• Title/Summary/Keyword: Non-equilibrium

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Simple Fabrication of Micromixer Based on Non-Equilibrium Electrokinetics in Micro/Nano Hybrid Fluidic System (단순공정으로 제작된 마이크로/나노 하이브리드 채널의 불균형 동전기성을 이용한 미세혼합기 연구)

  • Yu, Samuel;Kim, Sun-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.385-390
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    • 2011
  • In this study, we developed a micromixer based on the non-equilibrium electrokinetics at the junction of a microchannel and nanochannel. Two fluid streams were mixed by an electro-osmotic flow and a vortex flow created as a result of the non-equilibrium electrokinetics at the junction of the microchannel and nanochannel. Initially, the microchannel was fabricated using Polydimethylsiloxane (PDMS) by the general soft lithography process and the nanochannel was created at a specific position on the microchannel by applying a high voltage. To evaluate the mixing performance of the micromixer, fluorescent distribution was analyzed by using the fluorescent dye, Rhodamine B. About 90% mixing was achieved with this novel micromixer, and this micromixer can be used in microsystems for biochemical sample analysis.

Modeling of Non-Equilibrium Kinetics of Fuel Rich Combustion in Gas Generator (농후 연소 가스발생기의 비평형 연소 화학반응 모델링)

  • 유정민;이창진
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.7
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    • pp.89-96
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    • 2006
  • The combustion temperature in gas generator should be kept below around 1,000K to avoid any possible thermal damages to turbine blade by adopting either fuel rich or oxidizer rich combustion. Thus, non-equilibrium chemical reaction dominates in the gas generator. Meanwhile, Kerosene is a compounded fuel mixed with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focus to model the non-equilibrium chemical reaction of kerosene/LOX with detailed kinetics developed by Dagaut using PSR(Perfectly stirred reactor) assumption. Also, droplet evaporation time is taken into account by calculating for the residence time of droplet and by decoupling reaction temperature from the reactor temperature. In Dagaut’s surrogate model for kerosene, chemical kinetics of kerosene consists of 1592 reaction steps with 207 chemical species. The comparison of calculation results with experimental data could provide very reliable and accurate numbers in the prediction of combustion gas temperature, species fraction and other gas properties.

On a New Equilibrium Existence Theorem

  • Kim, Tai Sung;Kim, Won Kyu;Lim, Jong Sul
    • Journal of the Chungcheong Mathematical Society
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    • v.5 no.1
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    • pp.143-149
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    • 1992
  • The purpose of this note is to give a new existence theorem of equilibrium in non-compact generalized games with uncountable number of agents.

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Simulation of Miniaturized n-MOSFET based Non-Isothermal Non-Equilibrium Transport Model (디바이스 시뮬레이션 기술을 이용한 미세 n-MOSFET의 비등온 비형형장에 있어서의 특성해석)

  • Choi, Won-Cheol
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.3
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    • pp.329-337
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    • 2001
  • This simulator is developed for the analysis of a MOSFET based on Thermally Coupled Energy Transport Model(TCETM). The simulator has the ability to calculate not only stationary characteristics but also non - stationary characteristics of a MOSFET. It solves basic semiconductor devices equations including Possion equation, current continuity equations for electrons and holes, energy balance equation for electrons and heat flow equation, using finite difference method. The conventional semiconductor device simulation technique, based on the Drift-Diffusion Model (DDM), neglects the thermal and other energy-related properties of a miniaturized device. I, therefore, developed a simulator based on the Thermally Coupled Energy Transport Model (TCETM) which treats not only steady-state but also transient phenomena of such a small-size MOSFET. In particular, the present paper investigates the breakdown characteristics in transient conditions. As a result, we found that the breakdown voltage has been largely underestimated by the DDM in transient conditions.

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Oscillatory Reaction in a Liquid-Liquid System with Nano-Particle Under Microwave Irradiation

  • Asakuma, Y.;Takahashi, S.;Saptoro, A.;Maeda, Y.;Araki, N.
    • Particle and aerosol research
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    • v.11 no.3
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    • pp.77-85
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    • 2015
  • A Belousov-Zhabotinsky reaction in a liquid-liquid system under microwave radiation was observed under non-stirring conditions. To control this non-equilibrium reaction, nano-particle, which is active under microwave irradiation, was added to the solution. Color changes of the solution during the oscillatory reaction were found to be influenced by the irradiation power although the droplet temperature was equal to the temperature of surrounding oil. During the irradiation, the period of oscillation became shorter because the reaction rate was faster. It could also be observed that there is possibility to eliminate oscillatory behaviors of the reaction using higher power of microwave. The possibility of controlling non-linear reaction using microwave was shown since microwave can easily travel through oil phase and reach water phase.

