• Title/Summary/Keyword: Organic removal

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Estimation of VOCs Emissions from Small-Scale Surface Coating Facilities in Seoul

  • Jin-Ho, SHIN;Woo-Taeg, KWON
    • Journal of Wellbeing Management and Applied Psychology
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    • v.6 no.1
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    • pp.17-22
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    • 2023
  • Purpose: VOCs (volatile organic compounds) are all the organic compounds that react with solar rays and increase the concentration of ozone in the troposphere and are partially also known as carcinogens. The adsorption using activated carbon is usually applied to remove VOCs. Research design, data and methodology: The 20 places of surface coating facilities were selected to evaluate the emission amount of VOCs in Seoul. In addition, the removal efficiency of VOCs in 25 places of automobile coating facilities was evaluated. Results: The average emission amount of VOCs was 10.903 kg/hr from automobile coating facilities, while 3.520 kg/hr from other surface coating facilities. The removal efficiency in adsorption with the combustion catalytic process has the mean value of 87.9% and the regeneration efficiency of activated carbon has the mean value of 95.0%. Conclusions: The removal efficiency in adsorption with the biofiltration process has the mean value of 89.8% and the regeneration efficiency of activated carbon has the mean value of 94.8%. The removal efficiency in the plasma catalyst process has the mean value of 79.3%.

Recent Advances in the Removal of Radioactive Wastes Containing 58Co and 90Sr from Aqueous Solutions Using Adsorption Technology

  • Alagumalai, Krishnapandi;Ha, Jeong Hyub;Choi, Suk Soon
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.352-366
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    • 2022
  • Nuclear power plant operations for electricity generation, rare-earth mining, nuclear medical research, and nuclear weapons reprocessing considerably increase radioactive waste, necessitating massive efforts to eradicate radioactive waste from aquatic environments. Cobalt (58Co) and strontium (90Sr) radioactive elements have been extensively employed in energy generation, nuclear weapon testing, and the manufacture of healthcare products. The erroneous discharge of these elements as pollutants into the aquatic system, radiation emissions, and long-term disposal is extremely detrimental to humans and aquatic biota. Numerous methods for treating radioactive waste-contaminated water have emerged, among which the adsorption process has been promoted for its efficacy in eliminating radioactive waste from aquatic habitats. The current review discusses the adsorptive removal of radioactive waste from aqueous solutions using low-cost adsorbents, such as graphene oxide, metal-organic frameworks, and inorganic metal oxides, as well as their composites. The chemical modification of adsorbents to increase their removal efficiency is also discussed. Finally, the current state of 58Co and 90Sr removal performances is summarized and the efficiencies of various adsorbents are compared.

Removal characteristics of NOM in advanced water treatment using ceramic MF membrane (세라믹막(MF) 고도정수처리에서 NOM 제거 특성)

  • You, Sang-Jun;Park, Sung-Han;Lim, Jae-Lim;Suh, Jeong-Min;Jang, Seong-Ho;Hong, Sung-Chul;Yi, Pyong-In
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.367-376
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    • 2014
  • This study assessed the removal efficiency of NOM which is known as the precursors of DBPs in advanced water treatment using the ceramic membrane filtration, introduced the first in the nation at the Y water treatment plant (WTP). It is generally well-known that the removal of NOM by MF Membrane is very low in water treatment process. But, the result of investigation on removal efficiency of NOM in advanced water treatment using the ceramic membrane was different as follows. The removal rate of organic contaminant by the ceramic membrane advanced water treatment was determined to be 65.5% for the DOC, 85.8% for UV254, and 77 to 86% for DBPFP. The removal rate of pre-ozonation was found to be 6 to 15% more effective compared with the pre-chlorination. The removal rate of DOC and $UV_{254}$ in biological activated carbon(BAC) process was over 50% and 75%, respectively although the rate was decreased 10 ~ 20% according to analysis items in converting from GAC to BAC.

