• 공업화학
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• 제34권4호
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• pp.357-364
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• 2023

선택적 촉매 환원(SCR)은 질소산화물 배출을 줄이는 가장 효과적인 방법이지만, V₂O₅-WO₃/TiO₂ 촉매가 좁은 작동온도 (300~400℃) 범위를 가지기 때문에, V₂O₅-WO₃/TiO₂ 촉매의 작동 온도범위가 200~450℃인 새로운 촉매를 개발하였다. SCR 과정에서 생성되는 촉매 독인 황산암모늄은 350℃ 이상으로 가열함으로써 제거할 수 있다. 촉매 활성 부위의 수를 증가시키고 활성 물질의 분산을 촉진하기 위해 TiO₂ 지지체에 티타늄 이소프로폭사이드(TTIP) 처리를 여러 TTIP/TiO₂ 질량비로 진행하였다. 그 중 5 wt% TTIP 부하에서 높은 W 분산성으로 인해 열 안정성이 증가하였고 V⁵⁺가 형성되어 최적의 성능을 보였다. 5 wt% TTIP 부하로 처리된 촉매를 One-step co-precipitation으로 제조하였을 때 기존의 방법보다 더 나은 V-OH와 W-OH 분산 및 상호작용 향상이 나타나 더 낮은 온도에서 높은 촉매 활성으로 인해 향상된 성능을 보였다. 이를 향후 TTIP를 이용하여 TiO₂촉매의 표면을 개선하려는 연구자에게 이해하기 쉽게 설명하고자 하였다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2008년도 추계학술발표대회 논문집
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• pp.220-225
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• 2008

Cylindrical stainless-steel/sodium heat pipe for a high-temperature solar thermal application was manufactured and tested for transient and steady-state operations. Two layers of stainless-steel screen mesh wick was inserted as a capillary structure. The outer diameter of the heat pipe was 12.7 mm and the total length was 250 mm. The effective heat transport length, the thermal load, and the operating temperature were varied as thermal transport conditions of the heat pipe. The thermal load was supplied by an electric furnace up to 1kW and the cooling was performed by forced convection of air The effective thermal conductivity and the thermal resistance were investigated as a function of heat flux, heat transport length, and vapor temperature. Typical range of the total effective thermal conductivity was as low as 43,500 W/m K for heat flux of 176.4 kW/$m^2$ and of operating temperature of 1000 K.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2340-2345
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• 2008

Cylindrical stainless-steel/sodium heat pipe for a high-temperature application was manufactured and tested for transient and steady-state operations. Two layers of Stainless-steel screen mesh wick was inserted as a capillary structure. The outer diameter of the heat pipe was 12.7 mm and the total length was 250 mm. As thermal transport conditions, the effective transport length, the heat flux, the tilt angle and the operating temperature were varied. The heat was supplied by an electric furnace up to 1 kW and the cooling was performed by forced convection of air. The effective thermal conductivity and the thermal resistance were investigated as a function of heat flux, heat transport length, and vapor temperature. Typical range of the total thermal resistance was as low as $0.036^{\circ}C/W$ at $175.8\;kW/m^2$ of heat flux and $700^{\circ}C$ of operating temperature.

• 설비공학논문집
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• 제20권8호
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• pp.541-546
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• 2008

A coolant operating condition in al fuel cell stack was an important factor to determine the temperature distribution which affected the fuel cell performance and relative humidity. In this study, the fuel cell performance was evaluated as a function of the coolant flow rate with the range of $0.1{\sim}0.8$ liter/min cell and the coolant inlet temperature of $20{\sim}82^{\circ}C$. The cell temperature increased with increasing the coolant inlet temperature and with decreasing the coolant flow rate. The coolant inlet temperature and flow rate to maintain the better performance of the fuel cell were in the range of $45{\sim}60^{\circ}C$ and $0.2{\sim}0.4$ liter/min cell, respectively. The experimental results showed that the optimal heat removal rate from the stack by coolant was $0.4{\sim}0.6W/cm^2$ cell.

• 한국재료학회지
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• 제31권11호
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• pp.642-648
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• 2021

The precipitation effect of Al-6%Si-0.4%Mg-0.9%Cu-(Ti) alloy (in wt.%) after various heat treatments was studied using a laser flash device (LFA) and differential scanning calorimetry (DSC). Solid solution treatment was performed at 535 ℃ for 6 h, followed by water cooling, and samples were artificially aged in air at 180 ℃ and 220 ℃ for 5 h. The titanium-free alloy Al-6%Si-0.4%Mg-0.9%Cu showed higher thermal diffusivity than did the Al-6%Si-0.4%Mg-0.9%Cu-0.2%Ti alloy over the entire temperature range. In the temperature ranges below 200 ℃ and above 300 ℃, the value of thermal diffusivity decreased with increasing temperature. As the sample temperature increased between 200 ℃ and 400 ℃, phase precipitation occurred. From the results of DSC analysis, the temperature dependence of the change in thermal diffusivity in the temperature range between 200 ℃ and 400 ℃ was strongly influenced by the precipitation of θ'-Al₂Cu, β'-Mg₂Si, and Si phases. The most important factor in the temperature dependence of thermal diffusivity was Si precipitation.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1469-1478
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• 2014

