• Title/Summary/Keyword: O:N ratio

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Novel SAW-based pressure sensor on $41^{\circ}YX\;LiNbO_3$ ($41^{\circ}YX\;LiNbO_3$ 기반 SAW 압력센서 개발)

  • Wang, Wen;Lee, Kee-Keun;Hwang, Jung-Soo;Kim, Gen-Young;Yang, Sang-Sik
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.1 s.343
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    • pp.33-40
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    • 2006
  • This paper presents a novel surface acoustic wave (SAW)-based pressure sensor, which is composed of single phase unidirectional transducer (SPUDT), three reflectors, and a deep etched substrate for bonding underneath the diaphragm. Using the coupling of modes (COM) theory, the SAW device was simulated, and the optimized design parameters were extracted. Finite Element Methods (FEM) was utilized to calculate the bending and stress/strain distribution on the diaphragm under a given pressure. Using extracted optimal design parameters, a 440 MHz reflective delay line on 41o YX LiNbO3 was developed. High S/N ratio, shan reflection peaks, and small spurious peaks were observed. The measured S11 results showed a good agreement with simulated results obtained from coupling-of-modes (COM) modeling and Finite Element Method (FEM) analysis.

Synthesis of Titanium Dioxides by Microemulsion Method and Their Photocatalytic Degradation of p-Nitrophenol (마이크로에멀젼법에 의한 이산화티탄의 합성 및 p-Nitrophenol의 광촉매 분해반응)

  • Jung, Won Young;Han, Yeon Hee;Lee, Gun-Dae;Park, Seong Soo;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.351-356
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    • 2008
  • Titania nanoparticles were prepared by controlled hydrolysis of titanium tetraisopropoxide (TTIP) in water-in-oil (W/O) and microemulsion stabilized with a nonionic surfactant, N P-10 (Polyoxyethylene Nonylphenol Ether: $C_9H_{19}C_6H_4(OCH_2CH_2)_{10}OH$)). The nanosized particles prepared in W/O microemulsion were characterized by FT-IR, TEM, XRD, TGA, and DTA. In addition, the photocatalytic degradation of p-nitrophenol has been studied by using a batch reactor in the presence of UV light in order to compare the photocatalytic activity of prepared nanosized titania. The nanaosized titania particles calcined at $300{\sim}600^{\circ}C$ showed an anatase structure, but it transformed to a rutile phase above $700^{\circ}C$ of calacination temperature. With an increase of $W_o$ ratio, the crystallite size increased but photocalytic activity decreased. The titania synthesized at $W_o=5$, R = 2, and calcined at $400{\sim}500^{\circ}C$ showed the highest activity on the photocatalytic degradation of p-nitrophenol.

Petrology and Geochemistry of Peridotite Xenoliths from Miocene Alkaline Basalt Near the Mt. Baekdu Area (백두산 지역의 마이오세 알칼리 현무암에 포획된 페리도타이트의 암석학적/지화학적 특성)

  • Kim, Eunju;Park, Geunyeong;Kim, Sunwoong;Kil, Youngwoo;Yang, Kyounghee
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.311-325
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    • 2017
  • Peridotite xenoliths in middle Miocene alkaline basalt from the Mt. Baekdu area are mainly anhydrous spinel lherzolites, displaying coarse-grained protogranular texture. These xenoliths have late-stage secondary orthopyroxene replacing olivine as the metasomatic mineral and glass formed along the grain boundaries. The studied xenoliths are characterized by the high $Mg{\sharp}[=100{\times}Mg/(Mg+Fe_{total})$ atomic ratio] of olivine, orthopyroxene and clinopyroxene (89~92) and the $Cr{\sharp}[=100{\times}Cr/(Cr+Al)$ atomic ratio] of spinel (10~29). Based on major-element data, the studied xenoliths are similar to those from the abyssal peridotites. Clinopyroxenes of the xenoliths are mostly enriched in incompatible trace elements, exhibiting two types of REE patterns: (1) LREE-depleted with $(La/Yb)_N$ of 0.1~0.2 and $(La/Ce)_N$ of 0.4~0.8. (2) LREE enriched with $(La/Yb)_N$ of 2.2~3.8 and $(La/Ce)_N$ of 1.2~1.6. The calculated equilibrium temperatures and oxygen fugacities resulted in $920{\sim}1050^{\circ}C$ and ${\Delta}fO_2(QFM)=-0.8{\sim}0.2$, respectively. It is suggested that the Mt. Baekdu peridotite xenoliths represent residues left after variable degrees of melt extraction(less than 15 vol%), which was subsequently subjected to different degrees of modal/cryptic metasomatism by silica- and LREE-enriched fluids (or melts).