Nitrogen Removal using Autotrophic Microorganism in Membrane-Attached Biofilm Reactor (MABR) (Membrane-Attached Biofilm Reactor(MABR)에서의 독립영양 미생물을 이용한 질소 제거)

  • Shin, Jeong-Hoon;Sang, Byoung-In;Chung, Yun-Chul;Choung, Youn-Kyoo
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.624-629
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    • 2005
  • The purpose of this study is to investigate the performance of nitrogen removal using autotrophic microorganism in the Membrane-Attached Biofilm Reactor (MABR). The treatment system consists of an aerobic MABR (R1) for nitrification and an anaerobic MABR (R2) for hydrogenotrophic denitrification. Oxygen and hydrogen were supplied through the lumen of hollow-fiber membranes as electron acceptor and donor, respectively. In phase Ι, simultaneous organic carbon removal and nitrification were carried out successfully in R1. In phase II, to develop the biofilm on the hollow-fiber membrane surface and to acclimate the microbial community to autotrophic condition, R1 and R2 were operated independently. The MABRs, R1 and R2 were connected in series continuously in phase III and operated at HRT of 8 hr or 4 hr with $NH_4{^+}-N$ concentration of influent, from 150 to 200 mgN/L. The total nitrogen removal efficiency reached the maximum value of 99% at the volumetric nitrogen loading rate of $1.20kgN/m^3{\cdot}d$ in the combined MABR system with R1 and R2. The results in this study demonstrated that the combined MABR system could operate effectively for the removal of nitrogen in wastewater not containing organic materials and can be used stably as a high rate nitrogen removal technology.

Removal of Nitrate and Particulate from Groundwater with Two stage Biofilter system (2단 생물막여과 탈질시스템에서 지하수의 질산성질소 및 입자제거특성)

  • Lee, Moo-Jae;Park, Sang-Min;Jun, Hang-Bae;Kim, Kong-Soo;Lim, Jeoung-Su
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.669-675
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    • 2005
  • Biological nitrate removal from groundwater was investigated in the biofilters packed with both gravel/sand and plastic media. Removal of particles and turbidity were also investigated in the 2-stage biofilter system consisted of biofilter and subsequent sand filter. In the single biofilter packed with gravel and sand, nitrate removal efficiency was dropped with the increase of filtration velocity and furthermore, nitrite concentration increased up to 3.2 mg-N/L at 60 m/day. Denitrification rate at the bottom layer below 25 cm was faster 8 times than upper layer in the up-flow biofilter. Nitrite build-up, due to the deficiency of organic electron donors, occurred at the upper layer of bed. Besides DO concentration and organic carbon, contact time in media was the main factor for nitrate removal in a biofilter. The most of the effluent particles from biofilter was in the range from 0.5 to $2.0{\mu}m$, which resulted in high turbidity of 1.8 NTU. However, sand filter followed by biofilter efficiently performed the removal of particles and turbidity, which could reduce the turbidity of final filtrate below 0.5 NTU. Influent nitrate was removed completely in the 2-stage biofilter and no nitrite was detected.

Nitrogen and Phosphorus Removal in Domestic Wastewater using SBR Process with Flow Changing Continuous Feed and Cyclic Draw (교대연속유입식 SBR 공정을 이용한 하수중의 질소 및 인 제거)

  • Seo, In-seok;Kim, Hong-suck;Kim, Youn-kwon;Kim, Ji-yeon
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.203-208
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    • 2006
  • A continuous feed and cyclic draw SBR process was developed to overcome flow rate fluctuation and to maximize organic matters utilization efficiency for nitrogen and phosphorus removal. The developed SBR process was operated with two parallel reactors. Influent was supplied to one reactor which was not obligately aerated. At the same time, the other reactor was just aerated without supplying influent. In addition this mode was changed periodically. Cycle time was 6hr and aeration time ratio($t_{aer}/t_{total}$) was 0.33, respectively. $COD_{cr}$ and SS removal efficiencies of 95% or higher were achieved. Nitrogen removal was so greatly influenced by influent $COD_{cr}/T-N$ ratio. At influent $COD_{cr}/T-N$ ratio of 5.7, removal efficiencies of ammonia-N, T-N and T-P were 96%, 78% and 55%, respectively. Influent $COD_{cr}/T-N$ of 4 or higher ratio was necessary to achieve 60% or higher nitrogen removal. Organic matters of influent was efficiently utilized in denitrification reaction and consumed COD has a good correlation with removed T-N(about 6.5 mgCOD/mgTN). Continuous feed and cyclic draw SBR process could be one of alternative processes for the removal of nutrients in rural area where $COD_{cr}/T-N$ ratio was low and fluctuation of flow rate was severe.

