• Structural Engineering and Mechanics
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• v.59 no.2
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• pp.261-275
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• 2016

Effect of silica fume on fresh properties, compressive strength at 28 days and fracture behavior of fly ash concrete composite were studied in this paper. Test results indicated that the fluidity and flowability of fly ash concrete composites decreased and fly ash concrete composite are more cohesive and appear to be sticky with the addition of silica fume. Addition of silica fume was very effective in improving the compressive strength at 28 days of fly ash concrete composite, and the compressive strength of fly ash concrete composite has a trend of increase with the increase of silica fume content. Results also indicated that all the fracture parameters of effective crack length, fracture toughness, fracture energy, the critical crack opening displacement and the maximum crack opening displacement of fly ash concrete composite decreased with the addition of silica fume. When the content of silica fume increased from 3% to 12%, these fracture parameters decreased gradually with the increase of silica fume content. Furthermore, silica fume had great effect on the relational curves of the three-point bending beam specimen. As the silica fume content increased from 3% to 12%, the areas surrounded by the three relational curves and the axes were becoming smaller and smaller, which indicated that the capability of concrete composite containing fly ash to resist crack propagation was becoming weaker and weaker.

• Magazine of the Korea Concrete Institute
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• v.5 no.4
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• pp.156-166
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• 1993

The results of an experimental study on the manufacture and the mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products(fly ash) are presented in this paper. The composites using steel fiber, fly ash, unsaturated polyester resin, styrene monomer, catalyst (cobalt octate) and accelerator(methyl ethyl ketone peroxide), fine and coarse aggreates were prepared using various mixing conditions. As the test results show. the mechanical and physical properties, such as the compressive, tensile and flexural strengths, and the setting shrinkage of fly ash$\cdot$polyester resin composites were improved considerably by increasing the fly ash-binder ratio. And the workability of steel fiber reinforced fly ash$\cdot$polyester resin composites was reduced with increasing the fly ash-binder ratio and steel fiber content. Also, the compressive, flexural strength and toughness of the composites were remarkably increased by increasing steel fiber content.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.04a
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• pp.141-145
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• 1996

The primary purpose of this study is to investigate reusal techniques of by-product produced the combined heat power plant in the construction field, which may contribute to the savings of construction materials and the conservation of enviornment. This study is compared and evaluated by testing the chemical resistance, adiabatic temperature rising test, creep and drying shrinkage. As the result of the study, the following conclusions are derived : (1) hydration heat of the fly ash concrete is less than the plain concrete in adiabatic temperature rising test, (2) the fly axh concrete (FA 30%) is similar to the plain concrete in the chemical resistamce, (3) the fly ash concrete (FA 10, 30%) is similar to the plain concrete in drying shrinkage, but the fly ash concrete (FA 50%) is highly increased, (4) the fly ash concrete (FA 30%) is less than the plain concrete in creep test.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04a
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• pp.123-128
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• 1998

Currently the study on the effective use of the fly ash is concentrated as construction materials, which is by product of electric power generating plants. Fly ash, therefore, can be used as concrete admixture for the purpose of not only increasing the concrete quality but also of utilizing materials. Within the country it is not easy to use fly ash for the construction purpose because the properties of fly ash are varied due to the use of different raw ores in the various power plants. And little previous construction experiments and the basic experiments about the formation of bubbles are performed. In this study the water-cement ratio is varied in 3 different values and compressive strength is measured and freeze-thaw experiments are preformed to establish the relationships between water-cement ratios and the durability. And also for each batch of different water-cement ratio fly ash is substituted 10%, 20% and 30% of cement and concrete mixture the admixture and the formation of bubbles and also freeze-thaw resistance.

• Journal of environmental and Sanitary engineering
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• v.14 no.3
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• pp.22-30
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• 1999

This study was carried out to examine the compressive strength characteristics of solids solidified with the lead sludge with mixture of cement and fly ashes as additive. And the additives are commercial fly ash and ESP(Electrostatic precipitator) fly ash. The compressive strength of solidified lead sludge solid was increased by adding fly ash up to 46~62%, which was the results of pozzolanic reaction. When replaced the cement with 10%of commercial fly ash, the solid showed the highest value $210{\;}kg/cm^2$, and the solidification conditions were 0.55 of the water/cement ratio and curing for 14 days. Also, the results of leaching test by EPT(Environmental Protection Agency-Toxicity Test) were showed that the solidified lead has leached out under 10%, which was less than 0.173 mg/L of EPA standard. As leaching solutions, the demineralized water, 0.1N acetic acid solution, and synthetic brine were used. and the observations by SEM of the solidified lead-laden solid after EPT leaching test were indicated the severe erosion on solid surface.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.277-280
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• 2003

