• Title/Summary/Keyword: Organic coatings

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The Experimental Study on Performance of Cementitious and Organic Anti-corrossion Coatings (시멘트계 및 유기계 도포재료의 방청성능에 관한 실험적 연구)

  • 신도철;이종열;박정순;오희갑;이태규
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.150-154
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    • 1995
  • The purpose of this study is to evalute the mechanical and the anti-corrosion characteristics of cementitious, organic coatings on steel plates. Tests are performed according to KS M 5331, 5250, etc'. For the test, we used water based epoxy, Tar epoxy, the red lead, and cementitious anti-corrosion coatings. The results of adhension tests satisfying the requirements in relevant standards The impact test shown that the impact test shown that the impact resistance of cementitious anti-corrosion test, rred lead, epoxy, cementitiouse show good corrosion resistance.

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Durability of Various Anti-Corrosive Organic Coatings in Marine Environment for Twelve Years

  • Yamamoto, Mashiro;Kajiki, Toshitaka;Kamon, Toshikuni;Yoshida, Kotaro
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.20-25
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    • 2004
  • In order to clarify the durability of protective coatings for maritime steel structures, various anti-corrosive organic coated steel samples were exposed for twelve years in semitropical marine environment at Miyakojima Island, Okinawa, JAPAN. Samples were various organic coated steel pipes, 4.0 m in length and 150 mm in diameter. While the bare steel pipe entirely corroded in 4.5 mm thickness in four and half years, these organic coated steel pipes exhibited protective appearances after twelve-year-exposure except for the defect in the coatings. Polyethylene (PE) lining pipe exhibited a good protective performance. Urethane painted pipe was also good but some barnacles stuck to its surface. A combination of petrolatum tape and FRP cover showed sufficient corrosion resistance for steel surface. The correlation in results between exposure and laboratory acceleration test was examined. It was found that salt spray test (SST) results corresponded to rusted area of scratched portion and that adhesion change of coating layer corresponded to the rotating immersion test result. Among the on-site measured data, volume resistivity is utilized for the index of corrosion protection performance of organic coating.

Measurement of Water Absorption in Anticorrosive Organic Coatings Using Quartz Crystal Microbalance (QCM) (수정진동자 미세저울을 이용한 방식도막의 물 흡수 측정)

  • 이근대;도윤정;김진호;박성수;홍성수;서차수;박진환
    • Journal of Ocean Engineering and Technology
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    • v.17 no.6
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    • pp.77-82
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    • 2003
  • The absorption of water into an anti-corrosive organic coating, such as alkyd and urethane resin coating, was investigated, using a quartz crystal microbalance (QCM). Anticorrosive properties of the coatings were also measured, by means of electrochemical impedance spectroscopy (EIS). The overall absorption of water in the coating is determined by the chemical nature of resin, and decreases with increasing thickness. The enhancement of anti-corrosive performance, through increase of coating thickness, was more remarkable in the case of the coating that hadlower equilibrium water absorption. The absorption kinetics curves were Fickian in nature. The EIS analysis confirmed that the resin, having lower equilibrium water absorption, shows higher anti-corrosive performan.

Syntheses of Novel Sol-Gel Precursor Containing Anti-corrosive Functional Group and Their Uses in Organic-Inorganic Hybrid Coatings (내부식성이 우수한 졸-젤 전구체의 합성 및 이를 함유하는 유무기 하이브리드 코팅재)

  • Han, Mi-Jeong;Mang, Ji-Young;Seo, Ji-Yeon
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.405-409
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    • 2010
  • New sol-gel precursors having the ability to protect iron against corrosion were synthesized and used to prepare organic-inorganic hybrid coatings based on epoxy. Bisphenol A epoxy was modified with 3-isocyanatopropyltriethoxysilane to improve the compatibility, and water and HCl were used as catalysts for sol-gel process. Various coating formulations were prepared depending on the type of sol-gel precursors and the amount of each ingredient, and cast on iron substrates by dip-coating and thermally cured. Corrosion protection properties of coated iron were studied by a salt spray test and electrochemical impedance spectroscopy under 0.1 M NaCl electrolyte. Hybrid coatings containing anticorrosive functional group exhibited excellent corrosion protection on iron, compared to that of typical hybrid coatings. From electrochemical impedance spectroscopy, the hybrid coatings containing anticorrosive functional group could maintaine the initial impedance after 500 h, while the impedance of hybrid coatings without them started to decrease after 24 h.

