• Title/Summary/Keyword: O.B.G

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The Reactivity and Regiochemical Effect of Nitrosonium Species in the Nitrosation of N-Methyl-N'-Substituted Phenylureas (N-메틸-N'-치환페닐우레아화합물들의 니트로소화 반응에 있어서 니트로소화 화학종의 반응성 및 위치화학적 영향)

  • Jack C. Kim;In-Seop Cho;Soon-Kyu Choi
    • Journal of the Korean Chemical Society
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    • v.35 no.3
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    • pp.240-248
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    • 1991
  • The regioselectivity in the nitrosation of seven N-methyl-N'-substituted phenylureas ($CH_3NHCONHC_6H_4-G$; G = H, p-CH$_3$, m-CH$_3$, m-CH$_3$O, p-F, m-F, m-Br) was examined using NaNO$_2$ and 4 different acids (diluted HCl, HCOOH, CH$_3$COOH, CF$_3$COOH). In all cases, the two regioisomeric products, N-nitroso-N-methyl-N'-substituted phenylureas (A) and N'-nitroso-N-methyl-N'-substituted phenylureas (B) were observed to be formed as major products and product ratios were determined by the integration of their methyl peaks in $^1$H-NMR. Electron donating substitutent(G) on phenyl of the ureas generally led to increase the ratio of B to A. The data have revealed that the relative sensitivity of the nitrosonium species (HONO, HCOONO, CH$_3$COONO, CF$_3$COONO) toward the change of electron density on nitrogen with phenyl substitutents are 1.00 : 0.93 : 0.78 : > ∼ 0.7.

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Mossbauer Spectroscopy Studies of Garnet $Y_{2.5}La_{0.5}Fe_5O_{12}$ (Garnet $Y_{2.5}La_{0.5}Fe_5O_{12}$의 Mossbauer 분광학 연구)

  • 염영랑;김철성
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.29-34
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    • 1999
  • $Y_{2.5}La_{0.5}Fe_5O_{12}$ is fabricated by a sol-gel method and the magnetic properties of single phase garnet are investigated by using X-ray diffraction, vibrating sample magnetometer, scanning electron microscopy and M$\"{o}$ssbauer spectroscopy. The single phase powders garnet was fired at 100$0^{\circ}C$ for 8 hours. The crystal structures of samples are cubic garnet. Mossbauer spectroscopy were measured from 13 K to 750 K. M$\"{o}$ssbauer spectra show that the iron exist ferric trivalence in sample. The spin wave constants were determined $B_{3/2}=0.32{\pm}0.05,\; C_{5/2}=0.18{\pm}0.05$ and Debye temperature were determined 382 K at 24(d) site and 246 K at 16(a)-site. The saturation magnetization $M_s$ of powder is 25 emu/g. 25 emu/g.

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Study on the Treatment of Hydrogen Chloride Gas used in Semiconductor Process by using Gas Adsorption Agents such as Zeolite Resins, ZnO, and AgMnO3 (제올라이트 수지 및 ZnO, AgMnO3 등의 무기흡착제를 이용한 반도체 공정에서 사용되는 염산가스의 처리 및 측정에 관한 연구)

  • Park, Jeong-Jun;Lim, H.B.;Hwang, Cheong-Soo
    • Analytical Science and Technology
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    • v.16 no.3
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    • pp.218-225
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    • 2003
  • Hydrogen Chloride is among the most problematic gases used in semiconductor process. It raises serious environmental and health problems due to its extreme toxicity. This study is to develop a method to effectively remove hydrogen chloride gas during the process by using various types of inorganic gas adsorption agents, which have not been attempted in the conventional methods. The removal efficiency of the gas was both qualitatively and quantitatively measured by a FT-IR spectrophotometer. The whole device for the measurement has been designed and built in our lab. The removal efficiencies of hydrogen chloride gas were compared between those tested resins; zeolite A, modified AgA zeolite, ZnO, and $AgMnO_3$. The experimental result revealed that ZnO showed the best efficiency that had removed 0.067 g of HCl per 1 g of the resin used.

