• Title/Summary/Keyword: Out-diffusion

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Effects of Alkaline Additives on CO2 Removal by Li2ZrO3 (Li2ZrO3로 CO2 제거시 알칼리 첨가제 효과)

  • Park, Joo-Won;Kang, Dong-Hwan;Jo, Young-Do;Yoo, Kyung-Seun;Lee, Jae-Goo;Kim, Jae-Ho;Han, Choon
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.535-539
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    • 2006
  • Effects of alkaline additives on the $CO_2$ removal reaction have been investigated by a thermogravimetric analyzer. $Li_2ZrO_3$ was synthesized by soild reaction of $ZrO_2$ with $Li_2CO_3$ and then alkali chemicals were added to the synthesized $Li_2ZrO_3$ and then heat treatment was carried out. Addition of alkali chemicals enhanced the reactivity of $Li_2ZrO_3$ with the following order; $K_2CO_3>NaCl>LiCl>Na_2CO_3$, which were resulted from the formation of partially melted $Li_2CO_3$. SEM photographs showed the presence of melted state and the XRD results showed that the chemical states of added salts were not changed. Addition of NaCl caused the induction time of about 60 min at the initial reaction stage and the addition of $Na_2CO_3$ inhibited the decomposition of $Li_2CO_3$ at about $700{\sim}750^{\circ}C$.

Study of Optimization and Characteristics of PSCF3737(Pr0.3Sr0.7Co0.3Fe0.7O3) for IT-SOFC (중저온형 SOFC를 위한 PSCF3737(Pr0.3Sr0.7Co0.3Fe0.7O3) 공기극 물질의 특성 및 최적화께 관한 연구)

  • Park, Kwang-Jin;Lee, Chang-Bo;Kim, Jung-Hyun;Baek, Seung-Wook;Bae, Joong-Myeon
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.207-212
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    • 2007
  • [ $PSCF3737(Pr_{0.3}Sr_{0.7}Co_{0.3}Fe_{0.7}O_3)$ ] is a good candidate cathode material for IT-SOFC(intermediate temperature solid oxide fuel cell) because of high MIEC(mixed ionic electronic conductor) conductivity. In this study, the characteristics of PSCF3737 was investigated and optimizations of sintering temperature and thickness for $PSCF3737(Pr_{0.3}Sr_{0.7}Co_{0.3}Fe_{0.7}O_3)$ was carried out. Impedance responses were divided into two parts by frequency region. Middle frequency part (${\sim}10^2\;Hz$) was concerned with oxygen reduction reaction on surface and low frequency part (${\sim}10^{-1}\;Hz$) was related with oxygen diffusion. The reasonable sintering temperature and thickness of cathode were $1200^{\circ}C$ and about $27\;{\mu}m$ with regard to EIS(electrochemical impedance spectroscopy). ASR(areas specific resistance) of optimized cathode is $0.115\;{\Omega}\;cm^2$ at $700^{\circ}C$.

An Experimental Study on the Effect of Low Fin Tube Geometry on Pool Boiling of a LiBr Solution (낮은 핀관의 형상이 LiBr 수용액의 풀 비등에 미치는 영향에 대한 실험적 연구)

  • Kim, Nae-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.7
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    • pp.591-598
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    • 2015
  • Pool boiling heat transfer coefficients of a LiBr solution were obtained for seven low fin tubes having different fin pitch and fin height. The test range covered saturation pressure from 7.38kPa to 101.3kPa, heat flux from $20kW/m^2$ to $40 kW/m^2$ and LiBr concentration from 0% to 50%. The optimum fin geometry for the present experimental range turned out to be 26 fpi with 0.18 mm fin height.The advantage of added heat transfer area and the disadvantage of slower bubble growth and departure appear to have yielded an optimum fin pitch. The heat transfer coefficient decreased as saturation pressure decreased and Libr concentration increased. The reason may be attributed to the low saturation pressure, which increased the bubble departure diameter and decreased the bubble departure frequency. As the LiBr concenreation increased, the saturation temperature increased and the mass diffusion rate decreased, which resulted in a reduced heat transfer coefficient. The heat transfer coefficients of the low fin tube were greater than those of the smooth tube. Correlations were developed based on the present data.

The Perception on Alternative Therapy of Adults in Some Areas (일부 지역 성인의 대체요법에 대한 인식도)

