• 제목/요약/키워드: Omega phase

검색결과 393건 처리시간 0.024초

역상(逆相)-HPLC와 $Ag^+$-HPLC에 의한 잣기름의 트리아실글리세롤분자종(分子種)의 상호분리(相互分離) (Studies on Resolution of the Molecular Species of Triacyl-glycerols in the Seed of Pinus koraiensis by HPLC in the Reverse-phase and Ag-ion Modes.)

  • 우효경;조용계;김성진
    • 한국응용과학기술학회지
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    • 제15권4호
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    • pp.1-9
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    • 1998
  • The lipids from the seeds of Pinus koraiensis mostly composed of triacylglycerols (TGs), in which linoleic acid (46.2 mol%) and oleic acid (25.6 mol%) are present as main components in the fatty acid composition. Surprisingly, they also have unusual fatty acids with ${\Delta}^5$-double bond systems such as ${\Delta}^{5.9.12}-C_{18:3}$ (16.0 mol%), ${\Delta}^{5.9}-C_{18:2}$ (2.3 mol%) and ${\Delta}^{5.11.14}-C_{20:3}$ (0.8 mol%). Saturated fatty acids of palmitic, stearic and arachidic acid were present in less than 8.0 mol%. TG was resolved into 17 fractions by reverse-phase HPLC according to so-called partition number (PN) suggested by Plattner, in which TG molecules with ${\Delta}^{5}$-NMDB acyl chains eluted later than did those with ${\Delta}^{9}$-MDB acyl radicals. $Ag^+$-HPLC separated the TG into 14 fractions more clearly than did those with ${\Delta}^{9}$-MDB acyl radicals. $Ag^+$-HPLC separated the TG into 14 fractions more clearly than did reverse-phase HPLC, and the complexity of ${\Delta}^{5.9.12}-C_{18:3}$ moiety with silver ion impregnated in the column bed was in the level between ${\Delta}^{9.12.15}-C_{18:3}$ ($C_{18:3{\omega}3}$) and $C_{18:2{\omega}6}$ (${\Delta}^{9.12}-C_{18:2}$). In the $Ag^+$-HPLC, it was found that the molecular species having a given-numbered double bonds widely spreaded in the acyl chains eluted earlier than those concentrated in one acyl chain. The main molecular species are $(C_{18:2{\omega}6})_2/{\Delta}^{5.9.12}-C_{18:3}$ (14.8 mol%), $C_{18:1{\omega}9}/C_{18:2{\omega}6})_2$ (12.8 mol%) and $C_{18:1{\omega}9}/C_{18:2{\omega}6}/{\Delta}^{5.9.12}-C_{18:3}$ (10.9 mol%).

마르텐사이트계 스테인리스강의 템퍼 취성과 준안정상에 관한 분석 (Analysis on Temper Embrittlement and Metastable Phase of Martensitic Stainless Steel)

  • 이길재;최병학;김재훈
    • 열처리공학회지
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    • 제34권1호
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    • pp.1-9
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    • 2021
  • The martensitic stainless steel has excellent corrosion resistance and higher strength by quenching and tempering heat treatment. It has been widely used as blade material due to these properties. The hardness and impact toughness of martensitic stainless steel depended strongly on tempering temperatures. The 12Cr martensite stainless steel (SS 410) tempered about 540℃ showed temper embrittlement. To know cause of temper embrittlement in terms of phase identification, a detailed analysis of electron diffraction patterns during TEM observations has been carried out on the <110>α-Fe and <113>α-Fe zone axes for temper embrittlement specimen. The double electron diffraction spots at 1/3(211) and 2/3(211) positions were observed. The lattice space between individual diffraction spots was about 3.5 Å and this value coincide with three times to α-bcc lattice space (1.17 Å). The area which found double diffraction spots was judged metastable "zone" similar to the omega phase and induced embrittlement of SS410 material.

개선된 산 클러스터링 방법의 매개변수 설정법 (Identification of the Advanced Mountain Methods parameter)

  • 손세호;권순학;이중우
    • 한국지능시스템학회:학술대회논문집
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    • 한국퍼지및지능시스템학회 2000년도 추계학술대회 학술발표 논문집
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    • pp.125-128
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    • 2000
  • In this paper, we introduce an algorithm for identification of the Advanced Mountain Methods parameter. It consists of two phases: Phase I and Phase II. In Phase I, a given data space is divided into subspaces based on the density of the given data. In Phase II, we obtain the AMMs parameter $\omega$ by selecting the minimum of variances of subspaces obtained in Phase I. Numerical examples are presented to show the validity of the proposed method.