The fabrication of microwave circulator using polycrystalline $Y_{2.4}Ca_{0.3}Sn_{0.3}Fe_{5-x}Al_xO_{12}$ garnets (다결정 $Y_{2.4}Ca_{0.3}Sn_{0.3}Fe_{5-x}Al_xO_{12}$ 가네트 자성체를 이용한 마이크로파대 서큘레이터 구현)

  • 박정래;김태홍;김명수;한진우
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.22 no.11
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    • pp.2573-2584
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    • 1997
  • In this paper, Ca, Sn substitute YIC(Yttrium Iron Garnet) ceramics were fabricated with Al substitutions in Fe sites. The strip-line circulator was designed and the properties of fabricated ciculator were measured. When the electric, magnetic and microwave properties were measured in Ca, Sn substituted YIG with Al subsititions, the relative permittivity and perfmeability in microwave frequencies were 15.623 and 0.972, repectively. For $Y_{2.4}Ca_{0.3}Sn_{0.3}Fe_{5-x}Al_xO_{12}$ garnet ceramics sintered at $1450^{\circ}C$, the ferrimagnetic resonance line width $\Delta{H}$) of 42 Oe and the saturation magnetization of 487 G were measured at 10 GHz. The strip-line circulator was simulated with 3-D FEM(Finite Element Method) software and designed to have insertion loss of 0.8dB, return loss of 25dB, isolation of 35dB at the center frequency of 1.9GHz. The fabricated strition loss of 0.8B, reture loss of 25dB, isolation of 35dB at the center frequency of 1.9GHz. The fabricated strip-line junction circulator using above YIG ceramics had insertion loss of 0.869dB, return loss of 26.955dB, isolation of 44.409dB at the center frequency of 1.9GHz.

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An effective immunoaffinity clean-up method for multi-DDT residue analysis

  • Hong, Ji-Youn;Hong, Jee-Eun;Lee, Eun-Ah;Park, Song-Ja;Lho, Dong-Seok;Kim, Jong-Hyun;Choi, Myung-Ja
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.290.3-291
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    • 2003
  • To increase detection sensitivity for multi-DDT residues (o,p-/p,p-DDT, o,p-/p,p-DDE, o,o-/o,p-DDD) analysis, a highly selective sample clean-up method was introduced prior to GC/MS analysis using immunoaffinity column. The immunoaffinity matrix was prepared by coupling IgG fraction of DDT antiserum to cyanogens bromide activated Sepharose 4B. Three DDT antisera (DDA-1, DDHP-2, DDCP-3) were test for affinity column ligand that obtained by imunizing respective DDT immunogen to rabbits, and IgG was purified using protein A affinity purification. (omitted)

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Comparison of Common Enrichment Methods for Recovery of Yersinia Enterocolitica from Artificially Inoculated Swine Feed Samples

  • Kim, Joo-Sung;Draughon, F.A.
    • Journal of Food Hygiene and Safety
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    • v.25 no.4
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    • pp.320-324
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    • 2010
  • Five different enrichment methods were studied to find an optimal method to recover Yersinia enterocolitica from swine feed samples. When the recovery of Y. enterocolitica GER-C (serotype O:3) strain was studied at 1000 CFU/g feed, phosphate-buffered saline (PBS) enrichment at $4^{\circ}C$ and PBS plus sorbitol and bile salts (PSB) enrichment at $4^{\circ}C$ and $21^{\circ}C$ were not effective (< 22%). In contrast, both irgasan-ticarcillin-potassium chlorate (ITC) and tryptic soy broth plus polymyxin B sulfate and novobiocin (TSBPN) enrichment methods showed a full recovery (100%) at 100-1000 CFU/g feed. At 10 CFU/g feed, both ITC and TSBPN methods still recovered the strain (> 50%). In recovery of ATCC 9610 (serotype O:8) strain, TSBPN method was more sensitive than any other methods (P < 0.05) at 1000 CFU/g feed. Using TSBPN method, the strain was still recovered at 100 CFU/g feed, but not at 10 CFU/g feed. With its sensitivity and relatively simple recipe, TSBPN was most desirable method to recover Y. enterocolitica from swine feed samples.