  • Gim, Nan-Hee;Hong, Seong-Gyun
    • Journal of the Korean Society of Radiology
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    • v.1 no.2
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    • pp.37-53
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    • 2007
  • This study is carried in the goal to investigate the individual awareness rate about alternative therapy among the unspecified persons and their experience of using it, and to promote the diffusion of alternative therapy. The questionnaire research for this study has been conducted among 300 unspecified persons who live in some areas. The following is figured out in this study: 1. To the question of knowledge grade about alternative therapies, 44.4% of respondents answer they 'know a little.' 2. Regarding the experience of using alternative therapies, 22.6% of respondents answer 'Yes.' This rate is very low, the reason of it can be perceived that the names of categories in alternative therapies has not been showed to them and they don't have pre-knowledge about it. 3. The 166 persons of 248 reply that they use alternative therapies. This rate indicate their recognition of categories of alternative therapies, and the gap of the question of experience and using nowadays is interpreted to result from the gap of the pre-knowledge. 4. Regarding the field of the alternative therapies that the respondents want to learn, the first field the male respondents choose is acupuncture(41 persons, Res in needle, bloodletting, etc.), and the female respondents choose acupuncture firstly(20 persons). Therefore the learning courses of alternative therapies are more effective when the preference of men and women is considered. Consequently, both the research about the given kinds of alternative therapies with demonstration of their medical effect and the systematic promotion and education about alternative therapy is considered to be needed.

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The Effect of Collaboration and Organization's Performance Depending on the Partnership by Information Technology Using Level: Key Subject is Moderating Variable of Information Technology Using Level (정보기술 활용 수준이 기업 간 협업과 조직의 성과관계에 미치는 영향: 정보기술 활용수준의 조절효과를 중심으로)

  • Lee, Seung-Je;Han, Pil-Koo;Kang, Byung-Goo
    • Information Systems Review
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    • v.11 no.2
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    • pp.67-90
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    • 2009
  • This study addresses information technology using level has an effect on the collaboration and organization's performance depending on the partnership that is important because of rapid development of information technology and internet diffusion. In the long view, information technology persistently increases the performance and expects the useful factor for the examing the organization's performance. Information technology using level leaves the lowness or highly, information technical application effort for the future value of each enterprise is necessary, the staff education which continuous for this the fact that the introduction is more important what continuously is information technology which is suitable at the enterprise of execution. The main purpose of this study is to figure out the difference between collaboration and organization's outcome using information technology using level that is moderating variable and difference the effect.

Isolation of Cymbidium mild mosaic virus (Cymbidium mild mosaic virus의 분리동정)

  • Chang M. U.;Doi Y.;Yora K.
    • Korean journal of applied entomology
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    • v.17 no.3 s.36
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    • pp.131-138
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    • 1978
  • A virus named Cymbidium mild mosaic virus(Cy MMV), was mechanically transmitted to Chenopodium amaranticolor from the leaves of Cymbidium with mild mosaic symptoms. The virus was cultured in C. amaranticolor, in which it produced local chlorotic and ring spots, followed by systemic vein clearing with distortion. CyMMV infected 7 out of 35 species of plants. In C. amaranticolor juice infectivity was lost by heating at $90^{\circ}C$ for 10 miuntes, and by aging at$20^{\circ}C$ for 60 days, and by diluting at $10^{-6}$ when bioassayed on C. amaranticolor. CyMMV was not transmitted by Myzus persicae. The virus was purified after clarification of homogenized C. amaranticolor leaf tissues with chloroform, by differential centrifugation followed by sucrose density gradient centrifugation. Electron microscopic examination of purified preparation showed spherical particles of 28nm in diameter. The UV absorption spectrum of purified preparation was typical of u nucleoprotein (max. at 261nm. min. at 243nm), and showed 260/280=1.72 and max/min=1.26. The value of the sedimentation coefficient of the virus was S20.w=126. In gel-diffusion tests, CyMMV antiserum reacted with CarMV, but not with any of four other viruses (BBWV, CRSV, CMV, TBRV) having similar particles and properties in vitro. In ultra-thin sections of CyMMV infected tissues, a large number of virus particles were found in the cytoplasm of mesophyll cells and in xylem vessels.

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Nasal Carriage of Staphylococcus aureus from Healthy Children Attending Day Care Center (어린이집 소아에서의 황색포도알균의 비강 보균율에 관한 연구)

  • Kim, Young Min;Oh, Chi Eun;Kim, So Hee;Lee, Jina;Choi, Eun Hwa;Lee, Hoan Jong
    • Pediatric Infection and Vaccine
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    • v.17 no.1
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    • pp.9-15
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    • 2010
  • Purpose : This study was performed to investigate the prevalence of Staphylococcus aureus (S. aureus) nasal carriage in Korean children attending day care centers. Methods : During September and October 2009, a survey for nasal carriage of S. aureus and methicillin-resistant S. aureus (MRSA) was conducted among children attending day care centers located in Seoul with questionnaire survey for evaluation of risk factors of acquisition of MRSA was obtained from their guardians. A culture of the anterior nares swabs using enrichment broth was executed for isolating S. aureus and oxacillin susceptibility was assessed by the disk diffusion method. Results : Out of the 428 children enrolled whose mean age was 55 months old, 163 (38.1%) were colonized with S. aureus. Of the 163 isolates, 40 (24.5%) were MRSA. The nasal carriage rate of S. aureus showed an increasing trend with increase of age. Based on the answer to the questionnaire, 9.2% and 3.6% of children had a recent history of hospitalization and surgery, respectively, and approximately 40% of children had a history of prescription of antibiotics within 1 year prior to enrollment. Of the 428 subjects, 40 (9.3%) were MRSA nasal carriers. Conclusion : S. aureus and MRSA carriage rate of children attending day care center in Korea was 38.1% and 9.3%, respectively. Continued surveillance for nasal carriage rate of S. aureus and MRSA (especially community-associated MRSA) is mandatory.

