• 대한화학회지
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• 제26권1호
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• pp.31-35
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• 1982

Amberdentate 리간드인 isonitrosobenzoylacetone imine 및 N-알킬 치환제들의 새로운 팔라듐(Ⅱ) 착물 Pd(IBA-NH)(IBA-NH') 및 Pd(IBA-NR)2를 합성하였다. 여기서 IBA-NH 및 IBA-NR (R: methyl, ethyl, n-propyl, n-butyl, benzyl)은 각각 isonitrosobenzoylacetone imine 및 그 N-알킬 치환제를 표시한다. 합성한 팔라듐(II) 착물들의 적외선, 핵자기 공명, 전자 스펙트라 등을 측정한 결과 이들 착물 중에서 Pd(IBA-NH)(IBA-NH')는 IBA-NH는 이소니트로소기의 산소를 통하여 팔라듐에 배위되어 6각형 고리를 이루며 IBA-NH'는 이소니트로소기의 질소를 통하여 배위되어 5각형 고리를 이루고 있음을 확인하였다. 그리고 Pd$(IBA-NR)_2$는 양쪽의 IBA-NR이 같이 이소니트로소기의 질소를 통하여 배위되어 5각형 고리를 이루고 있음을 확인하였다. 이들 리간드의 배위구조는 $Bose^5$등에 의하여 알려진 isonitrosoacetylacetone imine 및 그 N-알킬 유도체들의 구조와 유사하다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.490.1-490.1
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• 2014

The ZnO nanowire (NW)-based nanogenerators (NGs) can have rectifying current and potential generated by the coupled piezoelectric and semiconducting properties of ZnO by variety of external stimulation such as pushing, bending and stretching. So, ZnO NGs needed to enhance durability for stable properties of NGs. The durability of the metal electrodes used in the typical ZnO nanogenerators(NGs) is unstable for both electrical and mechanical stability. Indium tin oxide (ITO) is used as transparent flexible electrode but because of high cost and limited supply of indium, the fragility and lack of flexibility of ITO layers, alternatives are being sought. It is expected that carbon nanotube and Ag nanowire conductive coatings could be a prospective replacement. In this work, we demonstrated transparent flexible ZnO NGs by using CNT/Ag nanowire hybrid electrode, in which electrical and mechanical stability of top electrode has been improved. We grew vertical type ZnO NW by hydrothermal method and ZnO NW was coated with hybrid silicone coating solution as capping layer to enhance adhesion and durability of ZNW. We coated the CNT/Ag nanowire hybrid electrode by using bar coating system on a capping layer. Power generation of the ZnO NG is measured by using a picoammeter, a oscilloscope and confirmed surface condition with FE-SEM. As a results, the NGs using the CNT/Ag NW hybrid electrode show 75% transparency at wavelength 550 nm and small change of the resistance of the electrode after bending test. It will be discussed the effect of the improved flexibility of top electrode on power generation enhancement of ZnO NGs.

• 한국정보통신학회:학술대회논문집
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• 한국정보통신학회 2012년도 추계학술대회
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• pp.307-311
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• 2012

본 논문에서는 금속 환경에서 사용이 가능한 RFID 국제 규격인 910MHz 대역에서 최상의 성능을 갖는 미앤더 형태의 마이크로스트립 패치 안테나를 설계하였다. 안테나에 부착되는 상용 태그 칩과 정합을 위해 사각 형태의 급전부를 본체에 연결하였으며, 사각 형태의 급전부를 본체 안에 위치하였고, 안테나의 복수부인 본체를 효과적으로 축소하기 위하여 패치의 소자를 증가시켜 다중의 미앤더 형태로 설계하였다. 제안된 안테나의 크기와 접은 횟수에 따른 대역폭, 효율, 인식 거리 등의 특성을 비교 분석하였다. 측정결과 안테나의 크기와 미앤더 형태로 접은 횟수에 따른 효율 및 이득 특성 변화가 안테나의 인식 거리에 큰 영향을 미치는 것을 확인하였다.