Floral Image Make-up - Centered on Georgia O'Keeffe's Paintings - (Floral Image Make-up에 관한 연구 - 조지아 오키프(Georgia O'Keeffe)의 작품을 중심으로 -)

  • Kim, Hyo-Sook;Kang, In-Ae
    • Journal of the Korean Home Economics Association
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    • v.43 no.11 s.213
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    • pp.97-107
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    • 2005
  • Ed- the file appears to be corrupted, and in many sections (these are highlighted) I cannot read it. I presume it has been copied from another format, maybe Hangul 2004. The purpose of this study was to determine a method of make-up image extraction from specific paintings and also to create cyber make-up models according to the images. For this study, Georgia O'Keeffee's floral paintings were analyzed and their colors were compiled to make color palettes. This study attempted to approach floral image make-up which applies specific paintings through the digital mode in the manner of computer graphics. The results of this study were as follows: First, we found romantic images, including feminine, lovely and soft images by Y, GY and RP group colors, in 'Two Calla Lillies on Pink'. Second, we found modem images, including urban, up-to-date and cool images by G, GY and B group colors, in 'Blue and Green Music'. Third, we found sexy images, including brilliant, tempting and daring by R, B and G group colors, in 'Music-Pink and Blue'. To summarize, the images of the paintings were similar to those of the make-up models.

Procyanidins from Acer komarovii Bark

  • Lee, Tae-Sung;Kwon, Dong-Joo;Bae, Young-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.2
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    • pp.214-223
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    • 2015
  • The bark of Acer komarovii was collected, ground, and extracted with 70% aqueous acetone to obtain concentrates. The concentrates were suspended in $H_2O$, and then successively partitioned with n-hexane, dichloromethane and ethylacetate to be freeze dried. A portion of ethylacetate fraction was chromatographed on a Sephadex LH-20 and a RP C-18 column with various aqueous MeOH-$H_2O$ (1:0, 1:1, 1:2, 1:5, 1:7, 1:9, 1:10, 3:1, and 4:1, v/v) eluents. Four compounds were isolated; (-)-epicatechin (9.6 g), procyanidin A2 (epicatechin-($4{\beta}{\rightarrow}8$, $2{\beta}{\rightarrow}O{\rightarrow}7$)-epicatechin) (1.3 g), procyanidin B2 (epicatechin-($4{\beta}{\rightarrow}8$)-epicatechin) (40.0 mg), and cinnamtannin B1 (epicatechin-($4{\beta}{\rightarrow}8$, $2{\beta}{\rightarrow}O{\rightarrow}7$)-epicatechin-($4{\beta}{\rightarrow}8$)-epicatechin) (690 mg). The analysis of the bark procyanidins showed that the basic unit constituting condensed tannins was only (-)-epicatechin. This study, for the first time, report the procyanidins of Acer komarovii bark.

Synthesis of Nucleophilic Adducts of Thiols (Ⅳ). Addition of Glutathione to $\beta$-Nitrostyrene Derivatives

  • Kim, Tae-Rin;Choi, Sung-Yong;Choi, Won-Sik
    • Bulletin of the Korean Chemical Society
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    • v.4 no.2
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    • pp.92-95
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    • 1983
  • The addition products of glutathione to ${\beta}$ -nitrostyrene derivatives were synthesized. ${\beta}$ -Nitrostyrene (1a), p-methyl-${\beta}$-nitrostyrene (1b), 3,4,5-trimethoxy-${\beta}$-nitrostyrene (1c), o-, m- and p-chloro-${\beta}$-nitrostyrene (1e, 1f, 1g) and o-, m- and p-methoxy-${\beta}$-nitrostyrene (1h, 1i, 1j) undergo addition reactions with glutathione to form S-(2-nitro-1-phenylethyl)-L-glutathione (5a), S-[2-nitro-1-(p-methyl)phenylethyl]-L-glutatione (5b), S-[2-nitro-1-(3', 4', 5'-trimethoxy)phenylethyl]-L-glutathione (5c), S-[2-nitro-1-(o-chloro)phenylethyl]-L-glutathione (5e), S-[2-nitro-1-(m-choro)phenylethyl]-L-glutathione (5f), S-[2-nitro-1-(p-chloro)phenylethyl]-L-glutathione (5g), S-[2-nitro-x-(o-methoxy)-phenylethyl]-L-glutathion e(5h), S-[2-nitro-x-(m-methoxy)phenylethyl]-L-glutathion e (5i), and S-[2-nitro-1-(p-methoxy)phenylethy])-L-glutathione (5j), respectively. The structure of adducts were identified by UV and IR-spectra, molecular weight measurement, and elemental analysis.