Adsorption Properties of Paint Mixed with Powdered Activated Carbon According to the Number of Coatings (분말활성탄을 혼합한 도료의 도장횟수에 따른 흡착 특성)

  • Choi, Byung-Cheol;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.25-26
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    • 2021
  • Due to COVID-19, the spread of non-face-to-face culture is increasing the time spent indoors. Accordingly, it is necessary to reduce indoor air pollutants. Also, among building materials, there are paints. As the number of coatings increases, the coating film becomes thick, and there is a risk of cracking and falling off. Therefore, this study is to examine the adsorption properties of indoor air pollutants according to the number of coatings of a paint mixed with powdered activated carbon. In the experimental plan, the addition ratio of powdered activated carbon was selected as 30%, and the number of coatings was selected as primcoating, second coat, and finishing coat, and the concentration of formaldehyde and volatile organic compounds were measured. As a result, as the number of coatings increased, the concentration of formaldehyde and volatile organic compounds tended to decrease. This is considered to be due to the fact that not only the physical adsorption acted by the internal pores of the powdered activated carbon, but also because a lot of powdered activated carbon was present on the painted surface as the coating film was formed. However, since it is judged that there is an error in the concentration due to the inflow of external air as the chamber cover is opened to put the test object in the adsorption test process, it is considered that the experimental method needs to be supplemented.

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Effect of Cellulose Coatings on Postharvest Storage Qualities of Plums(Prunus salicina L.) (셀룰로오스코팅이 자두의 저장중 품질특성에 미치는 영향)

  • Song, Tae-Hee;Kim, Chul-Jai
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.4 no.2
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    • pp.45-57
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    • 1998
  • Immature and mature plums(Prunus salicina L.) were coated with calcium-added methylcellulose(CaMC) and hydroxypropylmethyl-cellulose-15(CaHPMC-15). Physicochemical, nutritional and sensory characteristics were compared during the 8-day storage period at $30^{\circ}C$. Irrespective of maturity, pH of plums increased and the titratable acidity decreased during storage. Free sugars such as glucose, fructose, sucrose and sorbitol were eventually decreased during storage, but Ca-added cellulose coatings influenced on the prevention of free sugars from decreasing especially in mature plums. Vitamin C contents in immature and mature plums became decreased during storage, but the coatings took effective on its retention. Changes of malic acid, the major organic acid in plums were appeared the same tendency as vitamin C during storage. Results of sensory evaluation showed the development of red color in peel and the softening of plum tissue, and also showed that the overall eating quality and appearance generally decreased during storage. However, the coated plums either CaMC or CaHPMC-15 exhibited the better sensory characteristics. As though the significant difference in postharvest storage quality were not found between the two coatings, CaMC and CaHPMC-15 coatings significantly contributed to the improvement of overall storage quality, especially the retention of vitamin C and organic acids only on the mature plums.

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A study on the water absorption in protective coatings (방식도막에 있어서 물의 흡수에 관한 연구)

  • Park Jin-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.55-59
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    • 1998
  • The water absorption in protective coatings, which may greatly influence the durability of these coatings, was studied using quartz crystal microbalance and electrochemical impedance technique. The water absorption in protective coatings and the change of coating capacitance with concentration of electrolyte were measured. The water absorption in coatings seems to be driven by osmotic pressure, and larger amount of water was absorbed in thinner coatings at initial stage of absorption. The amount of water absorbed in coatings changed with the type and crosslinking density of resin used in coating formulation. When water absorption and desorption of coating occured by exposing the coatings to electrolyte solutions of different concentration, increase in impedance caused by desorption of water was found to be higher in the case of thinner film.

