• Title/Summary/Keyword: On-site treatment

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Treatment of Landfill Leachate using H2O2/O3 AOP and UASB Process (I) - Treatment Characteristics of Leachate depending on H2O2/O3 AOP Pretreatment and Available Nitrogen Form - (H2O2/O3 AOP와 UASB 공정을 이용한 매립지 침출수 처리(I) - H2O2/O3 AOP 전처리 및 질소원에 따른 침출수별 처리특성 -)

  • Jeong, Seung Hyun;Jeong, Byung Gon
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.643-650
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    • 2005
  • In order to treat leachate from aged landfill site effectively, removal of biologically recalcitrant organic matter and denitrification efficiency were evaluated through the combination of $H_2O_2/O_3$ AOP pretreatment process and UASB process. The results can be summarized as follows. In case of leachate having low COD/N ratio from aged landfill site, it is possible to increase available COD for denitrification in nitrate utilizing denitrification and nitrite utilizing denitrification both by enhancing biodegradability of recalcitrant organic matter as applying $H_2O_2/O_3$ AOP to pretreatment process. In this experiment, it is found that available COD for denitrification can be increased to 1.0 and 0.4 g/day, respectively. Comparison has been made between requiring COD and available COD for denitrification in each experimental stages. It is expected that high rate of denitrification can be achieved with leachate from young landfill site because higher amount of available COD for denotrification is present in the leachate than the amount of requiring COD for denitrification. Especially, In leachate from aged landfill site with low COD/N ratio, it can be concluded that denitrification using nitrite nitrogen can enhance overall denitrification performance efficiently because denitrification using nitrite nitrogen requires less amount of carbon source than denitrification using nitrate nitrogen. Comparing the biogas production rate and nitrogen content of biogas under the condition of same amount of nitrate and nitrite addition, biogas production and nitrogen content of biogas are increased during denitrification after $H_2O_2/O_3$ AOP pretreatment process. Therefore, it can be confirmed that COD/N ratio in the leachate is increased. Applying $H_2O_2/O_3$ AOP as pretreatment system of landfill leachate seems to have little economic benefit because it requires additional carbon source to denitrify ammonia nitrogen in leachate coming from aged landfill site. However, it is possible to apply this pretreatment process to leachate from old landfill site in view of AOP process can achieve removal of biologically recalcitrant organic matter and increase of available COD for denitrification simultaneously.

Synthesis of Nitrogen-Doped Graphene by Thermal Annealing of Graphene Oxide with Melamine Compounds (멜라민 화합물을 이용한 산화 그래핀 도핑 및 특성 평가)

  • Kim, Sumin;Kim, Hyun;Kim, So Yang;Han, Jong Hun
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.677-683
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    • 2019
  • In this paper, nitrogen-doped reduced graphene oxide(rGO) is obtained by thermal annealing of nitrogen-containing compounds and graphene oxide (GO) manufactured by modified Hummers' method. We use melamine as a nitrogen-containing compound and treat GO thermally with melamine at over $800{\sim}1,000^{\circ}C$ and 1 ~ 3 hr under Ar atmosphere. The electrical conductivity of doped rGO is measured by 4-point probe method. As a result, nitrogen contents on rGO are found to be in the range of 2.5 to 12.5 at% depending on the doping conditions after thermal annealing. The main doping site on graphene oxide is changed from pyridinic-N and pyrrolinic N to the graphitic site as the heat treatment temperature increases. The electrical conductivity of doped rGO increases as the N doping content increases. As the thermal treatment time increases, the change of both total doping contents and doping sites is slight and the surface resistance is remarkably reduced, which is caused by healing effects of doped graphene oxide at high temperature.

