• Title/Summary/Keyword: Non-ionic

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Cathodic Electrochemical Deposition of Highly Ordered Mesoporous Manganese Oxide for Supercapacitor Electrodes via Surfactant Templating

  • Lim, Dongwook;Park, Taesoon;Choi, Yeji;Oh, Euntaek;Shim, Snag Eun;Baeck, Sung-Hyeon
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.148-154
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    • 2020
  • Highly ordered mesoporous manganese oxide films were electrodeposited onto indium tin oxide coated (ITO) glass using sodium dodecyl sulfate (SDS) and ethylene glycol (EG) which were used as a templating agent and stabilizer for the formation of micelle, respectively. The manganese oxide films synthesized with surfactant templating exhibited a highly mesoporous structure with a long-range order, which was confirmed by SAXRD and TEM analysis. The unique porous structure offers a more favorable diffusion pathway for electrolyte transportation and excellent ionic conductivity. Among the synthesized samples, Mn2O3-SDS+EG exhibited the best electrochemical performance for a supercapacitor in the wide range of scan rate, which was attributed to the well-developed mesoporous structure. The Mn2O3 prepared with SDS and EG displayed an outstanding capacitance of 72.04 F g-1, which outperform non-porous Mn2O3 (32.13 F g-1) at a scan rate of 10 mV s-1.

Effect of Direct Emulsification Method and Invert Emulsification Method On Droplet Size of O/W Emulsion (O/W 에멀젼 입자의 크기에 미치는 Direct 유화법과 Invert유화법의 효과)

  • 김철훈;박재길
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.20 no.1
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    • pp.64-81
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    • 1994
  • O/W emulsions with mixed nonionic surfactants(polyoxyethylene(20)sorbitan monostearate/sorbitan sesquioleate), liquid paraffin, water prepared by direct inversion emulisification method and continuous inversion emulsification Method. The one-step, two-step and three-step phase inversion emulsification method were used in experiments. Effect of added water on droplet size of final O/W emulsions which is prepared by phase inversion emulsification method were investigated. In direct inversion emulsification method(two-step emulsification method), fine and homogeneous droplets of OIW emulsions were formed after phase inversion steps i.e. ,W/O - (W/O) If double emulsion - O/W emulsion. In continuous inversion emulsification method(three-step emulsification method), fine and homogeneous O/W emulsion were formed after phase inversion steps i.e., W/O - pseudomicroemulsion - O/W. By latter method, more Fine and homogenuous droplets were formed than former method. 10-10, 8 HLB region of mixed non-ionic surfactants could produce most fine droplets. This HLB region had maximum values of solubilization water and This HLB value of mixed nonionic surfactants produced fine and homogenuous droplets.

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A Customized Cleaning Agent for the Maintenance of Electric Fume Collector Used for the Purification of Effluent Gas from the Textile Industry (섬유산업 배기가스 정화용 Electric Fume Collector 설비의 유지보수를 위한 맞춤형 세정제)

  • Kim, Hotae;Yoo, Hwang-Yooll;Jeon, Koung Min;Song, Doori;Kim, Jin-Bae
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.229-236
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    • 2018
  • A customized cleaning agent was investigated for improving the performance decreased by the pollution of collecting plates in an electric fume collector (EFC) which was developed and applied for the purification of effluent gas including oil mist from the textile industry. The pollutants on the surface of collecting plates were blackened by the condensation of oil mist for a long time and difficult to remove by general cleaning agents. The composition of an optimized cleaning agent consisted of alkali, alcohol, glycol and non-ionic surfactant sources was determined by considering the pollutant properties and effect on the damage of the basic metal of collecting plate and so on. The developed cleaning agent solution diluted by 9.1% was applied to the field test, and also the pollutants strongly adhered on collecting plate surfaces were successfully removed by a simple spraying method. The effluent gas purification efficiency of EFC increased significantly by cleaning of collecting plates.

Preparation of Cosmeceuticals Containing Flos Sophorae Immaturus Extracts: Optimization Using Box-Behnken Design Model (회화나무꽃 추출물이 함유된 Cosmeceuticals의 제조: Box-Behnken 설계모델을 이용한 최적화)

  • Yoo, Bong-Ho;Zuo, Chengliang;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.404-410
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    • 2020
  • In this study, the stability criteria of cosmeceuticals emulsion containing Flos Sophorae Immaturus extracts was established using the Box-Behnken design model (BBD-RSM). As optimization conditions of the emulsification using the BBD-RSM, the amount of surfactant and additive, and emulsification time and speed were used as quantitative factors while mean droplet size (MDS), viscosity and emulsion stability index (ESI) were used as reaction values. According to the result of BBD-RSM, optimum conditions for the emulsification were as follows; the emulsification time and speed of 17.8 min and 5505 rpm, respectively and amounts of the emulsifier and additive of 2.28 and 1.05 wt.%, respectively. Under these conditions, the MDS, viscosity, and ESI after 7 days from the reaction were estimated as 1875.5 nm, 1789.7 cP, and 93.8%, respectively. The average error value from our actual experiments for verifying the conclusions was below 5%, which is mainly due to the fact that the BBD-RSM was applied to the optimized cosmeceuticals emulsification.