• 한국분말재료학회지
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• 제22권4호
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• pp.240-246
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• 2015

Anodic aluminum oxide (AAO) has been widely used for the development and fabrication of nano-powder with various morphologies such as particle, wire, rod, and tube. So far, many researchers have reported about shape control and fabrication of AAO films. However, they have reported on the shape control with different diameter and length of anodic aluminum oxide mainly. We present a combined mild-hard (or hard-mild) anodization to prepare shape-controlled AAO films. Two main parameters which are combination mild-hard (or hard-mild) anodization and run-time of voltage control are applied in this work. The voltages of mild and hard anodization are respectively 40 and 80 V. Anodization was conducted on the aluminum sheet in 0.3 mole oxalic acid at $4^{\circ}C$. AAO films with morphologies of varying interpore distance, branch-shaped pore, diameter-modulated pore and long funnel-shaped pore were fabricated. Those shapes will be able to apply to fabricate novel nano-materials with potential application which is especially a support to prevent volume expansion of inserted active materials, such as metal silicon or tin powder, in lithium ion battery. The silicon powder electrode using an AAO as a support shows outstanding cycle performance as 1003 mAh/g up to 200 cycles.

• 한국재료학회지
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• 제27권9호
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• pp.466-470
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• 2017

With the matters of climate change, energy security and resource depletion, a growing pressure exists to search for replacements for fossil fuels. Among various sustainable energy sources, hydrogen is thought of as a clean energy, and thus efficient hydrogen storage is a major issue. In order to realize efficient and safe hydrogen storage, various porous materials are being explored as solid-states materials for hydrogen storage. For those purposes, it is a prerequisite to characterize a material's textural properties to evaluate its hydrogen storage performance. In general, the textural properties of porous materials are analyzed by the Brunauer-Emmett-Teller (BET) measurement using nitrogen gas as a probe molecule. However, nitrogen BET analysis is sometimes not suitable for materials possessing small pores and surfaces with high curvatures like MOFs because the nitrogen molecule may sometimes be too large to reach the entire porous framework, resulting in an erroneous value. Hence, a smaller probe molecule for BET measurements (such as hydrogen) may be required. In this study, we describe a cost-effective novel cryostat for BET measurement that can reach temperatures below the liquefaction of hydrogen gas. Temperature and cold volume of the cryostat are corrected, and all measurements are validated using a commercial device. In this way, direct observation of the hydrogen adsorption properties is possible, which can translate directly into the determination of textural properties.

• 한국토양비료학회지
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• 제42권2호
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• pp.65-69
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• 2009

이 시험은 제주도 화산회토양을 이용하여 Ni, Cu, Zn의 토양중 존재형태를 알아보고 토양 중금속이 청경채의 흡수에 미치는 영향을 알아보고자 수행되었다. 토양 중 함량을 연속추출법에 의해 알아본 결과 토양 종류마다 각 중금속의 존재형태가 차이가 있었고, 이를 이용하여 토양 종류를 구분할 수 있었다. 중금속 함량이 다른 토양을 이용하여 청경채를 재배했을 경우 Zn, Cu는 뿌리에서 흡수되어 지상부로 이동되었으나 Ni은 지상부에서 거의 검출이 되지 않아 청경채 내에서 미량원소의 이동성이 달랐다. 그러나 토양 중 함량과 청경채의 함량 간에는 치환성 Zn을 제외하고는 상관관계가 없었으며, 특히 Ni은 식물체 내에서 이동도 어려울 뿐만 아니라 토양 중 함량과 상관관계를 내기도 어렵기 때문에 전함량이나 치환성함량 등 지금까지의 방법에 의한 토양 중 함량으로 식물체의 함량을 추정하기에는 매우 어렵다고 판단되므로 새로운 접근방법이 개발될 필요가 있다고 판단된다. 인체의 중금속 흡수에 의한 위해성 평가와 관련해서는 토양 식물체, 식물체 인체 두 단계를 거치게 되는데 각 단계에서 불확실성이 존재하므로 중금속의 기준을 토양 및 식물체 별로 각각 마련하는 것보다는 식물체내 농도만으로 정하는 것도 한가지 해결책이 될 수 있다고 생각한다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.319-319
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• 2011

Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol $H_2$/ mol Ru. Moreover, we observe that the RuHAP support exhibits a high catalytic lifetime of approximately one month upon repeated exposure to $NaBH_4$ solutions. In addition to examining surface area effects, we also identified the role of complex surface morphology in enhancing hydrolysis by the catalytic transition metal covered surface. Particularly, we found that a polycrystalline RuHAP catalytic support exhibits shorter induction times for the initial bubble formation as well as increased hydrogen generation rates as compared to a single crystal supports. The independent factor of a complex surface morphology is believed to provide enhanced sites for gas release during the initial stages of the reaction. By demonstrating the ability to shorten induction time and enhance catalytic activity through changes in surface morphology and Ru content, we find it feasible to further explore this catalyst support in the construction of a practical hydrogen generator.

