing) and the other is to supply oxygen directly from air separation unit ($O_2$ blowing). To separate $CO_2$ from the reformed gas, the chemical absorption system using MEA solution was used. The net cycle efficiency of the system adopting $O_2$ blown autothermal reforming was higher than the other two systems. The system using air blown autothermal reforming exhibited the largest net cycle power output. In addition to the performance analysis, the influence of fuel reforming and carbon capture on the operating condition of the gas turbine and the necessity of turbine re-design were investigated.

Photoelectrochemical Water Oxidation and $CO_2$ Conversion for Artificial Photosynthesis

  • Park, Hyunwoong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.70-70
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    • 2013
  • As the costs of carbon-footprinetd fuels grow continuously and simultaneously atmospheric carbon dioxide concentration increases, solar fuels are receiving growing attention as alternative clean energy carriers. These fuels include molecular hydrogen and hydrogen peroxide produced from water, and hydrocarbons converted from carbon dioxide. For high efficiency solar fuel production, not only light absorbers (oxide semiconductors, Si, inorganic complexes, etc) should absorb most sunlight, but also charge separation and interfacial charge transfers need to occur efficiently. With this in mind, this talk will introduce the fundamentals of solar fuel production and artificial photosynthesis, and then discuss in detail on photoelectrochemical (PEC) water splitting and CO2 conversion. This talk largely divides into two section: PEC water oxidation and PEC CO2 reduction. The former is very important for proton-coupled electron transfer to CO2. For this oxidation, a variety of oxide semiconductors have been tested including TiO2, ZnO, WO3, BiVO4, and Fe2O3. Although they are essentially capable of oxidizing water into molecular oxygen, the efficiency is very low primarily because of high overpotentials and slow kinetics. This challenge has been overcome by coupling with oxygen evolving catalysts (OECs) and/or doping donor elements. In the latter, surface-modified p-Si electrodes are fabricated to absorb visible light and catalyze the CO2 reduction. For modification, metal nanoparticles are electrodeposited on the p-Si and their PEC performance is compared.

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Tuning of Electro-optical Properties of Nano-structured SnO2:Ga Powders in a Micro Drop Fluidized Reactor

  • Lim, Dae Ho;Yang, Si Woo;Yoo, Dong June;Lee, Chan Gi;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.259-266
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    • 2019
  • Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

Effectiveness of Continuous Deflective Separation System to Control Nonpoint Source Pollution from Urban Areas (도시지역 비점오염원 관리를 위한 와류필터형 처리시설의 효율성 연구)

  • Park, Jong-Sik;Koh, Jeung-Hyun;Kim, Sang Keun;Chung, Ha-Ik
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.10 no.6
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    • pp.88-98
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    • 2007
  • The control of nonpoint source pollution from the urban paved areas with high imperviousness in is required to improve the water quality of aquatic resources. This research investigated the characteristics of urban runoffs and evaluate the effectiveness of the continuous deflective separation systems for stormwater best management practice. The systems were installed in the vicinity of a high-level road, an apartment complex, and the Cheonggye stream. Stormwater runoff was sampled in these sites. Biochemical oxygen demand ($BOD_5$), total suspended solid (TSS), total nitrogen (T-N), and total phosphorus (T-P) were analyzed. The removal efficiency of $BOD_5$, TSS, and T-P for the road was 10.9-81.0%, 11.7-93.4%, 0-37.5%, respectively. That of $BOD_5$, TSS, T-N, and T-P for the complex was 12.5-65.8%, 26.5-77.6%, 1.8-28.7%, and 20.0-37.5%, respectively. The abatement efficiency $BOD_5$, TSS, T-N, and T-P for the stream was 7.2-85.2%, 41.7-98.2%, 11.3-65.6%, and 2.0-71.5%, respectively. This study shows that the systems can be used to remove $BOD_5$ and TSS from urban runoffs efficiently.

Resourcing of Methane in the Biogas Using Membrane Process (분리막을 이용한 바이오가스의 메탄 자원화)

  • Park, Young G.;Yang, Youngsun
    • Clean Technology
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    • v.20 no.4
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    • pp.406-414
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    • 2014
  • Biogas is a gaseous mixture produced from microbial digestion of organic materials in the absence of oxygen. Raw biogas, depending upon organic materials, digestion time and process conditions, contains about 45-75% methane, 30-50% carbon dioxide, 0.3% of hydrogen sulfide gas and fraction of water vapor. To achieve the standard composition of the biogas the treatment techniques like absorption or membrane separation was performed for the resourcing of biogas. In this paper the experimental results of the methane purification in simulated biogas mixture consisted of methane, carbon dioxide and hydrogen sulfide were presented. The composite membrane is manufactured within polysulfone in order to increase the separation performances for the gaseous mixtures of $CO_2$ and $CH_4$ which are main components of the biogas. The effects of feed pressures and mixed gas on the separation of $CO_2-CH_4$ by membrane are investigated. Chelate chemical was utilized to treat the purification of methane from the $H_2S$ concentration of 0.3%.

Solvent Resistance and Gas Permeation Property of PEI-PDMS Hollow Fiber Composite Membrane for Separation and Recovery of VOCs (VOCs의 분리 및 회수를 위한 PEI-PDMS 중공사 복합막의 내용매성 및 기체 투과 특성)

  • Kim, Se-Jong;Lee, Chung-Seop;Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong;Rhim, Ji-Won;Choi, Whee-Moon
    • Membrane Journal
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    • v.22 no.1
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    • pp.54-61
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    • 2012
  • To separate and recover of VOCs, supporting membranes using PEI were prepared by phase separation method and it was coated with PDMS to prepare PEI-PDMS hollow composite membrane. To investigate characteristic of prepared membrane, pure gas permeability was measured using oxygen and nitrogen, the stage cut and permeance property with feed concentration were evaluated using xylene, ethyl benzene, toluene and cyclohexane. Also, to check solvent resistance on VOCs, stress-strain property of membrane with immersion time in solvent were measured by DMA. The permeance value of $O_2$ and $N_2$ showed 63 GPU and 30 GPU respectively. Permeated VOCs concentration was decreased with increasing stage cut. But, conversely, recovery efficiency that was increased with increasing stage cut. As a result of DMA test, the stress and strain were 11.93 MPa and 13.52%, respectively.