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나노급 수소화된 비정질 실리콘층 두께에 따른 저온형성 니켈실리사이드의 물성 연구 (Property of Nickel Silicides with Hydrogenated Amorphous Silicon Thickness Prepared by Low Temperature Process)

  • 김종률;최용윤;박종성;송오성
    • 대한금속재료학회지
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    • 제46권11호
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    • pp.762-769
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    • 2008
  • Hydrogenated amorphous silicon(a-Si : H) layers, 120 nm and 50 nm in thickness, were deposited on 200 $nm-SiO_2$/single-Si substrates by inductively coupled plasma chemical vapor deposition(ICP-CVD). Subsequently, 30 nm-Ni layers were deposited by E-beam evaporation. Finally, 30 nm-Ni/120 nm a-Si : H/200 $nm-SiO_2$/single-Si and 30 nm-Ni/50 nm a-Si:H/200 $nm-SiO_2$/single-Si were prepared. The prepared samples were annealed by rapid thermal annealing(RTA) from $200^{\circ}C$ to $500^{\circ}C$ in $50^{\circ}C$ increments for 30 minute. A four-point tester, high resolution X-ray diffraction(HRXRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and scanning probe microscopy(SPM) were used to examine the sheet resistance, phase transformation, in-plane microstructure, cross-sectional microstructure, and surface roughness, respectively. The nickel silicide on the 120 nm a-Si:H substrate showed high sheet resistance($470{\Omega}/{\Box}$) at T(temperature) < $450^{\circ}C$ and low sheet resistance ($70{\Omega}/{\Box}$) at T > $450^{\circ}C$. The high and low resistive regions contained ${\zeta}-Ni_2Si$ and NiSi, respectively. In case of microstructure showed mixed phase of nickel silicide and a-Si:H on the residual a-Si:H layer at T < $450^{\circ}C$ but no mixed phase and a residual a-Si:H layer at T > $450^{\circ}C$. The surface roughness matched the phase transformation according to the silicidation temperature. The nickel silicide on the 50 nm a-Si:H substrate had high sheet resistance(${\sim}1k{\Omega}/{\Box}$) at T < $400^{\circ}C$ and low sheet resistance ($100{\Omega}/{\Box}$) at T > $400^{\circ}C$. This was attributed to the formation of ${\delta}-Ni_2Si$ at T > $400^{\circ}C$ regardless of the siliciation temperature. An examination of the microstructure showed a region of nickel silicide at T < $400^{\circ}C$ that consisted of a mixed phase of nickel silicide and a-Si:H without a residual a-Si:H layer. The region at T > $400^{\circ}C$ showed crystalline nickel silicide without a mixed phase. The surface roughness remained constant regardless of the silicidation temperature. Our results suggest that a 50 nm a-Si:H nickel silicide layer is advantageous of the active layer of a thin film transistor(TFT) when applying a nano-thick layer with a constant sheet resistance, surface roughness, and ${\delta}-Ni_2Si$ temperatures > $400^{\circ}C$.

Reversed-phase 및 $Ag^{+}$-HPLC에 의한 Conjugate Trienoic Acid 함유(含有) Triacylglycerol 분자종(分子種)의 상호분리(相互分離) (Resolution of the Triacylglycerols Containing Conjugate Trienoic Acids into Their Molecular Species by HPLC in the Reversed-phase and Silver Ion Mode)