Equilibrium and Non-equilibrium Molecular Dynamics Simulations of Thermal Transport Coefficients of Liquid Argon

  • Chang Bae Moon;Gyeong Keun Moon;Song Hi Lee
    • Bulletin of the Korean Chemical Society
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    • v.12 no.3
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    • pp.309-315
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    • 1991
  • The thermal transport coefficients-the self-diffusion coefficient, shear viscosity, and thermal conductivity-of liquid argon at 94.4 K and 1 atm are calculated by non-equilibrium molecular dynamics (NEMD) simulations of a Lennard-Jones potential and compared with those obtained from Green-Kubo relations using equilibrium molecular dynamics (EMD) simulations and with experimental data. The time-correlation functions-the velocity, pressure, and heat flux auto-correlation functions-of liquid argon obtained from the EMD simulations show well-behaved smooth curves which are not oscillating and decaying fast around 1.5 ps. The calculated self-diffusion coefficient from our NEMD simulation is found to be approximately 40% higher than the experimental result. The Lagrange extrapolated shear viscosity is in good agreement with the experimental result and the asymptotic formula of the calculated shear viscosities seems to be an exponential form rather than the square-root form predicted by other NEMD studies of shear viscosity. The agreement for thermal conductivity between the simulation results (NEMD and EMD) and the experimental result is within statistical error. In conclusion, through our NEMD and EMD simulations, the overall agreement is quite good, which means that the Green-Kubo relations and the NEMD algorithms of thermal transport coefficients for simple liquids are valid.

Sectional analysis of stamping processes using Equilibrium approach (평형해법에 의한 스탬핑 공정의 단면 해석)

  • Yoon, J.W.;Yoo, D.J.;Song, I.S.;Yang, D.Y.;Lee, J.H.
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.4
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    • pp.58-68
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    • 1994
  • An equilibrium approach is suggested as an effective tool for the analysis of sheet metal forming processes on the basis of force balance together with geometric relations and plasticity theroy. In computing a force balance equation, it is required to define a geometric curve approximating the shape of the sheet metal at any step of deformation from the geometric interaction between the die and the deforming sheet. Then the geometic informations for contacting and non-contacting sections of the sheet metal such as the number and length of both non-contact region, contact angle, and die radius of contact section are known from the geometric forming curve and utilized for optimization by force balance equation. In computation, the sheet material is assumed to be of normal amisotropy and rigid-phastic workhardening. It has been shown that there are good agreements between the equilibrium approach and FEM computation for the benchmark test example and auto-body panels whose sections can be assumed in plane-strain state. The proposed equilibrium approach can thus be used as a robust computational method in estimating the forming defects and forming severity rather quickly in the die design stage.

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AN EXPERIMENTAL STUDY ON POST-CHF HEAT TRANSFER FOR LOW FLOW OF WATER IN A $3\times3$ ROD BUNDLE

  • MOON SANG-KI;CHUN SE-YOUNG;CHO SEOK;KIM SE-YUN;BAEK WON-PIL
    • Nuclear Engineering and Technology
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    • v.37 no.5
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    • pp.457-468
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    • 2005
  • An experimental study on post-CHF heat transfer has been performed with a $3\times3$ rod bundle using a vertical steam-water two-phase flow at low flow conditions. The effects of various parameters on the post-CHF heat transfer are investigated and the reasons for the parametric effects are discussed. As the heat transfer regime changes from CHF to post-CHF, the radial wall temperature distribution is changed depending on the pressure and the mass flux conditions. The superheat of the fluid increases considerably with an increase of the wall temperature (or heat flux) and with a decrease of the mass flux. This implies, indirectly, a strong thermal non-equilibrium at high wall temperature and low mass flux conditions. In order to improve the prediction accuracy of the existing post-CHF correlations, it is necessary to perform more experiments, particularly direct measurement of the vapor superheat, and to modify the correlation by considering a strong thermal non-equilibrium at low flow and low pressure conditions.

Chemical Leaching of Non-Equilibrium Al(Fe-Co) Powder Produced by Rod Milling

  • Kim, Hyun-Goo
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.305-309
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    • 2003
  • We report on the formation and chemical leaching of non-equilibrium $Al_{0.6}(Fe_{75}Co_{25})$ alloy produced by rod milling. X-ray diffractometry, transmission electron microscopy, differential scanning calorimetry, scanning electron microscopy, and vibrating sample magnetometry were used to characterize the as-milled and leached specimens. After 400 h, only the $Al_{0.4}Fe_{0.6}$ peak of the body-centered cubic type was present in the XRD pattern. The entire rod milling process could be divided into three different stages of milling: agglomeration, disintegration, and homogenization. The saturation magnetization, $M_s$ decreased with increased milling time, the $M_s$ of the powders before milling was about 113.8 emu/g, the $M_s$ after milling for 400 h was about 11.55 emu/g. Leaching of the Al in KOH of the Al at room temperature from the as-milled powders did not induce any significant change in the diffraction pattern. After the leached specimen had been annealed at $600^{\circ}C$ for 1 hour, the nanoscale crystalline phases were transformed into the bcc Fe, cubic Co, and $CoFe_2O_4$ phases. On cooling the specimen from 85$0^{\circ}C$, the degree of magnetization increased slightly, then increased sharply at approximately 364.8$^{\circ}C$, indicating that the bcc $Al_{0.4}Fe_{0.6}$ phase had been transformed to the Fe and Co phases.

Modeling of Non-Equilibrium Kinetics in Gas Generator including Soot Formation (Soot 생성을 고려한 가스발생기의 Kerosene/LOx의 비평형 화학반응 모델링)

  • Yu, Jung-Min;Lee, Chang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.150-153
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    • 2006
  • Gas generator should be adopted either fuel rich or oxidizer rich combustion because of the temperature restriction to avoid any possible thermal damages to turbine blade. This study focuses to model the non-equilibrium chemical reaction of kerosene/LOx with detailed kinetics developed by Dagaut using Perfectly stirred reactor(PSR) assumption. To predict more reliable species fraction and other gas properties, Frenklach's soot model was added to Dagaut's detailed kinetics.

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