The purpose of this study is for the active use of the fly ash, which is a by-product of the combustion pulverizes coal thermal power plants, to compensate for the lack of landfill and for conservation of energy, by using fly ash as the supplementary cementitious material, and to prove its possibility as the related products of the cement. First of all, we examined strength development of Micro grinding fly ash by elevating its fineness and using $Na_{2}SO_{4}$ as an activator to elevate pozzolanic reaction of fly ash. Following fly ash replacement ratio and curing temperature we hope to prove its properties to suggest its possibility in the concrete and cement industry. In case of water curing, the more fineness and higher annexing of activator is, the higher strength is, and the higher curing temperature is the more pozzolanic reaction happens.

• Journal of Environmental Science International
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• v.12 no.10
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• pp.1061-1069
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• 2003

The adsorption behaviors of strontium and cesium ions on fly ash, natural zeolites, and zeolites synthesized from fly ash were investigated. The zeolites synthesized from fly ash had greater adsorption capabilities for strontium and cesium ions than the original fly ash and natural zeolites. The maximum adsorption capacity of synthetic zeolite for strontium and cesium ions was 100 and 154 mg/g, respectively, It was found that the Freundlich isotherm model could fit the adsorption isotherm. The distribution coefficients (K$\_$d/) for strontium and cesium ions were also calculated from the adsorption isotherm data, The distribution coefficients decreased with increasing equilibrium concentration of strontium and cesium ions in solution. By studying the removal of cesium and strontium ions in the presence of calcium, magnesium, sodium, potassium, sulfate, nitrate, nitrite, and EDTA (in the range of 0.01 - 5 mM) it was found that these coexistence ions competed for the same adsorption sites with strontium and cesium ions.

• Bulletin of the Korean Chemical Society
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• v.35 no.1
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• pp.69-75
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• 2014

Accurate analysis of fly ash particles is not trivial because of complex nature in physical and chemical properties. SPLITT fractionation (SF) was employed to fractionate the fly ash particles into subpopulations in large quantities. Then the SF-fractions were analyzed by the steric mode of sedimentation field-flow fractionation (Sd/StFFF) for size analysis. The SF-fractions were also analyzed by ICP-OES. The results showed that the fly ash is mainly composed of Fe, Ca, Mg and Mn. No particular trends were observed between the particle size and the concentrations of Fe, Ca, Mg, while Mn, Cu and Zn were in higher concentrations in smaller particles. Sample preparation procedures were established, where the fly ash particles were sieved to remove large contaminants, and then washed with acetone to remove organics on the surface of particles. The sample preparation and analysis methods developed in this study could be applied to other environmental particles.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.713-716
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• 2006

The main purpose of this research was to enhance the durability in both the design and construction of dams. Especially, in case of rockfill dams, the durability of tunnel concrete in a concrete-faced rockfill dam(CFRD) is achieved by optimizing the fly ash replacement for cement and application of steel fiber. The effect on durability and thermal property corresponding to the increasing replacement of fly ash and application of steel fiber was evaluated, and the optimum value of fly ash replacement and steel fiber application was recommended. The results show that 15% of fly ash replacement and $20kg/m^3$ of steel fiber application was found to be an optimum level and demonstrated excellent performance in durability and thermal property.

• Resources Recycling
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• v.10 no.4
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• pp.10-17
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• 2001

The present work investigates the possible use of fly ash for the removal of heavy metal ions from aqueous solutions. Batch experiments were conducted and the influences of metal concentration, pH, and fly ash concentration were investigated. Heavy metals used in these studies were lead and zinc. Adsorption studies were done over a range of pH values (3~10) at $25^{\circ}C$ and heavy metal concentrations of 10~400 mg/L using fly ash concentrations of 10 and 20 g/L. Experiments were also conducted without fly ash to determine the extent of heavy metal removal by precipitation. Kinetic and equilibrium experiments were performed and adsorption data were correlated with both Langmuir and Freundlich adsorption models. The results of these studies indicate that 리y ash can be used as an adsorbent for heavy metals in the aqueous solutions, yet the degree of removal depends on the pH.