  • 김성진;우효정;조용계
    • 한국응용과학기술학회지
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    • 제18권3호
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    • pp.197-213
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    • 2001
  • Conjugate trienoic acids (CTA) occurred in triacylglycerols (TGs) of the seed oils of Trichosanthes kirilowii, Momordica charantia and Aleurites fordii, and they were easily converted to their methyl esters in a mixture of sodium methoxide-methanol without any structural destruction. The main fatty acids in triacylglycerol (TG) fraction of the seed oils of Trichosanthes kirilowii are $C_{18:2{\omega}6}$ (32.2 mol %), $C_{18:3{\;}9c.11t,13c}$ (38.0 mol %) and $C_{18:1{\omega}9}$ (11.8 mol %), followed with $C_{16:0}$ (4.8 mol %) and $C_{18:0}$ (3.1 mol %). The TG fraction was resolved into 20 TG molecular species according to the partition number (PN) by reversed-phase (RP)-HPLC. The main TG species were $DT_{c2}$, $MDT_{c}$ and $D_{2}T_{c}$, of which amounts reached 63 mol % of total TG molecular species. The TG sample was fractionated into 11 fractions according to the number of double bond in the molecule by $Ag^{+}-HPLC$ and the species of $DT_{c2}$, $MDT_{c}$ and $D_{2}T_{c}$ were also eluted as main components. The TG species containing CTA showed unusual behaviours in the order of elution by HPLC ; first, TG moleular species of $DT_{c2}$ (D; dienoic acid, $T_{c}$; punicic acid, $T_{ci}$; ${\alpha}-eleostearic$ acid, M ; monoenoic acid, $S_{t}$; stearic acid) was eluted earlier than $Mt_{c2}$, although they have the same PN number of 40, and, secondly, the species of $DT_{ci2}$ with eight double bonds was eluted earlier than that of $D_2T_{ci}$ with seven double bonds. Intact TG of the seed oils of Momordica charantia contained mainly fatty acids such as $C_{18:3{\omega}9c,11t,13t}$ (57.7 mol %), $C_{18:1{\omega}9}$ (17.4 mol %), $C_{18:0}$ (12.3 mol %) and $C_{18:2{\omega}6}$ (10.6 mol %), and was classified into 13 fractions by RP-HPLC. The main TG species were as follows ; $MT_{ci2}$ [$(C_{18:1{\omega}9})(C_{18:3\;9c,11t,13t})_{2}$, 39.1 mol %] and $S_{t}T_{ci2}$ [$(C_{18:0})(C_{18:3\;9c,11t,13t})_2$, 33.9 mol %] comprising about 73 mol % of total TG species, accompanied by $DT_{ci2}$ [$(C_{18:2{\omega}6})(C_{18:3\;9c,11t,13t})_{2}$, 7.3 mol %], $D_{2}T_{ci}$ [$ (C_{18:2{\omega}6})_{2}(C_{18:3\;9c,11t,13t})$, 3.6 mol %] and $MDT_{ci}$ [$(C_{18:1{\omega}9})(C_{18:2{\omega}6})(C_{18:3\;9c,11t,13t})$, 3.5 mol %]. Simple TG species of $T_{ci3}$ [$(C_{18:3\;9c,11t,13t})_3]$ was present in a small amount of 1.4 mol %, but other simple TG species were not detected. The TG was also resolved into 11 fractions according to the number of double bond by $Ag^{+}-HPLC$, and the species were mainly occupied by $MT_{ci2}$ [$(C_{18:1{\omega}9})(C_{18:3\;9c,11t,13t})_{2}$, 39.4 mol %] and $S_tT-{ci2}$ [$(C_{18:0})(C_{18:3\;9c,11t,13t})_{2}$, 35.4 mol %] $DT_{ci2}$ species with eight double bonds was also developed faster than $D_2T_{ci}$ one with seven double bonds as indicated in the analysis of TG of the seed oils of T. kirilowii, and $MT_{ci2}$ species with cis, trans, trans-configurated double bond was eluted earlier than $MT_{c2}$ species with cis, trans, cis-configurated double bond. The main components of fatty acid in total TG fraction isolated from the seed oils of of Aleurites fordii were in the following order ; $C_{18:3\;9c,11t,13t}$ (81.2 mol %)> $C_{18:2{\omega}6}$ (8.5 mol %)> $C_{18:1{\omega}9}$ (5.4 mol %)$. With resolution of the TG by RP-HPLC, eight fractions such as $T_{ci3}$, $Dt_{ci2}$, $D_{2}T_{ci}$, $MT_{ci2}$, $PT_{ci2}$ (P; palmitic acid), $PMT_{ci}$, $PDT_{ci}$ and $S_{t}T_{ci2}$ ($S_{t}$; stearic acid) were isolated, respectively. TG species of $T_{ci3}$ [$(C_{18:3\;9c,11t,13t})_{3}$, 54.2 mol %], $DT_{ci2}$ [$(C_{18:2{\omega}6})(C_{18:3\;9c,11t,13t})_{2}$, 15.0 mol %] and $MT_{ci2}$ [$(C_{18:1{\omega}9})(C_{18:3 9c,11t,13t})_{2}$, 14.8 mol %] were present as main species.

발열 전극에 따른 상변화 메모리 소자의 전자장 및 열 해석 (Electromagnetic and Thermal Analysis of Phase Change Memory Device with Heater Electrode)

  • 장낙원;마석범;김홍승
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권4호
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    • pp.410-416
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    • 2007
  • PRAM (Phase change random access memory) is one of the most promising candidates for next generation non-volatile memories. However, the high reset current is one major obstacle to develop a high density PRAM. One way of the reset current reduction is to change the heater electrode material. In this paper, to reduce the reset current for phase transition, we have investigated the effect of heater electrode material parameters using finite element analysis. From the simulation. the reset current of PRAM cell is reduced from 2.0 mA to 0.72 mA as the electrical conductivity of heater is decreased from $1.0{\times}10^6\;(1/{\Omega}{\cdot}m$) to $1.0{\times}10^4\;(1/{\Omega}{\cdot}m$). As the thermal conductivity of heater is decreased, the reset current is slightly reduced. But the reset current of PRAM cell is not changed as the specific heat of heater is changed.

