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http://dx.doi.org/10.5012/bkcs.2004.25.7.1012

Novel Group 9 Metal Complexes Containing an S,S'-Chelating o-Carboranyl Ligand System: Synthesis, Crystal Structures, and Electrochemical Properties of Dinuclear [{(cod)M}2(S,S'-S2C2B10H10)] (cod = 1,5-cyclooctadiene;M = Rh OR Ir)] and Mononclear Cp*CoI[S,S'-S(S=PMe2)C2B10H10] Metal Complexs  

Lee, Jong-Dae (Department of Chemistry, Korea University)
Kim, Bo-Young (Department of Chemistry, Ewha Womans University)
Lee, Chong-Mok (Department of Chemistry, Ewha Womans University)
Lee, Young-Joo (Department of Chemistry, Korea University)
Ko, Jae-Jung (Department of Chemistry, Korea University)
Kang, Sang-Ook (Department of Chemistry, Korea University)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.7, 2004 , pp. 1012-1019 More about this Journal
Abstract
The synthesis of novel group 9 metal complexes containing the S,S'-chelate ligands, $Li_2S_2C_2B_{10}H_{10}$ (2a) and $LiS(S=PMe_2)C_2B_{10}H_{10$} (2b), is described. Two new dinuclear complexes of the type $[{(cod)M}_2(S,S (cod = 1,5-cyclooctadiene; M = Rh (3a), or Ir (3b)) were synthesized by the reaction of chloridebridged dimers $[M({\mu}-Cl)(cod)]_2$ with one molar equivalent of the corresponding dilithium dithiolato ligand $Li_2S_2C_2B_{10}H_{10}$ (2a). X-ray crystal structure analysis of 3a revealed a dinuclear structure in which each (cod)Rh unit is attached to a distinct sulfur atom of a 1,2-dithio-o-carboranyl ligand (2a). Additionally, the electrochemical properties of 3a and 3b were investigated by cyclic voltammetry. In an analogous manner, reaction of the lithium dithiolato ligand $LiS(S=PMe_2)C_2B_{10}H_{10}$ (2b) with $Cp^{\ast}CoI_2(CO)$ produced a mononuclear dithiolato complex, $[Cp^{\ast}CoI{(S,S (4), which was characterized by single-crystal X-ray analysis.
Keywords
Group 9 metal complexes; S,S'-Chelate ligands; Dinuclear metal complexes; o-Carboranyl ligands;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 6  (Related Records In Web of Science)
Times Cited By SCOPUS : 6
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