• Title/Summary/Keyword: Nuclear magnetic resonance

Search Result 859, Processing Time 0.031 seconds

Mini-review on fabrication of nitrogen vacancy center in diamond and its application to NMR

  • Oh, Sangwon
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.23 no.3
    • /
    • pp.73-80
    • /
    • 2019
  • Nitrogen-vacancy (NV) is one of the most popular solid-state spin systems for quantum sensing. NV has been used for vector magnetometry with nanometer spatial resolution and sensors for nuclear magnetic resonance (NMR) in samples with small volume, less than 10 pL. Various studies are in progress to make NV a complementary sensor for current NMR technique. Fabricating and improving diamond itself are one of the research topics. This mini-review contains recent develops in diamond fabrication and treatment for higher NV yield. Additionally, we briefly introduce the development status of NV in NMR.

Calculation of electric field gradient tensor for simple point charge distributions and its application to real systems

  • Choh, Sung-Ho;Shin, Hee-Won;Park, II-Woo;Ju, Heong-Kyu;Kim, Jong-Hyun;Kim, Hae-Jin
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.7 no.1
    • /
    • pp.16-24
    • /
    • 2003
  • Nuclei with the spin quantum number not smaller than unity have not only the nuclear magnetic moment but also the electric quadrupole moment. The quadrupole moment couples with the electric field gradient (EFG) to produce the nuclear quadrupole interaction. It is well known that two independent parameters, i.e. the quadrupole coupling constant (QCC) and the asymmetry parameter ($\eta$) together with the principal axis directions can fully describe the interaction and are very sensitive to the local symmetry and structure of the solid. In order to obtain quantitative estimates of the EFG tensor for various simple ionic configurations surrounding the nucleus under consideration, we employ the simple point charge approximation and apply the calculated results to some real crystals. General agreement is rather satisfactory.

  • PDF

Application of NMR to Magnet Study (자성 연구에 있어서의 핵자기공명의 쓸모)

  • Lee, Soon-Chil
    • Journal of the Korean Magnetics Society
    • /
    • v.20 no.2
    • /
    • pp.68-74
    • /
    • 2010
  • Nuclear Magnetic Resonance (NMR) is a very useful tool for magnet study because it provides information on local spin environment. The valence of magnetic ions, spin canting angle, orbital state can be measured by NMR and the information on the position of the ions and the change of domains and domain walls can be obtained. The principle of operation is discussed with corresponding application examples.

Production of Hyperpolarized 129Xe Using Spin Exchange Optical Pumping

  • Kavtanyuk, Vladimir Vladimirovich;Kim, Wooyoung;Ando, Yu;Chebotaryov, Sergey;Seon, Yonggeun;Tan, Joshua Artem
    • Journal of the Korean Physical Society
    • /
    • v.73 no.10
    • /
    • pp.1458-1465
    • /
    • 2018
  • We present a constructed setup for polarizing $^{129}Xe$ noble gas. Hyperpolarized $^{129}Xe$ has been obtained via spin exchange with an optically pumped rubidium vapor. Optical pumping is based on polarizing the valence electron of rubidium by the resonant absorption of a circularly polarized laser light. The magnetic field of 30 G was used for obtaining $^{129}Xe$ polarization. The apparatus for detecting polarization is a nuclear magnetic resonance spectrometer. The highest $^{129}Xe$ polarization of 54% has been obtained using 60 W circularly polarized laser light with wavelength of 794.7 nm. The measured longitudinal relaxation time of the hyperpolarized $^{129}Xe$ was 72.3 minutes.

Nucleus-phonon interactions of MCsSO4 (M = Na, K, or Rb) single crystals studied using spin-lattice relaxation time

  • Choi, Jae Hun;Kim, Nam Hee;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.18 no.1
    • /
    • pp.15-23
    • /
    • 2014
  • The structural properties and relaxation processes of $MCsSO_4$ (M = Na, K, or Rb) crystals were investigated by measuring the NMR spectra and spin-lattice relaxation rates $1/T_1$ of their $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei. According to the NMR spectra, the $MCsSO_4$ crystals contain two crystallographically inequivalent sites each for the M and Cs ions. Further, the relaxation rates of all these nuclei do not change significantly over the investigated temperature range, indicating that no phase transitions occur in these crystals in this range. The variations in the $1/T_1$ values of the $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei in these three crystals with increasing temperature are approximately proportional to $T^2$, indicating that Raman processes may be responsible for the relaxation. Therefore, for nuclear quadrupole relaxation of the $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei, Raman processes with n = 2 are more effective than direct processes.

Preliminary Study on Magnetic Resonance Temperature Measurement using Brain-Metabolite Phantom (뇌 대사물질 팬텀을 이용한 뇌의 자기공명 온도측정법에 관한 기초 연구)

  • Han, Yong-Hee;Jang, Moo-Young;Mun, Chi-Woong
    • Journal of Biomedical Engineering Research
    • /
    • v.31 no.5
    • /
    • pp.412-416
    • /
    • 2010
  • In this study, we measured the chemical shift change of metabolite peaks in the brain-metabolite phantom according to the temperature variation using nuclear magnetic resonance(NMR). The temperature range in NMR system was controled from 25 to 80 (5 step) by internal temperature controller. Temperature coefficients of each metabolite peaks were also calculated from the measured chemical shift depending on the temperature. The chemical shift changes depending on temperature were validated by linear regression method for each metabolite peaks. The temperature coefficients of $_{tot}Cr$, Cho, Cr, NAA, and Lac were 0.0086, 0.0088, 0.0091, 0.0089, and 0.0088ppm/$^{\circ}C$, respectively. This study shows that chemical shift change of brain metabolite and temperature variation have linear relationship each other. This also makes authors believe that brain temperature measurement is possible using MR spectroscopic imaging technique.