• Title/Summary/Keyword: Oxygen Enrichment

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Petrochemistry of the Soyeonpyeong titaniferous iron ore deposits, South Korea (소연평도 함티타늄 자철광상의 암석지구화학적 연구)

  • Kim, Kyu Han;Lee, Jung Eun
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.345-361
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    • 1994
  • Lens shaped titanomagnetite ore bodies in the Soyeonpyeong iron mine are embedded in amphibolites, which were intruded into Precambrian metasediments such as garnet-mica schist, marble, mica schist, and quartz schist. Mineral chemistry, K-Ar dating and hydrogen and oxygen stable isotopic analysis for the amphibolites and titanomagnetite ores were conducted to interpret petrogenesis of amphibolite and ore genesis of titanomagnetite iron ore deposits. Amphibolites of igneous origin have unusually high content of $TiO_2$, ranging from 0.94 to 6.39 wt.% with an average value of 4.05 wt.%. REE patterns of the different lithology of the amphibolite show the similar trend with an enrichment of LREE. Amphiboles of amphibolites are consist mainly of calcic amphiboles such as ferro-hornblende, tschermakite, ferroan pargasite, and ferroan pargasitic hornblende. K-Ar ages of hornblende from amphibolite and gneissic amphibolite were determined as $440.04{\pm}6.39Ma$ and $351.03{\pm}5.21Ma$, respectively. This indicates two metamorphic events of Paleozoic age in the Korean peninsula which are correlated with Altin orogeny in China. The titanomagnetite mineralization seems to have occurred before Cambrian age based on occurrence of orebodies and ages of host amphibolites. The Soyeonpyeong iron ores are composed mainly of titanomagnetite, ilmenite, and secondary minerals such as ilmenite and hercynite exsolved in titanomagnetite. The temperature and the oxygen fugacity estimated by the titanomagnetite-ilmenite geothermometer are $500{\sim}600^{\circ}C$ (ave. $550^{\circ}C$) and about $2{\pm}10^{-23}bar$, respectively. Hornblendes from ores and amphibolites which responsible for magnetite ore mineralization, have a relatively homogeneous isotopic composition ranging from +0.8 to +3.9 ‰ in ${\delta}^{18}O$ and from -87.8 to -113.3 ‰ in ${\delta}D$. The calculated oxygen and hydrogen isotopic compositions of the fluids which were in equilibrium with hornblende at $550^{\circ}C$, range from 2.8 to 5.9‰ in ${\delta}^{18}O_{H2O}$ and from -60.41 to -81.31 ‰ in ${\delta}D_{H2O}$. The ${\delta}^{18}O_{H2O}$ value of magnetite ore fluids are in between +6.4 to + 7.9 ‰. All of these values fall in the range of primary magmatic water. A slight oxygen shift means that $^{18}O$-depleted meteoric water be acted with basic fluids during immiscible processes between silicate and titaniferous oxide melt. Mineral chemistry, isotopic compositions, and occurences of amphibolites and orebodies, suggest that the titanomagnetite melt be separated immisciblely from the titaniferous basic magma.

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Study of Euglenophytes Bloom and it's Impact on Fish Growth in Bangladesh

  • Rahman, M.M.;Jewel, M.A.S.;Khan, S.;Haque, M.M.
    • ALGAE
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    • v.22 no.3
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    • pp.185-192
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    • 2007
  • A study was carried out in nine fertilized fish ponds under three treatments (T-I, T-II and T-III) at Bangladesh Agricultural University, Mymensingh to see the bloom of euglenophytes with the intention of observing its impact on the growth of fish in culture condition. Some water quality parameters viz., temperature, dissolved oxygen, pH, PO4-P and NO3-N concentration and some biological parameters viz., phytoplankton population and growth of fish were monitored at fixed intervals. Euglenophytes showed a heavy bloom in late August in the ponds of T-II. The bloom was occurred by the genera, Euglena, Phacus and Trachelomonas of which Euglena was the most dominant genus. In relation of water quality parameters with euglenophytes bloom, it was hypothesized that euglenophytes prefers higher temperature and acidic environment with higher nutrient concentrations. Acidic environment and nutrient enrichment enhanced the bloom of euglenophytes which hampered the growth of other beneficial algal groups (chlorophytes and bacillariophytes) and fish. Due to heavy bloom, the fishes breathed with difficulty at the surface. The fishes in the heavy bloom ponds presented the weight values were lower than verified for those in the ponds where the bloom did not occur. Total production (calculated) of fish in different treatments ranged from 1355.89 to1760.63 kg ha–1 with significantly (p < 0.05) lowest in the ponds of T-II.

