• Title/Summary/Keyword: ODA

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The Korean Strategy for the Science and Technology Park of the Developing Countries : The cases of Ecuador and Kazakhstan (개발도상국의 과학기술단지(STP) 건립을 위한 한국의 전략 : 에콰도르, 카자흐스탄의 사례를 중심으로)

  • Kim, Jong Jin;Choi, Jong In
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.7 no.4
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    • pp.131-141
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    • 2012
  • The miracle of Korean economic development is the benchmarking for the developing countries. Among them, the STP of Science and technology area is very important case they tring to learn from Deadeok, Korea. Ecuador and Kazakhstan have the huge natural resources and they have interested in the model of Daedeok STP. This paper study about their needs and Daedeok's capability, and effective implementing factors. This paper suggest a six one based on the Daedeok Innopolis experiences for the successful local STP. First, most important thing is human resource development strategy for the knowledge and technology transfer. Second, the construction of Engineering Center for the collaboration of industry and academy is needed. This is important to have a bargaining power to the appropriate technology transfer. Third, they need a hardware and software infrastructure to the technology commercialization. It include a incubator, manager, and complimentary asset. Fourth, they have to connect with market closely for the venture creation and growth. Fifth, the clustering is realized by the STP construction. Lastly, leadership is critical factor to the absorptive capacity.

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Soluble Polyimide Binder for Silicon Electrodes in Lithium Secondary Batteries (리튬이차전지 실리콘 전극용 용해성 폴리이미드 바인더)

  • Song, Danoh;Lee, Seung Hyun;Kim, Kyuman;Ryou, Myung-Hyun;Park, Won Ho;Lee, Yong Min
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.674-680
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    • 2015
  • A solvent-soluble polyimide (PI) polymeric binder was synthesized by a two-step reaction for silicon (Si) anodes for lithium-ion batteries. Polyamic acid was first prepared through ring opening between two monomers, bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA) and 4,4-oxydianiline (ODA), followed by condensation reaction. Using the synthesized PI polymeric binder (molecular weight = ~10,945), the coating slurry was then prepared and Si anode was fabricated. For the control system, Si anode based on polyvinylidene fluoride (PVDF, molecular weight = ~350,000) having the same constituent ratio was prepared. During precycling, PI polymeric binder revealed much improved discharge capacity ($2,167mAh\;g^{-1}$) compared to that of using PVDF polymeric binder ($1,740mAh\;g^{-1}$), while the Coulombic efficiency of two systems were similar. PI polymeric binder improved the cycle retention ability during cycles compared to that of using PVDF, which is attributed to an improved adhesion property inside Si anode diminishing the dimensional stress during Si volume changes. The adhesion property of each polymeric binder in Si anode was confirmed by surface and interfacial cutting analysis system (SAICAS) (Si anode based on PI polymeric binder = $0.217kN\;m^{-1}$ and Si anode based on PVDF polymeric binder = $0.185kN\;m^{-1}$).

Changes in the Optical and Thermal Properties of Low-Temperature Cured Polyimide Thin Films Using the Catalyst (촉매를 이용한 저온경화 폴리이미드 박막의 광학적/열적 특성 변화)

  • Park, Myeong-Soon;Kim, Kwang-In;Nam, Ki-Ho;Han, Haksoo
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.320-326
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    • 2013
  • In this study, various polyimide films were synthesized via low temperature cure in order to understand changes in their physical properties when using 4,4'-oxydianiline (ODA) as a diamine and dianhydride molecules with different backbones on a single diamine such as 4,4'-Oxydiphthalic anhydride (ODPA), 4,4-hexafluoroisopropylidene diphthalic dianhydride (6FDA), and 3,3', 4,4'-benzophenone tetracarboxylic dianhydride (BTDA). After the synthesis of poly(amic acid), polyimide films were fabricated by adding 1,4-diazabicyclo [2.2.2]octane (DABCO), a low-temperature catalyst, at various wt% to poly(amic acid)s. Changes of optical and thermal properties were compared and analyzed between polyimide films without catalyst and polyimide films with catalyst by FT-IR, UV-Vis transmittance, DSC/TGA, and WAXD analysis. Wide-angle X-ray diffraction (WAXD) analysis revealed that the mean intermolecular distance decreased with the use of a catalyst by the type of dianhydride. Thus, while the optical properties of the films improve by a low-temperature cure performed using a catalyst, their thermal properties decrease. These changes can be explained by the changes in the morphological structure of the films triggered by a catalyst-induced reduction in the mean intermolecular distance. Moreover, the results show that the type of dianhydride determines the degree of change in the optical and thermal properties in each types of polyimide, demonstrating that changes in the optical and thermal properties are directly associated with the backbone of the polyimide structure.

