• 제목/요약/키워드: Novel metal

검색결과 638건 처리시간 0.034초

Novel Group 9 Metal Complexes Containing an S,S'-Chelating o-Carboranyl Ligand System: Synthesis, Crystal Structures, and Electrochemical Properties of Dinuclear [{(cod)M}2(S,S'-S2C2B10H10)] (cod = 1,5-cyclooctadiene;M = Rh OR Ir)] and Mononclear Cp*CoI[S,S'-S(S=PMe2)C2B10H10] Metal Complexs

  • Lee, Jong-Dae;Kim, Bo-Young;Lee, Chong-Mok;Lee, Young-Joo;Ko, Jae-Jung;Kang, Sang-Ook
    • Bulletin of the Korean Chemical Society
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    • 제25권7호
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    • pp.1012-1019
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    • 2004
  • The synthesis of novel group 9 metal complexes containing the S,S'-chelate ligands, $Li_2S_2C_2B_{10}H_{10}$ (2a) and $LiS(S=PMe_2)C_2B_{10}H_{10$} (2b), is described. Two new dinuclear complexes of the type $[{(cod)M}_2(S,S'-S_2C_2B_{10}H_{10})]$ (cod = 1,5-cyclooctadiene; M = Rh (3a), or Ir (3b)) were synthesized by the reaction of chloridebridged dimers $[M({\mu}-Cl)(cod)]_2$ with one molar equivalent of the corresponding dilithium dithiolato ligand $Li_2S_2C_2B_{10}H_{10}$ (2a). X-ray crystal structure analysis of 3a revealed a dinuclear structure in which each (cod)Rh unit is attached to a distinct sulfur atom of a 1,2-dithio-o-carboranyl ligand (2a). Additionally, the electrochemical properties of 3a and 3b were investigated by cyclic voltammetry. In an analogous manner, reaction of the lithium dithiolato ligand $LiS(S=PMe_2)C_2B_{10}H_{10}$ (2b) with $Cp^{\ast}CoI_2(CO)$ produced a mononuclear dithiolato complex, $[Cp^{\ast}CoI{(S,S'-S(S=PMe_2)C_2B_{10}H_{10})}]$ (4), which was characterized by single-crystal X-ray analysis.

Improved Plasmonic Filter, Ultra-Compact Demultiplexer, and Splitter

  • Rahimzadegan, Aso;Granpayeh, Nosrat;Hosseini, Seyyed Poorya
    • Journal of the Optical Society of Korea
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    • 제18권3호
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    • pp.261-273
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    • 2014
  • In this paper, metal insulator metal (MIM) plasmonic slot cavity narrow band-pass filters (NBPFs) are studied. The metal and dielectric of the structures are silver (Ag) and air, respectively. To improve the quality factor and attenuation range, two novel NBPFs based on tapered structures and double cavity systems are proposed and numerically analyzed by using the two-dimensional (2-D) finite difference time domain (FDTD) method. The impact of different parameters on the transmission spectrum is scrutinized. We have shown that increasing the cavities' lengths increases the resonance wavelength in a linear relationship, and also increases the quality factor, and simultaneously the attenuation of the wave transmitted through the cavities. Furthermore, increasing the slope of tapers of the input and output waveguides decreases attenuation of the wave transmitted through the waveguide, but simultaneously decreases the quality factor, hence there should be a trade-off between loss and quality factor. However, the idea of adding tapers to the waveguides' discontinuities of the simple structure helps us to improve the device total performance, such as quality factor for the single cavity and attenuation range for the double cavity. According to the proposed NBPFs, two, three, and four-port power splitters functioning at 1320 nm and novel ultra-compact two-wavelength and triple-wavelength demultiplexers in the range of 1300-1550 nm are proposed and the impacts of different parameters on their performances are numerically investigated. The idea of using tapered waveguides at the structure discontinuities facilitates the design of ultra-compact demultiplexers and splitters.