SPECTROSCOPY OF BRIGHT EXTRAGALACTIC PLANETARY NEBULAE

  • Richer, Michael G.
    • Journal of The Korean Astronomical Society
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    • v.40 no.4
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    • pp.183-186
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    • 2007
  • The spectroscopic properties of bright extragalactic planetary nebulae are reviewed, considering primarily their chemical abundances and their internal kinematics. Low-resolution spectroscopy is used to investigate how the precursor stars of bright planetary nebulae modify their original composition through nucleosynthesis and dredge up. At present, the evidence indicates that oxygen and neon abundances usually remain unchanged, helium abundances are typically enhanced by less than 50%, while nitrogen enhancements span a very wide range. Interpreting these changes in terms of the masses of their progenitor stars implies that the progenitor stars typically have masses or order $1.5M_{\bigodot}$ or less, though no models satisfactorily explain the nitrogen enrichment. High-resolution spectroscopy is used to study the internal kinematics of bright planetary nebulae in Local Group galaxies. At first sight, the expansion velocities are remarkably uniform, with a typical expansion velocity of 18 km/s and a range of 8-28 km/s, independent of the progenitor stellar population. Upon closer examination, bright planetary nebulae in the bulge of M31 expand slightly faster than their counterparts in M31's disk, a result that may extend generally to the planetary nebulae arising from old and young stellar populations. There are no very strong correlations between expansion velocity and global nebular properties, except that there are no large expansion velocities at the highest $H{\beta}$ luminosities (i.e., the youngest objects never expand rapidly). These results independently suggest that bright planetary nebulae arise from a similar mass range in all galaxies. Nonetheless, there are good reasons to believe that bright planetary nebulae do not arise from identical progenitor stars in all galaxies.

Experimental Investigation of NOX Reduction using a Hybrid Fuel Lean Reburning System (NOx 저감을 위한 하이브리드 연료희박 재연소 연구)

  • Kim, Hak-Young;Baek, Seung-Wook;Hwang, Chang-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.3
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    • pp.283-290
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    • 2010
  • The main goal of this study is to examine the use of a hybrid -fuel lean reburning system with air staging for $NO_X$ reduction. The experimental variables include the reburn fuel fraction, sizes of reburn- fuel-injection nozzles, oxygen enrichment ratio, and location of reburn- fuel- injection. The effect of the flow field induced by air- staging combustion on $NO_X$ reduction is considered, and then, the $NO_X$ reduction rate is compared with only fuel lean reburning system. On the basis of the effectiveness of each De-$NO_X$ process, the advantage of using the hybrid reburning system with air staging is determined and discussed.

Analysis of Water-Quality Constituents Variations before and after Weir Construction in South Han River using Probability Distribution (확률분포를 이용한 남한강 보 건설 전·후 수질변화 분석)

  • Kim, Kyung Sub
    • Journal of Korean Society on Water Environment
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    • v.35 no.1
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    • pp.55-63
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    • 2019
  • The Four Major Rivers Restoration Project started in 2009 and completed in early 2013 is a large-scale inter-ministry SOC project investing ₩22.2 $10^{12}$ and one of the Project's objectives was to enhance the water-quality grade through recovering the river eco-system and environment. The average concentration and probability distribution of water-quality constituents at given and selected sampling sites are very significant elements for analyzing and controlling the water-quality of rivers or reservoirs effectively. Average concentration can be estimated by point estimator, distribution function of water-quality constituents or Bootstrap method, in which the distribution function estimated with more data in case of insufficient dataset, is applied. Ipo and Gangcheon water-quality monitoring stations in South Han River were selected to compare and analyze the variation of concentration before and after Ipo and Gangcheon Weirs construction, using the whole 4-year's data, from 2005 to 2008 and from 2014 to 2017. Water-quality constituents such as BOD and COD relating to oxygen demanding wastes and TP and Chlorophyll-a relating to the process of nutrient enrichment called eutrophication were also selected. The guidelines for water-quality control and management after weir construction including evaluation of water-quality constituents' variations can be presented by this paper.