THE PROPERLY SUPPORTED GENERALIZED PSEUDO DIFFERENTIAL OPERATORS

  • Kang, Buhyeon
    • 충청수학회지
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    • 제28권2호
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    • pp.269-286
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    • 2015
  • In this paper, we extend the concept of the pseudo differential operators in the usual Schwartz's distribution spaces to the one of the generalized pseudo differential operators in the Beurling's generalized distribution spaces. And we shall investigate some properties of the generalized pseudo differential operators including the generalized pseudo local property. Finally, we will study the smoothness and properly supported property of these operators.

FDTD 방법을 이용한 Corrugated Feed-Horn Antenna 의 특성에 대한 연구 (A Study on the Characteristics of the Corrugated Feed-Horn Antenna Using FDTD Method)

  • 박혁균;성혁제;손병문;구연건
    • 한국전자파학회논문지
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    • 제11권4호
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    • pp.619-626
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    • 2000
  • 본 논문에서는 $\infty$rrugation이 개구변에 수직인 환형 급전-혼 안테나의 전파반사를 FDTD 방법으로 해석하였 다. 동축선로로 혼 안테나가 급전할 때 thin wire 안테나 모델과 전계와 자계를 전압과 전류로 모댈렁한 1차원 F FDTD코딩방법을 이용하여 계산시간을 효율적으로 줄일 수 있었다. 중심주파수 11.8 GHz(X -band)에서 급천 동축선로의 특성임피던스를 50$\Omega$에서 20$\Omega$까지 lO$\Omega$씩 변화시켜 가며 계산한 결과 특성임피던스가 30$\Omega$인 경우 11 GHz-14 GHz의 넓은 주파수 영역에서 반사손실이 -25 dB 이상의 좋은 특성을 보인다. 또한 corrugation이 있을 때 방사패턴의 지향성이 개선되며 개구변에서의 위상오차가 감소됨을 확인하였다.

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회전유동에서의 관성진동 원인규명 (Onset of Inertial Oscillation in a Rotating Flow)

  • 박준상
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2536-2539
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    • 2008
  • A study has been made on how to occur inertial oscillations in a rotating flow. The flow is considered to be induced by differentially-rotating top and bottom disks with infinite radius. The top and bottom disks are assumed to be set in motion over a finite initial start-up time duration from initial solid body rotation ($\Omega$) to each finial state, i.e., the top disk is rotating at the angular velocity (${\Omega}+{\Delta}{\Omega}$) and the bottom disk (${\Omega}-{\Delta}{\Omega}$). The system Reynolds number, which is a reciprocal of conventional Ekman number in rotating flows, is very high so that a boundary layer flow near disks is pronounced. From a strict theoretical analysis, it is clearly found the fact that inertial oscillation in a rotating flow is caused by excessive input of torque during start-up phase. Above finding comes from the following physics of theoretical result: in the case of abrupt start-up within very shorter time-duration than spin-up time scale, the inertial oscillation is magnified but it could be completely depressed in the case of mildly accelerated start-up, i.e., start-up process being established over diffusion time scale.

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Stefan Holm의 높이뛰기 발구름 동작에서의 충격력과 상지와 하지 분절의 운동학적 분석 (Analysis of Impulse Force and Kinematic Factors of the Limbs during Stefan Holm's Take-off Phase and Penultimate Stride of High Jump)

  • 이진택
    • 한국운동역학회지
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    • 제21권1호
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    • pp.97-105
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    • 2011
  • The purpose of this study was to investigate the kinetic factors of Stefan holm's take-off motion and provide the technical data. Collected data of the subject(height: 181 cm, weight: 71 kg, record: 230 cm) were used for the last two strides and take-off phase. The results were as follows: The vertical impulse force was 2044.8 N which was 2.49 times and the anterior-posterior impulse force was -1306.4 N which was 1.88 times of the subject's weight. The take-off leg angular velocities($\omega_x,\;\omega_y$) were switched drastically from clockwise to count clockwise direction between two-step touchdown and take-off. The highest jerk of the take-off foot was 368.97 m/s3 during the two step take-off and the take-off foot made an impact to the ground with 1225.07 m/s3 during the one step touchdown.