Thermal Effects on Stoichiometric LiTaO3 Single Crystal (정비조성 LiTaO3 단결정에 대한 열처리 효과)

  • Yeom, T.H.;Lee, S.H.
    • Journal of the Korean Magnetics Society
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    • v.15 no.3
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    • pp.177-180
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    • 2005
  • Ferroelectric $LiTaO_3$ single crystals, grown by the Czochralski method, were thermally treated at temperature $1000^{\circ}C\;and\;1100^{\circ}C$. Electron paramagnetic resonance (EPR) study of stoichiometric $LiTaO_3$ and thermally treated $LiTaO_3$ crystals has been investigated by employing an X-band spectrometer. From the $Fe^{3+}$ EPR spectra, it turned out that there is no change of site location and local site symmetry around $Fe^{3+}$ impurity ion between stoichiometric and thermally treated $LiTaO_3$ single crystals. We confirmed that the ionic state of $Fe^{3+}$ ion changed after thermal treatment. The EPR parameters of $Fe^{3+}$ ion in $LiTaO_3$ single crystals are determined with effective spin Hamiltonian.

Transformation using Conjugal Transfer and attB Site Properties of Streptomyces natalensis ATCC27448 (접합전달을 이용한 Streptomyces natalensis ATCC27448의 형질전환 최적화 및 attB-site의 특성연구)

  • Lee Kang-Mu;Choi Sun-Uk;Park Hae-Ryong;Hwang Yong-Il
    • Korean Journal of Microbiology
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    • v.41 no.2
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    • pp.140-145
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    • 2005
  • Streptomyces natalensis ATCC27448 produces natamycin, a commercially important macrolide antifungal antibiotic. For molecular genetic study of S. natalensis, we have developed a system for introducing DNA into S. natalensis via conjugal transfer from Escherichia coli. An effective transformation procedure for S. natalensis was established based on transconjugation from E, coli ET12567/pUZ8002 using a ${\Phi}C31$-derived integration vector, pSET152, containing oriT and attP fragments. The high frequency was obtained on MS medium containing 10 mM $MgCl_2$ using $6.25\times10^8$ of E.coli donor cells without heat treatment of spores. In addition, southern blot analysis of exconjugants and the sequence of plasmids containing DNA flanking the insertion sites from the chromosome revealed that S. natalensis contains a single ${\Phi}C31$ attB site and at least a secondary or pseudo attB site. Similar to the case of various Streptomyces species, a single ${\Phi}C31$ attB site of S. natalensis is present within an ORF encoding a pirin-homolog, but a pseudo-attB site is present within a distinct site (GenBank accession no. $YP\_117731$) and also its sequence deviates from the consensus sequences of attB sequence.

Clinical predictive diagnostic study on prognosis of Bell's palsy with the Digital Infrared Thermal Image (적외선 체열진단법을 이용한 Bell's palsy의 임상적 예후 진단 연구)

  • Song, Beom-Yong
    • Journal of Acupuncture Research
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    • v.18 no.1
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    • pp.1-13
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    • 2001
  • The Background and Purpose : Most diagnostic method for the facial palsy were invasive and complex. And we don't know very well prognosis for the recovery of facial palsy in the first stage after the onset. But the Digital Infrared Thermal Image(DITI) isn't invasive and complex diagnostic method for the facial palsy. So we should study on the clinical prognostic diagnosis of Bell's palsy among facial palsy with the DITI. Objective and Methods : This study researched into the clinical statistics for 89 case who are in Bell's palsy, and they are treated with oriental medical care at the Woosuk university during 2 years form November 1998 to October 2000. All objectives have the Grade 6(Zero state) of Bell's palsy in first week after the onset. It takes a patient's facial temperature after the onset. Group A is taken from 1 day to 4 days after the onset. Group B is taken from 5 day to 8 days after the onset. And group C is taken from 9 day to 12 days after the onset. Results and Conclusions : The Digital Infrared thermal image technique showed the more high temperature, the more rapid cure and short treatment period on TE23, B2, S3, S6 in abnormal site of Bell's palsy. But it showed the more low temperature, the more rapid cure and short treatment period on TE17 of abnormal site of Bell's palsy. As a conclusion, we could think that the prognostic diagnosis of Bell's palsy closely related with the thermal difference normal and abnormal site of Bell's palsy that were took picture after the onset.