Responses of Cytochrome P450 and EROD Activity in Rockfish (Sebastes schlegeli) Administered Intraperitoneal Injection of 4-nonylphenol (노닐페놀을 주사한 조피볼락의 간장 cytochrome P450과 EROD의 반응)

  • 전중균;이지선;손영창;심원준;정지현;홍경표;김병기;한창희
    • Korean Journal of Environmental Biology
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    • v.22 no.1
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    • pp.171-176
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    • 2004
  • Nonyphenol (NP) used actively as non-ionic surfactant is classified as one of most potent endocrine disrupting chemicals. Effects of NP on mixed function oxygenase (MFO) system in rockfish (Sebastes schlegeli) were investigated for seven days after intraperitoneal injection (10 and 25 mg $kg^{-1}$). Hepatosomatic index (BSI) of fishes exposed to NP of 25 mg $kg^{-1}$ was significantly reduced compared to those in control group. NP exposure enhanced cytochrome P450 levels in the fish liver, while 7 ethoxyresorufin-O-deethylase (EROD) activity was inhibited. NP exposure levels in this study were much higher than those found in the coastal environment of Korea. Effects on HSI and liver MFO system, which is involved in steroid hormone metabolism, imply that W may influence on reproduction of fish by not only hormone receptor mediated response but also through effects on the MFO system.

Diagnostic Value of Thoracography in Pneumothorax (기흉에서 흉강조영술(Thoracography)의 진단적 가치)

  • 박영식;한재열;장지원
    • Journal of Chest Surgery
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    • v.31 no.7
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    • pp.730-734
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    • 1998
  • Background: It is important to know the location, number, size and shape of bullae before thoracotomy or VATS bullectomy. Chest X-ray and chest CT may be used but with some limitation. The purpose of this study was to compare the diagnostic value of thoracography with that of chest X-ray in preoperative detection of bullae. Meterial and Method: Thoracography was performed by injection of non-ionic water-soluble dye into pleural space in 22 primary spontaneous pneumothoraces, which underwent thoracotomy or VATS bullectomy. Chest X-ray and thoracography were compared through operative finding. Results: Sensitivity and accuracy of thoracography(75% and 72.7%) were higher than those of chest X-ray(30% and 36.4%). However, specificity of thoracography(50%) was lower than that of chest X-ray (100%). There were no complications during or after thoracography. Conclusion: Thoracography is a safer and more useful method for preoperative detection of bullae when compared with chest X-ray.

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Effects of Sodium Sulfate and Surfactants on Papain Treatment of Wool Fabrics

  • Kim, In Young
    • Fashion & Textile Research Journal
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    • v.16 no.2
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    • pp.333-338
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    • 2014
  • This study identifies the effects of sodium sulfate and surfactants in the papain treatment of wool fabrics using L-cysteine and EDTA as activators. The research method involves the use of 2% L-cysteine and 7% EDTA as activators at optimal conditions, papain treatment of wool fabrics with the joint use of sodium sulfates and surfactants, and measurements of the weight loss rate, tensile strength, and whiteness. Results showed that for both 2% L-cysteine and 7% EDTA, the maximum papain activity appeared at 0.5% sodium sulfate concentration. In both cases, the papain activity was enhanced at sodium sulfate concentrations lower than 0.5%. In contrast, the papain activity declined at sodium sulfate concentrations higher than 0.5%. The joint use of EDTA with 0.5% sodium sulfate was proven to be very effective in improving the papain activity. The joint use of 2% L-cysteine with 0.5% sodium sulfate appeared slightly effective in improving the activity but resulted in excessive decrease in the tensile strength and whiteness, compared to improvement in the activity. The joint use of surfactants, in the case of L-cysteine, interrupted the papain activity and decreased the tensile strength regardless of the surfactant type and concentration. In the case of EDTA, however, the joint use with 0.1-5% non-ionic surfactants, 0.1-0.5% anionic surfactants, and 0.1% cationic surfactant appeared to improve the papain activity. The maximum papain activity was observed when 0.1% of surfactant was used, regardless of the surfactant type. The nonionic surfactant was the most effective in improving the papain activity.

