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http://dx.doi.org/10.5012/bkcs.2014.35.1.69

Characterization of Fly Ash by Field-Flow Fractionation Combined with SPLITT Fractionation and Compositional Analysis by ICP-OES  

Kang, Dong Young (Yonsei Center for Research Facilities)
Eum, Chul Hun (Korea Institute of Geoscience and Mineral Resources)
Lee, Seungho (Department of Chemistry, Hannam University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.1, 2014 , pp. 69-75 More about this Journal
Abstract
Accurate analysis of fly ash particles is not trivial because of complex nature in physical and chemical properties. SPLITT fractionation (SF) was employed to fractionate the fly ash particles into subpopulations in large quantities. Then the SF-fractions were analyzed by the steric mode of sedimentation field-flow fractionation (Sd/StFFF) for size analysis. The SF-fractions were also analyzed by ICP-OES. The results showed that the fly ash is mainly composed of Fe, Ca, Mg and Mn. No particular trends were observed between the particle size and the concentrations of Fe, Ca, Mg, while Mn, Cu and Zn were in higher concentrations in smaller particles. Sample preparation procedures were established, where the fly ash particles were sieved to remove large contaminants, and then washed with acetone to remove organics on the surface of particles. The sample preparation and analysis methods developed in this study could be applied to other environmental particles.
Keywords
Fly ash; Field-flow fractionation; SPLITT fractionation; Characterization;
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