The effect of geochemical characteristics and environmental factors on the growth of cultured Arkshell Scapharca broughtonii at several shellfish-farming bays on the South coast of Korea (남해 연안 피조개 (Scapharca broughtonii) 양식장의 환경특성)

  • Choi, Yoon Seok;Jung, Choon-Goo
    • The Korean Journal of Malacology
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    • v.32 no.3
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    • pp.149-155
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    • 2016
  • To assess the effects of environmental factors on the sustainability of cultured ark shell Scapharca broughtonii production, we investigated the habitat characteristics of shellfish-farming bays (Gangjin Bay, Yeoja Bay, Keoje Bay and Deukryang Bay). We measured the physiochemical parameters (temperature, salinity, dissolved oxygen, nutrients, chemical oxygen demand and Chlorophyll a) and the geochemical characteristics (chemical oxygen demand, ignition loss, C/N ratio and C/S ratio). Surface sediments were collected from several shellfish-farming bays to examine the geochemical characteristics of both the benthic environment and heavy metal pollution. The grain sizes for Gangjin Bay, Yeoja Bay and Keoje Bay were similar, at the ratio of silt and clay in comparison with Deukryang bay of it. The C/N ratio was more than 5.9, reflecting the range arising from the mix of marine organisms and organic matter. The C/S ratio (more than 4.2) showed that the survey area had anoxic or sub-anoxic bottom conditions. The index of accumulation rate (Igeo) of the metals showed that those research areas can be classified as heavily polluted, heavily to moderately polluted, or more or less unpolluted, respectively. We suggested that the growth of ark shell Scapharca broughtonii in the shellfish-farming bay was effected by the various environmental conditions.

Experimental Investigation into the Combustion Characteristics on the Co-firing of Biomass with Coal as a Function of Particle Size and Blending Ratio (바이오매스(우드펠릿) 혼소율 및 입자크기에 따른 연소 특성에 관한 연구)

  • Sh, Lkhagvadorj;Kim, Sang-In;Lim, Ho;Lee, Byoung-Hwa;Kim, Seung-Mo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.1
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    • pp.31-37
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    • 2016
  • Co-firing of biomass with coal is a promising combustion technology in a coal-fired power plant. However, it still requires verifications to apply co-firing in an actual boiler. In this study, data from the Thermogravimetric analyzer(TGA) and Drop tube furnace(DTF) were used to obtain the combustion characteristics of biomass when co-firing with coal. The combustion characteristics were verified using experimental results including reactivity from the TGA and Unburned carbon(UBC) data from the DTF. The experiment also analyzed with the variation of the biomass blending ratio and biomass particle size. It was determined that increasing the biomass blending ratio resulted in incomplete chemical reactions due to insufficient oxygen levels because of the rapid initial combustion characteristics of the biomass. Thus, the optimum blending condition of the biomass based on the results of this study was found to be 5 while oxygen enrichment reduced the increase of UBC that occurred during combustion of blended biomass and coal.

How are the Spatio-Temporal Distribution Patterns of Benthic Macrofaunal Communities Affected by the Construction of Shihwa Dike in the West Coast of Korea? (시화방조제의 건설은 저서동물군집의 시${\cdot}$공간 분포에 어떠한 영향을 미쳤는가?)

  • HONG Jae-Sang;JUNG Rae-Hong;SEO In-Soo;YOON Kon-Tak;CHOI Byong-Mee;YOO Jae-Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.882-895
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    • 1997
  • Changes in the benthic communities have been studied to investigate the environmental effects before and after the construction of Shihwa Dike in the West coast of Korea. It is suggested that sequential changes in macrofaunal assemblages progressed in two sucressional directions. In the Shihwa lake under the influence of organic enrichment. First, the appearance of 'azoic tone' or 'grossly polluted zone' developed in the area of less than 6 m in depth resulted from the severe dissolved oxygen depletion due to the eutrophication from the increased organic loading. Second, the 'polluted zone' characterized by the proliferation of the opportunistic species in organically enriched area, was found in the vicinity of the industrial discharges and nearby fluvial inputs. This benthic community succession in the Shihwa lake seemed to be caused by the various ecological events such as an eutrophication in this organically enriched environment after construction of the dike and other physico-chemical parameters like salinity and dissolved oxygen in the bottom water, which may be influenced by the irregular surface water discharge and dilution by outer seawater inflow through the water gate of the dike. On the other hand, the benthic communities in the outside of the dike showed that the species richness was more than doubled and the abundance increased almost seven times more than that before the dike construction. This may be a typical characteristics of the initial phase in benthic eutrophication, suggesting that an increased organic input area may have been reponsible for this faunal change in the study area.