Comparative Study of Corrosion Resistance of Organic Coating and Dry Coating on 304 Stainless Steels Used for Bipolar Plates in Polymer Electrolyte Membrane Fuel Cells (고분자전해질 연료전지 분리판용 304 스테인리스 강재의 유기습식 및 건식코팅에 따른 내식성 비교연구)

  • Yong Hyeon Kim;Jin Sung Park;Sung Jin Kim
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.242-251
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    • 2023
  • The electrochemical corrosion behaviors of 304 stainless steels (STSs) with various coatings (organic coating and dry coating) were examined, and their applicability as bipolar plates in polymer electrolyte membrane fuel cells (PEMFCs) was validated. The results showed that the organic-coated samples had a significant decrease in anodic and cathodic current density compared to the uncoated sample. However, an increase in carbon black content in the organic coating or additional heat treatment at 700 ℃ resulted in a decrease in corrosion resistance. In addition, improvements in corrosion resistance achieved by adding TiO2 powder to the organic coating were found to be limited. In contrast, dry coating with TiC and CrC exhibited higher corrosion potential, significantly lower current density, and reduced contact resistance compared to the organic coatings. Notably, the TiC-coated sample showed a comparatively lower current density and more stable behavior than the CrC-coated sample. Based on a series of experimental results, a thin TiC coating without defects is proposed as a promising surface treatment strategy for STS bipolar plates in PEMFC.

UV Blocking Coatings by Combination of Organic-inorganic Hybrid Materials and UV absorbers (유-무기 하이브리드 재료와 자외선 흡수제의 배합에 의한 자외선 차단 코팅)

  • Yu, Dong-Sik;Lee, Ji-Ho;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1296-1301
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    • 2006
  • The human eye is exposed to UV and visible light. UV light exposure becomes harmful to the eye. Protection for eyes should block all ultraviolet rays. In our study, organic-inorganic hybrid materials have been applied to UV blocking coatings with UV absorbing materials on transparent plastics. The optical properties of UV blocking coatings were investigated in PMMA, CR 39 and PC substrates. In case of all UV absorbers, the transmission of UV light decreases with an increased amount of absorber. Our findings indicate that PMMA significantly reduced the transmission of UV radiation, CR 39 showed moderate decrease, while UV-uncoated PC had some UV blocking properties. Adhesion, hot water resistance and chemical resistance of the UV-coated CR 39 lenses were good. Pencil hardness were 4H. Abrasion resistance were poor.

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Study on Tribological Behavior of Porous Anodic Aluminum Oxide with respect to Surface Coating (다공성 산화알루미늄의 표면코팅에 따른 트라이볼로지적 특성연구)

  • Kim, Young-Jin;Kim, Hyun-Joon
    • Tribology and Lubricants
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    • v.33 no.6
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    • pp.275-281
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    • 2017
  • In this work, we have fabricated anodic aluminum oxide (AAO) with ordered nanoscale porosity through an anodization process. We deposited gold and nano-organic thin films on the porous AAO surface to protect its structure and reduce friction. We investigated the tribological characteristics of the porous AAO with respect to the protective surface coatings using tribometers. While investigating the frictional characteristics of the samples by applying normal forces of the order of micro-Newton, we observed that AAO without a protective coating exhibits the highest friction coefficient. In the presence of protective surface coatings, the friction coefficient decreases significantly. We applied normal forces of the order of milli-Newton during the tribotests to investigate the wear characteristics of AAO, and observed that AAO without protective surface coatings experiences severe damage due to the brittle nature of the oxide layer. We observed the presence of several pieces of fractured particles in the wear track; these fractured particles lead to an increase in the friction. However, by using surface coatings such as gold thin films and nano-organic thin films, we confirmed that the thin films with nanoscale thickness protect the AAO surface without exhibiting significant wear tracks and maintain a stable friction coefficient for the duration of the tribotests.