Synthesis and Characterization of Soluble Co-polyimides for Biogas Purification (바이오가스 정제용 용해성 폴리이미드 공중합체의 합성과 특성분석)

  • Shin, So Ra;Han, Sang Hoon;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.25 no.3
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    • pp.231-238
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    • 2015
  • Co-polyimide membranes were prepared by two-step polymerization using semi-alicyclic 5-(2,5-dioxotetrahydrofuryl)-3-methyl-cyclohexene-1,2-dicarboxylic anhydride (DOCDA) with five diamines such as 2,5-dimethyl-1,4-phenylene diamine (2M), 2,4,6-trimethyl-1,3-phenylene diamine (3M), 1,5-naphthalene diamine (NDA), 4,4-diaminodiphenyl methane (MDA), 4,4'-diaminodiphenyl ether (ODA). Synthesized co-polyimides were characterized by FT-IR, viscosity, solubility, DSC, TGA and gas permeation properties, compared with 6FDA-based co-polyimides. All co-polyimides had the intrinsic viscosity of 0.32~0.58 and excellent solubility in various solvents. DOCDA-based co-polyimides had thermal stability over $400^{\circ}C$ although those were lower than 6FDA-based co-polyimides. Gas permeabilities of the copolyimide membranes were measured for $CO_2$ and $CH_4$ at room temperature and presented the trade-off relationship.

Gas Separation Properties of Polyaniline/Polyimide Blend Membranes (Polyaniline/Polyimide 혼합막의 기체 분리 특성)

  • Lee, Ki-Seob;Kim, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.483-489
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    • 2007
  • Polyaniline (PANI)/Polyimide (PI) membranes were prepared and the effects of PANI contents and doping on the structural properties and gas separation properties were studied. The polyamic acid (PAA) solution was prepared by the polycondensation reaction of 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) and 4,4'-oxydianiline (ODA) in 1-methyl-2-pyrrolydinone (NMP) solvent. The PANI/PI blends were obtained by mixing PAA solution and PANI solution, and were doped with 1 M aqueous HCl solution for 24 h. The structural characterizations of the as-cast and doped membranes were examined by FT-IR, XRD, and TGA. The gas permeation experiments with $H_2$, $CO_2$, $O_2$, $N_2$, and $CH_4$ were carried out by variable pressure method at $30^{\circ}C$ and 5 atm. For all gases tested, the permeability coefficients of the blends decreased with increasing PANI content and the magnitude of permeability was in the order of $H_2$ > $CO_2$ > $O_2$ > $N_2$ > $CH_4$. The permeability for PANI/PI membranes decreased after the doping process while the permselectivity increased. For $H_2/CH_4$ separation, the doped PANI/PI (75/25) membrane has a permselectivity of 991.

Resudual Stress Behavior and Characterization of Poly(urethane-imide) Crosslinked Networks (가교형 폴리우레탄이미드의 합성을 통한 잔류 응력 거동 측정 및 특성 분석)

  • Park, Mi-Hee;Yang, Seung-Jin;Jang, Wonbong;Han, Haksoo
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.305-312
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    • 2005
  • Poly(urethane-imide)s were prepared by reaction between crosslinkable endgroup containing soluble polyimide (PI) by chemical imidization and acrylate end-capped polyurethane (PU). Poly (amic acid) was prepared from 2,2'-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) and 4,4'-oxydianiline (ODA) and then end-capped with maleic anhydride (MA). The PU prepolymers were prepared by the reaction of polycaprolactone diol, tolylene 2,4-diisocyanate and end-capped with hydroxyl ethyl acrylate. The effect of PU content on the residual stress behavior, morphology and thermal property was studied. The poly(urethane-imide)s were characterized by thin film stress analyzer (TFSA), XRD, TGA and DMTA. Low residual stress and slope in cooling curve were achieved by higher PU content. Compared to typical polyurethane, these polymers exhibited better thermal stability due to the presence of the imide groups. Finally the residual stress of poly(urethane-imide)s was strongly affected by the morphological structure.

Mycelial characteristics for the artificial cultivation of Inonotus obliqua (Pers.) Pilot (차가버섯(Inonotus obliqua) 인공재배를 위한 균사 배양적 특성)

  • 장현유
    • Korean Journal of Plant Resources
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    • v.15 no.2
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    • pp.135-143
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    • 2002
  • The results of examining characteristics of mycelial growth and culture condition for determining the condition of artificially culturing Inonotus obliqua (chaga) are as follows. 1) Mycelial growth and density oft, oblique were the highest in the medium of BDA (Birch Dextrose Agar; 66.3mm/10d) followed by the order of GDA, PDA, CDA, PODA, ODA, YM, MCM, MEA (pH 7.0), CHA, and MEA (pH 4.7). 2) Optimal temperature for the mycelial growth and density of 1. obliqua were shown to be 30$^{\circ}C$, but the mycelia were dead at 40$^{\circ}C$. the mycelial growth and density of KNAC3005 strains was the highest at 30$^{\circ}C$(66.3mm/10d) followed by the order of 25, 20, 15, 35, 10, and 5$^{\circ}C$. 3) Optimal pH for the mycelial growth and density were revealed to be 6.0 (88.4mm/10d). Above or below pH 6.0, the mycelial growth and density were shown to be retarded. 4) Optimal carbon, nitrogen and organic acid sources for the spawn growth of 40 were maltose (331mg/25$m\ell$/15d), peptone (347mg/25$m\ell$/15d), and glutamic acid (357mg/25$m\ell$/15d), respectively. Optimal level of biotin was 370mg/15d and optimal C/N ratio was 40.