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The Comparison on Treatment Method of Liquid Radioactive Waste in Yonggwang #3&4 and #5&6 (영광 3&4와 5&6호기에서 액체 방사성폐기물 처리방법의 비교)

  • Yeom, Yu-Seon;Kim, Soong-Pyung;Lee, Seung-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.219-230
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    • 2004
  • Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), and into radiochemical and radioactive laundry waste. Although the evaporation process has a high decontami- nation ability, it has several problems such as corrosion, foam, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED), instead of the current evaporation process, has been introduced into the Yonggwang NPP #5 and 6. These two methods have been compared to understand the differences in this study. Aspects compared here were the released radioactivity amount of the liquid radioactive wastes, the dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. The IED system is designed to discharge higher radioactivity about 20% than the evaporating system, and the actual radioactivity released from the evaporating and IED system were 0.473mCi and 1.098mCi, respectively. The radioactivity released from the IED was 2.32 times higher than that of the evaporating system. The dose of off-site residents was $2.97{\times}10^{-6}$mSv for the evaporating system, and $6.47{\times}10^{-6}$mSv for IED. The decontamination factor(DF) of the evaporator is, in most cases, far lower than the lower limits of detection(LLD) with the Ge-Li detector. Due to the low concentration of the liquid wastes collected from the liquid waste system, the decontamination factor of IED is very low. Since there is not enough data on the amount of solid radioactive wastes generated by the evaporation system, the comparison on these two systems has been conducted on the basis of the design, and the comparison result was that the evaporating system generated more wastes about 40% than IED.

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A Study of Conservation Treatment for Gilt-Bronze Cap Excavated from Ahndong Tumulus, Gildu-ri Site in Goheung (고흥 길두리 안동고분 출토 금동관모의 수습과 보존처리(II))

  • Seo, Jung-Eun
    • 보존과학연구
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    • s.30
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    • pp.5-19
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    • 2009
  • This study is about the conservation treatment from 2008 through 2009 of Gilt-Bronze Cap excavated from Andong tumulus at Guildu-ri, Podumyeon, Goheung, Jeonnan. The whole shape of Gilt-Bronze Cap was distorted and destroyed by the earth pressure. For the conservation treatment, first, soil and pollutants came from the findspot were removed. And then to assemble the whole shape of Gilt-Bronze Cap, we carried out the jointing work forming the shape after dismantling. Under that process, the rust of bronze was removed through the microscope at every moment and the gold-plated surface was revealed. Now the conservation treatment was completed and it is expected to perform the scientific research on the manufacturing methods and composition analysis of Gilt-Bronze Cap.

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A Study on the Adequate Treatment of Municipal Landfill Leachate -A Case Study of Nanjido Landfill Leachate- (도시폐기물 매립지 침출수의 적정처리에 관한 연구 -난지도 폐기물 매립지 침출수를 대상으로-)

  • 이병인
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.269-276
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    • 1995
  • An experimental research was conducted in order to study the treatability of municipal landfill leachate using a combined physio-chemical and biological treatment. The leachate was obtained from Nanjido landfill site in Seoul. Several sets of bench-scale sequencing batch reactor(SBR) and physic-chemical reactors were used as experimental apparatus. This experiment lasted for about 2 years. The results are as follows: 1. The characteristics of Nanjido landfill leachate were pH 7.4~8.2, BOD 79~450mg/L, COD 998~1460mg/L, $NH_3-N$ 1380~3412mg/L, 7-P 2.6~7.0mg/L, color 890~1992 unit, and heavy metals are a very small amount. 2. Either physio-chemical or biological treatment of Landfill leachate alone did not work well. So for the adequate treatment of leachate, it was necessary to deal with the physio-chemical pretreatment before biological treatment. And it was found that both electrolysis and ozone treatment are better pretreatments of leachate than others. 3. In this study, landfill leachate was effectively processed by two step : first by electrolysis pretreatment, and secondly by SBR treatment. Thus, the study showed considerable substrate removal of raw leachate, even though the rate of COD removal depended on HRT.

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