Nitrogen Removal in Flat-Panel Air-Cathode Microbial Fuel Cell according to Various Inoculum Sources and Organic Concentration (식종원 및 유기물 농도 변화에 따른 평판형 외기환원전극 미생물 연료전지의 질소 제거)

  • Park, Younghyun;Yu, Jaecheul;Nguyen, Thi Hien;Lee, Taeho
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.12
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    • pp.635-640
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    • 2016
  • Although microbial fuel cell (MFC) can produce electricity from organics in wastewater, nitrogen removal is required for application of process for wastewater treatment plant. This study developed flat-panel air-cathode MFCs (FA-MFCs) comprised of two large separator electrode assemblies (SEAs) and evaluate total nitrogen removal according to three inoculum sources and pre-nitrification acclimation. The nitrification efficiencies were >99% regardless of inoculum sources under the phase for pre-nitrification acclimation. The total nitrogen removal efficiencies of FA-MFCs without pre-nitrification acclimation were the highest at the low organic conditions (<300 mg-COD/L) under the phase for nitrification and denitrification. The increase of organic concentration influenced the total nitrogen removal efficiency, positively. The organics were removed >95% but were not used for heterotrophic denitrification totally. This study suggests that application of FA-MFC system for wastewater treatment can allow the simultaneous removal of organic and nitrogen compounds, although this affects the low electricity production.

Advanced Treatment of Swine Wastewater using Hybrid-process (복합형 공정을 이용한 양돈폐수의 고도처리)

  • Kim, Choong-Gon;Kang, Seon-Hong;Shin, Hyun-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.3
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    • pp.126-133
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    • 2004
  • This study is performed to examine the removal efficiency of organic materials,$NH_4-N$ and P in Swine-Wastewater Treatment using Hybrid-process. It named SBR process, Hybrid-process as RunI(SBR), and Run II(Struvite Tank-SBR), and compared the removal efficiency of each Run. The removal efficiency of the organic materials in each Run is like this; In Run I, TS, VS and COD was 43%, 39%, and 70%, respectively. And in Run II, TS VS, and COD was 52%, 52%, and 82%, respectively. It shows that the removal efficiency of Run II using Strutive Tank is higher. And as for the removal efficiency of $NH_4-N$ and T-P in each Run, Run II using Strutive Tank was 90% and 57%, higher than 56% and 49% of RunI. Especially for $NH_4-N$, Run II showed much higher efficiency, and this proved that Strutive Tank was very efficient process of all for the removal of N and P. As a result of this study, Hybrid-process that combines Strutive Tank and SBR is proved to be a very good process in Swine Wastewater Treatment.

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Nitrate Removal by Immobilized Denitrifying Bacteria in Recirculating Aquaculture System (순환여과식 양식 시스템에 있어서의 고정화 탈진균에 의한 질산염 제거)

  • 김상희;김필균;김중균
    • Journal of Life Science
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    • v.9 no.6
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    • pp.698-703
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    • 1999
  • For the nitrate removal in recirculating aquaculture system, a denitrifying bacterium, Pseudomonas fluorescens, was isolated from municipal sewage and the cells were immobilized in modified-polyvinly alchol (PVA) gel beads. The immobilized cells in both the fixed-and fluidized-bed reactors showed 98% of denitrification efficiency with 6hr HRT, and the removal efficiency of total organic carbon (TOC) was above 90%. Form scanning electron microscopy (SEM) observation, it was known that biofilm formed in fixed-bed reactor was thicker than that formed in fluidized-bed reactor as operation time passed.

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Ammonia Removal by Use of Zeolite at Small Wastewater Treatment System (소규모 오수처리시스템에서의 제올라이트에 의한 암모니아성 질소 제거(지역환경 \circled3))

  • 방천희;권순국
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.643-648
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    • 2000
  • The purpose of this study is to remove the ammonia by using the ion exchange effect of natural zeolite (clinoptilolite in this system) and artificial zeolite and remove the organic material by using the Absorbent Biofilter. On the removal of ammonia, natural zeolite is the more effective than artificial zeolite But on the simultaneous removal of ammonia and phosphorus, artificial zeolite is the more effective than natural zeolite.

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