Use of acetonitrile in electrolytes promotes better operation of supercapacitors. Recent efforts show that electrolytes containing acetonitrile can also function in a wide range of operating temperatures. Therefore, this paper addresses the dielectric relaxation processes, structure and dynamic properties of the bulk acetonitrile at various temperatures. Systems of acetonitrile were modeled using canonical ensemble and simulated by employing Molecular Dynamics method. Results show that interactions among the molecules were correlated within a cut-off radius while parallel and anti-parallel arrangements are observed beyond this radius at relatively high and low temperatures respectively. Furthermore, effects of C-C-N and C-H bending modes were greatly appreciated on the power spectral density of time rate change of dipole-dipole correlations whereas frequency shifts were observed on all modes at the lowest temperature under consideration. Linear variations with temperature were depicted for reorientation times and self-diffusion coefficients. Shear viscosity was also computed with a good accuracy within a certain range of the temperature as well.

• 한국연소학회지
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• 제19권4호
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• pp.35-41
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• 2014

The experiment was conducted to measure temperature and pressure around operating portable butane gas ranges with oversized cookwares. In this experiment, portable butane gas range with different safety equipment and two kinds of oversized cookware, each of which is made of aluminum alloy and rock, was used. As a result, temperature of the bottom of the butane and the pressure of butane barrel tend to aligned with each other. Through this result, it is reasonable that a safety criteria can be decided based on the temperature of the bottom of butane. Especially, portable butane gas ranges are safely conducted under the condition of the temperature is under 50 degree and pressure is under 500 kPa, respectively, at the bottom of the butane barrel.

• 한국광학회지
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• 제12권4호
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• pp.281-288
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• 2001

본 연구에서는 넓은 운용온도에서 열영상 장비의 광학성능을 유지하도록 하기 위한 비열화 분석 및 시험을 수행하였다. 비열화 분석은 광학계 설계를 위한 컴퓨터 프로그램인 Code-V와 SIGMA2100으로 수행하였으며 비열화 시험은 열영상 장비와 콜리메이터를 온도챔버에 함께 넣어 온도에 따른 영상을 녹화하였다. 2차원배열 검출기를 사용한 20:1 줌 열영상 장비를 가지고 비열화 시뮬레이션을 수행하였으며 그 결과를 이용하여 줌궤적을 보상하였다. 비열화 시험을 통하여 온도변화에 따라 줌궤적어 적절히 작동되어 $-32^{\circ}C-+50^{\circ}C$의 온도범위 내에서 만족할 만한 광학성능이 유지되는 것을 확인하였다.

• 전기학회논문지
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• 제64권5호
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• pp.817-823
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• 2015

IPMSM for traction motor has high power density and wide operating range. But high power density causes internal temperature rise and it makes big armature reaction which causes irreversible demagnetization. And with wide operating range, rotor rotating fast gets stress from centrifugal force. For this reason, traction motor is designed to considerate stress of rotor and irreversible demagnetization for reliability. This paper explains shape design method of 120kW IPMSM accounting improvement of reliability. Finally, the validity of the analysis and the performance evaluation were verified through testing of the final model.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.289-290
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• 2002

Stainless steel ball bearings are used in the control element drive mechanism and driving mechanisms such as step motor and gear boxes for the integral nuclear reactor, SMART. The bearings operate in pressurized pure water (primary coolant) at high temperature and should be lubricated with only this water because it is impossible to supply greases or any additional lubricant since the whole nuclear rector system should be perfectly sealed and the coolant cannot contain ingredients for bearing lubrication. Temperature of water changes from room temperature to about 120 degree Celsius and pressure rises up to 15MPa in the nuclear reactor. It can be anticipated that the frictional characteristics of the ball bearings changes according to the operating conditions, however little data are available in the literature. It is found that friction coefficient of 440C stainless steel itself does not change sharply according to temperature variation from the former research, and the friction coefficient is about 0.45 at low speed range. In this research frictional characteristics of the assembled ball bearings are investigated. A special tribometer is used to simulate the axial loading and the bearing operating conditions, temperature and pressure in the driving mechanism in the nuclear reactor. Highly purified water is used as lubricant ‘ and the water is heated up to 120 degree Celsius and pressurized to 15MPa. Friction force is monitored by the torque transducer.