• 미생물학회지
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• 제51권1호
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• pp.75-80
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• 2015

동해에서 분리된 Pseudoalteromonas donghaensis HJ51는 체외분비 단백질 분해효소를 생산하는 신종 미생물로 보고되었다. 체외 단백질 분해효소의 특성과 최적 생산 조건을 결정하기 위해 crude supernatant을 사용하여 단백질 분해효소의 최적 활성 온도와 pH를 조사한 결과 $40^{\circ}C$와 pH 7.5-10.5이었으며, pH 11에서도 88%의 높은 상대적인 효소 활성을 나타내었다. 효소의 금속 요구성을 조사한 결과, $Fe^{3+}$를 10 mM로 첨가하였을 때 최대 효소활성 증가를 보였다. 최대의 효소생산 조건을 탐색한 결과, 기본배지인 PY-ASW (peptone 0.5%, yeast extract 1.0%, artificial seawater)에 탄소원을 첨가하지 않는 것이 가장 높았으며, 질소원으로는 peptone 보다 beef extract, tryptone, casmino acids을 각각 첨가했을 때 활성이 21, 7, 4% 증가하였다. 이러한 결과를 종합해 볼 때 P. donghaensis HJ51이 생산하는 효소는 알칼리성 pH 환경 및 저온환경에서 활성이 필요한 분야에 응용이 가능할 것으로 사료된다.

• 공업화학
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• 제10권2호
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• pp.231-236
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• 1999

결정상과 분산도가 조절된 $MoO_3$/$SiO_2$ 담지촉매를 제조하여 촉매의 표면특성과 디벤조티오펜 탈황반응의 활성도를 고찰하였다. Mo의 표면담지량은 4 atoms $Mo/nm^2$이었으며, 실리카 표면 위에 형성된 $MoO_3$의 결정상은 sintered hexagonal, sintered orthorhombic, 및 dispersed hexagonal상이었다. XRD, Raman, 및 $O_2$ 흡착 결과 $MoO_3$의 표면분산도는 sintered hexagonal < sintered orthorhombic < dispersed hexagonal 순으로 증가하였다. TPR 결과 $MoO_3$ 결정은 $650^{\circ}C$에서 $MoO_2$로, $1000^{\circ}C$에서 Mo로 환원됨을 알 수 있었다. 디벤조티오펜 탈황반응을 30기압, $350{\sim}500^{\circ}C$ 온도범위에서 수행하였으며, 실험 결과 활성도는 $MoO_3$ 결정체의 $SiO_2$ 표면에서의 분산도에 비례하여 증가함을 알 수 있었다.

• 한국문헌정보학회지
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• 제29권
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• pp.345-382
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• 1995

The type printing of first Ch'ing dynasty term in China is worthy to be studied because the type printing during that period included metal type, wood type, and clay type as well as the development phase was similar to Chosun dynasty culturally and technologically. This paper studied typography during the first Ch'ing dynasty term, including Shunzhi(1662-1722), Yongaheng(1723-1735), Qianlong(1736-1795), Jiaqing(1796­1820) period. The main results of the study is as follows. 1. The main body of type printing was bookstore, lecture-hall, and individual as well as the royal court that is the central government. 2. The content of type edition covers classics, history, philosophy, and literary works. Specifically, even though Wuyingdienjuzhenban series is excluded, the content includs study of the classics, class of the history, class of the philosophy, literature works that include collection works and novel and government official bulletin. 3. The printing technique of bronze type was very popular In Beijing. Jiangsu, and Taiwan. It's scale and production technique was more elaborate than in Ming dynasty. 4. Wood type was very popular in Beijing, Jiangsu, Zhejiang, Anhui, Sichuan, and Fujian. In addition to wood type, chinese ware type was applied to book printing in Shandong. However, most of them were wood type and they were used after Qianlong period. 5. The production technique of type was skilled enough to present the fine view of a style of type. The typesetting technique was improved as much as woodblock printing. With regard to the making technology of Chinese ink, the light and darkness of chinese ink was not even sometimes. But, the technology was improved significantly when comparing with the failure experience of printing that chinese ink was not developed in early type invention. 6. In case that the book was printed in bookstore with the intention of profit and the number of book was large, the proofreading attitude was rough. However, overally, it was made correction carefully applying the various methods of proofreading. 7. The support of government made a great contribution in the area of all printing technology, including production, typesetting, and brushing of type.