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The Influence of the Dissolved Oxygen of Bottom Water on the Temporal Variation of the Benthic Polychaetous Community Structure in Dangdong Bay (저층수 용존산소가 당동만 저서다모류군집 구조의 시간적 변동에 미친 영향)

  • Yang, Jin Kyeong;Shin, Hyun Chool
    • Ocean and Polar Research
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    • v.42 no.3
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    • pp.233-247
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    • 2020
  • This study was carried out at 5 sites 11 times over two years to identify the variation of benthic environments and benthic polychaetous community and analyze the benthic healthiness in Dangdong Bay, a small semi-enclosed inner bay of Jinhae Bay. The temperature of bottom water showed the typical temporal fluctuation of a temperate zone and was in the range of 5.94 ~ 23.94℃. The salinity did not change significantly during the study period and was in the range of 32.93 ~ 35.72 psu. The concentration of dissolved oxygen of bottom water fluctuated a great deal and was in the range of 0.31 ~ 10.20 mg/L. The lowest DO value was recorded in July 2015, as 0.31±0.04 mg/L corresponding to the hypoxic water mass. The hypoxic water mass was formed continuously at some sites also in July and August 2016. The mean grain size was in the range of 7.57 ~ 9.81Ø and the average was 8.89±0.20Ø. The surface sediments were mainly composed of fine sediment (mud) above 85%. The mean of TOC was 3.09±0.22% and LOI was 13.30±0.47%, showing very high levels in Korean coastal waters. The concentration of AVS was in the range of 0.33 ~ 1.28 mgS/g-dry. The high values of organic contents and AVS indicated that there had been the serious organic enrichment in Dangdong Bay. The number of species and the density of the benthic polychaetous community in Dangdong Bay were in the range of 2 ~ 38 species and 2 ~ 2,185 ind./㎡ during the study period. The number of species and density were highly sustained in winter and spring, and then decreased gradually with the formation of a hypoxic water mass in summer, and the lowest number of species and density were recorded in autumn. In September and November 2015, the dead zone expanded to almost the whole study area. Dominant polychaetous species were Capitella capitata, Lumbrineris longifolia, Paraprionospio patiens and Sigambra tentaculata, each known as opportunistic species and potential organic pollutant indicator species. In particular, Paraprionospio patiens showed a very high population density of 2,019 ind./㎡ in December 2016. Polychaetous communities at each sampling time were classified into 4 temporal groups according to dominant species in each period by cluster analysis and nMDS. 'Period Group AI' was formed in winter and spring of 2015, dominated by Capitella capitata, 'Period AII' in summer dominated by Lumbrineris longifolia, 'Period B' in autumn with no fauna in the dead zone, and particularly 'Period C' in winter of 2016 dominated by Paraprionospio patiens. As a result of analysis of benthic healthiness, the study area was estimated to be in a Fair~Very Poor condition by AMBI and in a Poor~Very Poor condition by BPI during the study period. Both AMBI and BPI showed that the study area was in a Very Poor condition in September and November 2015, and when the dead zone occurred. In Dongdong Bay, the fact that the formation of a hypoxic water mass occurred in summer and a dead zone in autumn were confirmed. In addition, the dominance of opportunistic and organic pollutant indicator species was also observed clearly. The benthic healthiness indexes such as AMBI and BPI showed that organic enrichment was serious in Dangdong Bay.

Physiochemical Characteristics and Heavy Metal in the Surface Sediments of Marine Shellfish Farming Waters in Anjung Bay, Korea (안정만 패류양식해역의 표층퇴적물의 지화학적특성과 중금속 함량)

  • Jeong, Woo-Geon;Cho, Sang-Man;Lee, Sang-Jun
    • The Korean Journal of Malacology
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    • v.30 no.4
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    • pp.421-428
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    • 2014
  • Total 20 surface sediments were collected in Anjung bay to investigate the physicochemical environment and heavy metal contents. The physicochemical investigation ranged from 6.41% to 11.68% (average $9.52{\pm}1.28%$) for ignition loss (IL), from 17.99 mg/g to 43.84 mg/g (average $27.53{\pm}6.39mg/g$) for chemical oxygen demand (COD), and from 0.05 mg/g to 0.61 mg/g (average $0.17{\pm}0.14mg/g$) for acid volatile sulfide (AVS) with significant correlation between water content (W/C) and COD. A contour of spatial distribution indicated higher organic pollution at the bottom of ascidian, Stylea clava, cultural waters. Most of metals contents was not exceeded the NOAA's effect range-low (ERL). Estimated enrichment factor (EF) ranging 0.96-1.12 indicated that the sediment environment of the studied waters was relatively pristine from heavy metal pollution in spite of increased vessel traffics, so far.