Transdermal Permeation Behavior of 5-FU using Microneedle (마이크로니들을 이용한 5-FU의 경피투과 거동)

  • Kim, Myoung-Jin;Park, Jung-Soo;Kim, Yun-Tae;Lee, Jun-Hee;Ahn, Sik-Il;Park, Jong-Hak;Mo, Jong-Hyun;Lee, Tae-Wan;Lee, Han-Koo;Khang, Gil-Son;Lee, Hai-Bang
    • Journal of Pharmaceutical Investigation
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    • v.38 no.1
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    • pp.45-50
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    • 2008
  • 5-Fluorouracil (5-FU) is an antimetabolic of the pyrimidine derivatives that is used in chemotherapy for the treatment of several types of cancer. 5-FU have poor oral absorption and short biological half-time and strong side effects. Microneedle introduced to find a solution of problems. Microneedle device with roll was manufactured for transdermal delivery of various drugs. 5-FU was mixed in non-ionic surfactant such as tween 20 and tween 80. Camscope was used to analysis the permeation magnitude of treated skin by microneedle and trypan blue staining. The 5-FU solution with surfactant measured by ZETA-potential analysis system for stability of solution. The skin permeation rate of 5-FU determined by HPLC. We confirmed that cross treated skin was dyed more deeply than parallel treated skin through trypan blue staining. The results indicate that skin permeation rate of 5-FU was increased with the treatment types and treatment times.

Effects of Dietary Addition of Surfactant Tween 80 on Ruminal Fermentation and Nutrient Digestibility of Hanwoo Steers

  • Kim, Chang-H.;Kim, Jong N.;Ha, Jong K.;Yun, Sang G.;Lee, Sung S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.3
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    • pp.337-342
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    • 2004
  • A non-ionic surfactant, Tween 80 has been known to exert a number of positive effects on degradative enzymes in in vitro aerobic and anaerobic microbial cultures. An experiment was conducted to examine effects of supplementation of Tween 80 on ruminal fermentation and nutrient digestibility of Hanwoo steers. The experiment was designed as a $3{\times}3$ Latin square with duplication and six Hanwoo steers with rumen cannulae, average weight 497 (SE 61.1) kg. For the experiment the animals were given a basal diet consisting of rice straw and compound feed mixed at 4:6 ratio. The three experimental treatments were (1) the basal diet, supplemented with (2) 5 g/d Tween 80 and (3) 10 g/d Tween 80. Ruminal pH was significantly (p<0.05) affected by Tween 80 supplementation at 6 h after feeding. Increasing supplementation levels of Tween 80 linearly increased the total VFA concentration. CMCase activity by the 10g/d supplementation of Tween 80 were significantly increased (p<0.05) by 24.4% compared with that of control. Digestibility of crude fiber was significantly increased (p<0.05) in Hanwoo steers fed the diet supplemented with 10 g/d Tween 80 compared with those of control, whilst digestibility of ether extract (EE) was linearly increased by increasing Tween 80 supplementation level (p<0.05). In other nutrient components, their digestibilities of Hanwoo fed diets supplemented with Tween 80 tended to increase. It is concluded that Tween 80 has a potential for industrial application as a feed additive to improve ruminant production.

Isolation of an Acinetobacter junii SY-01 Strain Producing an Extracellular Lipase Enantioselectively Hydrolyzing Itraconazole Precursor, and Some Properties of the Lipase

  • Yoon, Moon-Young;Shin, Pyong-Kyun;Han, Ye-Sun;Lee, So-Ha;Park, Jung-Keug;Cheong, Chan-Seong
    • Journal of Microbiology and Biotechnology
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    • v.14 no.1
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    • pp.97-104
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    • 2004
  • Water-sludge bacteria were screened to find a lipase enantioselectively hydrolyzing itraconazole precursor, which is well known as the starting material of antifungal drug agents. A bacterial strain was isolated and identified as Acinetobacter junii SY-01. After the strain was cultivated, the enzyme was purified 39.4-fold using ultrafiltration and gel filtration through a Sephadex G-100 chromatographic column and the activity yield was 34.9%. The molecular weight of the enzyme was about 40 kDa, as measured by SDS-PAGE, and the optimum pH was 7.0- 9.0 and stable at pH 6.0- 9.0. The optimum temperature was 45- $5^{\circ}C$, and 73% of the enzymes activity remained after incubation at 70% for 1 h. Enzyme activity was enhanced by gall powder, sodium deoxycholate, a cationic detergent Tween 80, and a non-ionic detergent Triton X-100, but was markedly inhibited by metal ions such as $Hg^{2+},Cu^{2+},Ni^{2+}/,Ca^{2+}$, and an anionic-surfactant sodium dodecylsulfate. The $K_{m}$ values for (R)- and (S)-enantiomers of the itraconazole precursor were 0.385 and 21.83 mM, respectively, and the $V_{max} values ($\mu$Mㆍmin^{-1}.)$ were 6.73 and 6.49, respectively. The acetyl group among the different acyl moieties of itraconazole precursor showed the highest enantioselectivity for the hydrolysis by the Acinetobacter junii SY-01 lipase, and the lipase from Acinetobacter junii SY-01 displayed better enantioselectivity than that of commercially available lipases and esterases.