Dielectric and Piezoelectric Characteristics of PMW-PNN-PT-PZ Ceramics with addiction of MnO$_2$ (MnO$_2$가 첨가된 PMW-PNN-PT-PZ계 세라믹스의 유전 및 압전 특성)

  • 박석환;윤광희;박정흠;김현재;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.63-67
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    • 1996
  • In this paper, effect of MnO$_2$ addition(0, 0.1, 0.2, 0.3, 0.5wt%) on the microstructure, dielectric and piezoelectric properties of [xPMW - (0.15-x) PNN] - [yPT-(0.85-y)PZ] (x=0, 0.01, 0.02, 0.03, 0.05, y = 0.35, 0.40, ().425, 0.45, 0.5) were investigated. When Ti/Zr ratio was 1.0, dielectric and piezoelectric properties were highest value. With PMW 2mol%, dielectric constant, dielectric constant (d$\_$33/, d$\_$31/) and electromechanical coupling factor (kp, k$\_$31/) were highest values of 1995, 479, 186(x10$\^$-12/C/N), 0.61, 0.36, respectively. With the addition of MnO$_2$, dielectric constant, electromechanical coupling factor (kp, k$\_$31/) were decreased, but with 0.3wt% MnO$_2$, eletromechanical coupling factor was highest value of 0.63. With the addition of MnO$_2$, mechanical quality(Q$\_$m/ was increased.

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Development of Inorganic Metal Oxide based Hole-Transporting Layer for High Efficiency Perovskite Solar Cell (고효율 페로브스카이트 태양전지용 무기 금속 산화물 기반 정공수송층의 개발)

  • Lee, Haram;Mai, Cuc Thi Kim;Jang, Yoon Hee;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.8 no.2
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    • pp.60-65
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    • 2020
  • In perovskite solar cells with planar heterojunction configuration, selection of proper charge-transporting layers is very important to achieve stable and efficient device. Here, we developed solution processible Cu doped NiOx (Cu:NiOx) thin film as a hole-transporting layer (HTL) in p-i-n structured methylammonium lead trihalide (MAPbI3) perovskite solar cell. The transmittance and thickness of NiOx HTL is optimized by control the spin-coating rate and Cu is additionally doped to improve the surface morphology of undoped NiOx thin film and hole-extraction properties. Consequently, a perovskite solar cell containing Cu:NiOx HTL with optimal doping ratio of Cu exhibits a power conversion efficiency of 14.6%.

Piezoelectric Characteristics of Pb($Mg_{1/3}Nb_{2/3}$)$O_3$+ PZT Ceramics for Substrates of High-Frequency Devices (고주파소자의 기판용 Pb($Mg_{1/3}Nb_{2/3}$)$O_3$+ PZT 세라믹스의 압전특성)

  • 이개명;장낙원;김준한;이두희;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.60-64
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    • 1990
  • In this studies, structural, dielectrical piezoelectrical properties and temperature stability of 0.05Pb(Pb($Mg_{1/3}Nb_{2/3}$)$O_3$+ 0.95Pb($Zr_{0.53}Tio_{0.47}$)$O_3$+$\alpha$[wt%] $Cr_2O_3$ piezoelectric ceramics fabricated by the Hot-Press method were investigated. And Poisson ratios of the specimens were measured in order to see that they can be used as the substrates for energy-trapped devices. The specimens of which Poisson ratio was more than 3/1 had the $\alpha$ range 0.3~0.75, and piezoelectric properties were degraded in the range $\alpha$$\geq$0.75, and temperature stability was good in the $\alpha$ range 0.5~0.75. Accordingly, the optimal point of $Cr_2O_3$ additive weight is sure to be in the vicinity of 0.5[wt%].