Role of edge patterning and metal contact for extremely low contact resistance on graphene

  • Jo, Seo-Hyeon;Park, Hyung-Youl;Park, Jin-Hong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.294.2-294.2
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    • 2016
  • Graphene, a sigle atomic layered structure of graphite, has drawn many scientific interests for attractive future electronics and optoelectronics beyond silicon-based technology because of its robust physical, optical, and electrical properties. But high metal-graphene contact resistance prevents the successful integration of high speed graphene devices and circuits, although pristine graphene is known to have a novel carrier transport property. Meanwhile, in the recently reported metal-graphene contact studies, there are many attempts to reduce the metal-graphene contact resistance, such as doping and one-dimensional edge contact. However, there is a lack of quantitative analysis of the edge contact scheme through variously designed patterns with different metal contact. We first investigate the effets of edge contact (metal-graphene interface) on the contact resistance in terms of edge pattern design through patterning (photolithography + plasma etching) and electral measurements. Where the contact resistance is determined using the transfer length method (TLM). Finally, we research the role of metal-kind (Palladium, Copper, and Tianium) on the contact resistance through the edge-contacted devices, eventually minimizing contact resistance down to approximately $23{\Omega}{\cdot}{\mu}m$ at room temperature (approximately $19{\Omega}{\cdot}{\mu}m$ at 100 K).

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Novel Water-Soluble Polyfluorenes as an Interfacial layer leading to Cathodes-Independent High Performance of Organic Solar Cells

  • 오승환;심희상;박동원;정연길;이재광;문승현;김동유
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.394-394
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    • 2009
  • Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the polymer light-emitting diode and new materials for nano and micro hollow-capsules, and bio- or chemo-sensors. We synthesized neutral polyfluorenes containing bromo-alkyl groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl side groups in neutral polyfluorenes were quaternized by tri-methyl amine solution. The electrochemical and optical properties of water-soluble conjugated polymers are discussed. This novel synthesized water-soluble conjugated polymers were used as a interfacial dipole layer between active layer and metal cathode in polymer solar cell for enhancement of open-circuit voltage (Voc), which is one of the most critical factors in determining device characteristics. We also investigated the device performance of polymer solar cell with different metal cathode such as Al, Ag, Au and Cu. In polymer solar cell, novel cationic water-soluble conjugated polymers were inserted between active layer and high-work function cathode (Al, Ag, Au and Cu).

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지반주입용 활성 실리케이트 약액 (ASG) 의 개발 및 적용 (Development and Application of Activated Silicate for Chemical Grouting)

  • 천병식;류동성;조산연
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 1999년도 가을 학술발표회 논문집
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    • pp.131-136
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    • 1999
  • In this study, novel activated silicate grout solution for injection grouting was prepared by the reaction of ordinary waterglass with alkaline earth metal salts mixture by means of the high-speed stirring method with strong shearing force, and its chemical and physical properties were investigated. The variation of its gelation time plotted with the amount of dilution water showed that this novel silicate had better gelation characteristics in comparison with ordinary waterglass. And some other engineering characteristics of this grout such as durability and mechanical properties were investigated experimentally. The whole experimental results established that this novel silicate grout was a good alternative with an existing ordinary waterglass grouting method.

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신문지 재활용 공정의 이차 점착성 이물질 정량을 위한 새로운 방법 (Novel Method for the Measurement of Secondary Stickies in Process Water of Newspaper Recycling Mill)

  • 박진성;류정용;김용환;송봉근
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2002년도 춘계학술발표논문집
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    • pp.34-45
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    • 2002
  • The new measuring method of micro-stickies considering both the effects of charge neutralization and evaporation of process water was developed by KRICT PPRC. By the new KRICT method, the contamination of metal dryer surface and other machine clothes could be estimated quickly and simultaneously. According to this study, it could be confirmed that the novel method is a useful one for the evaluation of several treatments regarding the reduction of stickies troubles.

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