A study on Developing Competency-based Curriculum of International Social Welfare (국제사회복지 역량중심 교육과정개발에 관한 연구)

  • Un, Sun Kyoung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.508-518
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    • 2016
  • The purpose of this study was to develop a curriculum for international social workers. Due to the changed circumstances of social welfare agencies, the demand for international social welfare and the need for suitable training for social welfare education agencies has increased. This study explored the job competency of international social welfare and suggested a competency-based curriculum for international social welfare. Researchers analyzed the social welfare NCS, social welfare curriculum and job of international development cooperation agencies and presented a combined curriculum for international development cooperation and social welfare. The findings are as follows: the core subjects of international social welfare are "Human Rights and Social Welfare", "International Social Welfare", NGOs and International Development Cooperation", "the North Korea Development Project", "International Development Cooperation and ODA", "PCM (Project Cycle Management)", "Evaluation and Monitoring", "Seminars in International Social Welfare", "International Social Welfare Practicum", "International Social Welfare Internship", "Community Welfare and Practice", "Program Planning and Evaluation for Social Welfare", "Social Welfare Ethics and Philosophy", "Skills and Techniques for Social Work Practice", "Multicultural Social Welfare", "Poverty and Social Welfare", "Social Enterprise and the Third Sector", "Social Problems", etc.

A Study on the International Research Trend in Education Development focused on Text Network Analysis(2002~2017) (교육개발협력에 관한 국제 학술지 연구 동향 고찰 : 텍스트 네트워크 분석을 중심으로(2002~2017))

  • Kim, Sang-Mi;Kim, Young-Hwan;Cho, Won-Gyeum
    • Korean Journal of Comparative Education
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    • v.28 no.1
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    • pp.1-24
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    • 2018
  • The objective of the article is to find the research trends and the main traits presented in the keywords on abstracts of research articles of "International Journal of Education Development" from 2002 to 2017. To do this, Text Network Analysis(TNA) was applied targeting 966 papers on the journal and the major research outcomes are as follows. First, the frequency analysis on the keywords showed that the keywords like Administration of education program, Schools and instruction, Regional public administration, Educational support service, Elementary education, and Elementary and secondary school were analyzed more than 100 times and also high in centrality degree. Second, the analysis results of the keywords presented in those research articles by development goal periods showed that several new keywords like Elementary education, Elementary and secondary school, Education quality, Secondary education, Educational planning have emerged frequently after SDGs and these keywords showed high in their centrality analysis. Third, the analysis on education level showed that the keywords like Elementary education, Administration of education program, School children were high in frequency and centrality degree in Elementary level. In secondary level, Schools and instruction, Administration of education program, Academic achievement were high, and in high level, college and university was high, respectively.

Development of artificial intelligence-based river flood level prediction model capable of independent self-warning (독립적 자체경보가 가능한 인공지능기반 하천홍수위예측 모형개발)

  • Kim, Sooyoung;Kim, Hyung-Jun;Yoon, Kwang Seok
    • Journal of Korea Water Resources Association
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    • v.54 no.12
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    • pp.1285-1294
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    • 2021
  • In recent years, as rainfall is concentrated and rainfall intensity increases worldwide due to climate change, the scale of flood damage is increasing. Rainfall of a previously unobserved magnitude falls, and the rainy season lasts for a long time on record. In particular, these damages are concentrated in ASEAN countries, and at least 20 million people among ASEAN countries are affected by frequent flooding due to recent sea level rise, typhoons and torrential rain. Korea supports the domestic flood warning system to ASEAN countries through various ODA projects, but the communication network is unstable, so there is a limit to the central control method alone. Therefore, in this study, an artificial intelligence-based flood prediction model was developed to develop an observation station that can observe water level and rainfall, and even predict and warn floods at once at one observation station. Training, validation and testing were carried out for 0.5, 1, 2, 3, and 6 hours of lead time using the rainfall and water level observation data in 10-minute units from 2009 to 2020 at Junjukbi-bridge station of Seolma stream. LSTM was applied to artificial intelligence algorithm. As a result of the study, it showed excellent results in model fit and error for all lead time. In the case of a short arrival time due to a small watershed and a large watershed slope such as Seolma stream, a lead time of 1 hour will show very good prediction results. In addition, it is expected that a longer lead time is possible depending on the size and slope of the watershed.