Characteristics of Silicon Rich Oxide by PECVD (PECVD에 의한 Sirich 산화막의 특성)

  • Gang, Seon-Hwa;Lee, Sang-Gyu;Park, Hong-Rak;Go, Cheol-Gi;Choe, Su-Han
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.459-465
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    • 1993
  • By making the inter-metal PECVD $SiO_2$ as a Si rich oxide under the SOG, the hydrogen and water related diffusants could be captured a t SI dangling bonds. This gettering process was known to prevent the device characteristics degradations related to the H, $H_20$. The basic characteristics of Si rich oxide have been studied according to changing high/low frequency power and $SiH_4/N_2O$ gas flow ratio in PECVD. As increase in low frequency power, deposition rate decreased but K.I. and compressive stress increased. Decrease of the water peaks of FTIR spectra at the wave number range of 3300~3800$\textrm{cm}^{-1}$' also indicated that intensty the films were densified. As increase in SiH, gas flow rate, deposition rate, R.I. and etch rate increased while compressive stress decreased. F'TIK spectra showed that peak intensity corresponding to Si-0-Si stretching vibration decreased and shifted to the lower wave numbers. But AES showed that Si dangl~ng bonds were increased as a result of lower Si:O(l: 1.23) ratlo inthe Si rich oxide as compared to Si : O(1 : 1.98) ratio of usual oxide.

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Effects of $La_2O_3$, $MnO_2$ on the Dielectric and Piezoelectric Properties of $0.02Pb(Y_{2/3}W_{1/3}O_3-0.98Pb(Zr_{0.52}Ti_{0.48})O_3$ ($La_2O_3$$MnO_2$$0.02Pb(Y_{2/3}W_{1/3}O_3-0.98Pb(Zr_{0.52}Ti_{0.48})O_3$의 유전 및 압전 특성에 미치는 영향)

  • 윤석진;류소연;문종하;김현재;오상록;이종원;정형진
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.378-384
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    • 1995
  • Effects of $La_2O_3$, $MnO_2$ on the dielectric and piezoelectric properties of $0.02Pb(Y_{2/3}W_{1/3}O_3-0.98Pb(Zr_{0.52}Ti_{0.48})O_3$ system were investigated. The addition of La2O3 to the system enhanced electromechanical coupling factor (kp), piezoelectric constant (d33), but hardly changed mechanical quality factor (Qm). On the other hand, the addition of $MnO_2$ increased Qm significantly, but did not degrade kp and d33 so much. The piezoelectric properties of $0.02Pb(Y_{2/3}W_{1/3}O_3-0.98Pb(Zr_{0.52}Ti_{0.48})O_3$ containing 0.1wt% $La_2O_3$, 0.4wt% $MnO_2$ were very good and kp, d33, Qm were 55%, 350$\times$10-12C/N, 780, respectively. The size of the grains was proportional to the change of c/a (tetragonality) ratio caused by the addition of $La_2O_3$ and $MnO_2$, and dielectric, piezoelectric properties were sensitive to the amountof pyrochrole phase.

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Electrodeposited Ni-W-Si3N4 alloy composite coatings: Evaluation of Scratch test

  • Gyawali, Gobinda;Joshi, Bhupendra;Tripathi, Khagendra;Lee, Soo Wohn
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.178-179
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    • 2014
  • In this study, $Ni-W-Si_3N_4$ alloy composite coatings were prepared by pulse electrodeposition method using nickel sulfate bath with different contents of tungsten source, $Na_2WO_4.2H_2O$, and dispersed $Si_3N_4$ nano particles. The structure and microstructure ofcoatings was separately analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). Results indicated that nano $Si_3N_4$ and W content in alloy had remarkable effect on microstructure, microhardness and scratch resistant properties. Tungsten content in Ni-W and $Ni-W-Si_3N_4$ alloy ranged from 7 to 14 at.%. Scratch test results suggest that as compared to Ni-W only, $Ni-W-Si_3N_4$ prepared from Ni/W molar ratio of 1:1.5 dispersed with 20 g/L $Si_3N_4$ has shown the best result among different samples.

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Electrodeposition and characterization of Ni-W-Si3N4 alloy composite coatings

  • Choi, Jinhyuk;Gyawali, Gobinda;Lee, Soo Wohn
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.171-172
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    • 2015
  • $Ni-W-Si_3N_4$ alloy composite coatings were prepared by pulse electro-deposition method using nickel sulfate bath with different contents of tungsten source, $Na_2WO_4.2H_2O$, and dispersed $Si_3N_4$ nano-particles. The structure and micro-structure of coatings was separately analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). Results indicated that nano $Si_3N_4$ and W content in alloy had remarkable effect on micro-structure, micro-hardness and scratch resistant properties. Tungsten content in Ni-W and $Ni-W-Si_3N_4$ alloy ranged from 7 to 14 at.%. Scratch test results suggest that as compared to Ni-W only, $Ni-W-Si_3N_4$ prepared from Ni/W molar ratio of 1:1.5 dispersed with 20 g/L $Si_3N_4$ has shown the best result among different samples.

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