Synthesis and characterizations of the non-swelling property micas by hydrothermal method (비팽윤성 운모의 수열합성 및 특성평가)

  • Park, Chun-Won;Park, Sun-Min;Kambayashi, Akira
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.3
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    • pp.95-100
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    • 2006
  • Synthesis of the non-swelling property micas was carried out by hydrothermal method. In order to artificially induce the diffusion of ions, a rotating system was attached to the hydrothermal apparatus and by adding 0.7 mm zircon beads, synthesis of the non-swelling property micas could be performed in a low temperature area. The hydrothermal conditions for the preparation of micas were a reaction temperature of $260^{\circ}C$, for 72 hrs, using $1K_2O,\;1Al(OH)_3,\;4Mg(OH)_2\;and\;6SiO_2$ as the starting materials and a 8M-KOH solution as the hydrothermal solvent. The micas obtained under these conditions were a plate shape with a size of $2.89{\mu}m$ and showed a whiteness of over 97 %. Also, through the FT-IR analysis, because the absorption peak of the $Mg_3OH$ vibration was observed at approximately $3700cm^{-1}$, it could be known that it was phlogopite of non-swelling property showing the chemical composition of $KMg_3AlSi_3O_{10}(OH)_2$. This result was very consistent with the EDS analysis where O (41.34 %), Mg (3.88 %), Al (11.45 %), Si (17.62 %) and K (25.71%) elements were detected.

Effects of Vth adjustment ion implantation on Switching Characteristics of MCT(MOS Controlled Thyristor) (문턱전압 조절 이온주입에 따른 MCT (MOS Controlled Thyristor)의 스위칭 특성 연구)

  • Park, Kun-Sik;Cho, Doohyung;Won, Jong-Il;Kwak, Changsub
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.5
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    • pp.69-76
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    • 2016
  • Current driving capability of MCT (MOS Controlled Thyristor) is determined by turn-off capability of conducting current, that is off-FET performance of MCT. On the other hand, having a good turn-on characteristics, including high peak anode current ($I_{peak}$) and rate of change of current (di/dt), is essential for pulsed power system which is one of major application field of MCTs. To satisfy above two requirements, careful control of on/off-FET performance is required. However, triple diffusion and several oxidation processes change surface doping profile and make it hard to control threshold voltage ($V_{th}$) of on/off-FET. In this paper, we have demonstrated the effect of $V_{th}$ adjustment ion implantation on the performance of MCT. The fabricated MCTs (active area = $0.465mm^2$) show forward voltage drop ($V_F$) of 1.25 V at $100A/cm^2$ and Ipeak of 290 A and di/dt of $5.8kA/{\mu}s$ at $V_A=800V$. While these characteristics are unaltered by $V_{th}$ adjustment ion implantation, the turn-off gate voltage is reduced from -3.5 V to -1.6 V for conducting current of $100A/cm^2$ when the $V_{th}$ adjustment ion implantation is carried out. This demonstrates that the current driving capability is enhanced without degradation of forward conduction and turn-on switching characteristics.

Study of the Curing Reaction Rate of a Glass Fiber Reinforced Bisphenol-A (BPA) Epoxy Prepreg by Differential Scanning Calorimetry (DSC) (Differential Scanning Calorimetry (DSC)를 이용한 유리섬유 Bisphenol-A(BPA)계 에폭시 프리프레그의 경화 반응 속도 연구)

  • Kwon, Hyeon-Jin;Park, Hee-Jung;Lee, Eun-Ju;Ku, Sang-Min;Kim, Seon-Hong;Lee, Kee-Yoon
    • Composites Research
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    • v.31 no.1
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    • pp.30-36
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    • 2018
  • The curing behavior of glass fiber reinforced epoxy prepregs based on Bisphenol-A (BPA) was studied by differential scanning calorimetry (DSC). The total heat of reaction(${\Delta}H_{total}=280.3J/g$) was determined based on the results of the dynamic heating scanning experiments. Isothermal experiments were carried out at $110{\sim}130^{\circ}C$, and it was observed that the maximum conversion and the maximum reaction rate were increased as temperature increased. Also Kamal equation was applied to analyze autocatalytic reaction of epoxy prepregs. The higher temperatures, the greater reaction rate constants ($k_1$, $k_2$). Theoretical values were calculated by these reaction rate constants and compared with experimental values. And it was confirmed that they were in reasonable agreement. At the beginning of the reaction, the experimental data and theoretical prediction were shown the same tendency, but at the end of reaction, the experimental data were smaller than theoretical predicted values due to reaction rates controlled by diffusion.