• Title/Summary/Keyword: No decomposition

Search Result 681, Processing Time 0.031 seconds

Decomposition of Odorous Gases in a Pilot-scale Nonthermal Plasma Reactor

  • Hwang, Yoon-Ho;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.21 no.E2
    • /
    • pp.57-65
    • /
    • 2005
  • An experimental study was performed on the decomposition of gaseous ammonia and two selected volatile organic compounds (VOCs: toluene and acetone) in a combined nonthermal plasma reactor with corona and glow discharges. A lab pilot scale reactor (206 liter) equipped with a high electric power pack was used to determine the decomposition efficiency in relation with the inlet concentration and applied voltage. Three different types of discharging electrode such as wired rack, wire strings for corona discharge, and thin plate for glow discharge were put in order in the reactor. While decomposition of ammonia decreased with an increase in the initial concentration, acetone showed an opposite result. In the case of toluene however no explicit tendency was found in toluene and aceton. Negative discharge resulted in high decomposition efficiency than the positive one for all gases. A better removal of gas phase element could be achieved when fume dust were present simultaneously.

Numerical analysis of NOx reduction for compact design in marine urea-SCR system

  • Choi, Cheolyong;Sung, Yonmo;Choi, Gyung Min;Kim, Duck Jool
    • International Journal of Naval Architecture and Ocean Engineering
    • /
    • v.7 no.6
    • /
    • pp.1020-1033
    • /
    • 2015
  • In order to design a compact urea selective catalytic reduction system, numerical simulation was conducted by computational fluid dynamics tool. A swirl type static mixer and a mixing chamber were considered as mixing units in the system. It had great influence on flow characteristics and urea decomposition into ammonia. The mixer caused flow recirculation and high level of turbulence intensity, and the chamber increased residence time of urea-water-solution injected. Because of those effects, reaction rates of urea decomposition were enhanced in the region. When those mixing units were combined, it showed the maximum because the recirculation zone was significantly developed. $NH_3$ conversion was maximized in the zone due to widely distributed turbulence intensity and high value of uniformity index. It caused improvement of $NO_x$ reduction efficiency of the system. It was possible to reduce 55% length of the chamber and connecting pipe without decrease of $NO_x$ reduction efficiency.

Studies on the Decomposition of CN ion in the electroplating waste Water and COD Variation of photodeveloping Waste-water (오존에 의한 폐수처리에 관한 연구 -도금폐액의 CN이온 분해와 사진 폐수의 COD 처리-)

  • 김덕묵;이치종
    • Journal of the Korean Professional Engineers Association
    • /
    • v.14 no.1
    • /
    • pp.22-29
    • /
    • 1981
  • This study concernes the decomposition of cyanide ion in electroplating plant wastewater and COD variation of photodeveloping wastewater under various conditions. Determinations of CN- concentration were carried out by AgNO$_3$ titration method. The sample solutions were pretreated by passing ozone and decompositions were checked as a function of time for ozone treatment. Analysis of film developing wastewater was carried out by KMnO$_4$ method. Electroplating plant wastewater was also examined at various pH; decomposition rate of cyanide ion was found to increase at higher pH. Time required for the decomposition could be shortened by removing the heavy metal ions under alkaline condition. The effect of temperature on decomposition was studied at 40$^{\circ}$ and 60$^{\circ}C$. The result was better at 40$^{\circ}C$ although time for decomposition was almost same at both temperatures. Analysis of film developing wastewater revealed that COD decrease was faster during the first 1 to 2 hours. However, further decrease could not be effected. The existence of unknown special organics resistant to the decomposition was believed to be the reason.

  • PDF

Method for Rapid Determination and Removal of Nitrogen Oxides in Flue Gas (II). Removal of Nitrogen Oxides Using Ammonia (배기가스중 질소산화물의 신속측정법과 그 제거에 관한 연구 (제 2 보). 암모니아에 의한 $NO_x$의제거)

  • Yong Keun Lee;Kee Jung Paeng;Kyu Ja Hwang
    • Journal of the Korean Chemical Society
    • /
    • v.30 no.2
    • /
    • pp.207-215
    • /
    • 1986
  • A new method was proposed to improve removal of nitrogen oxides $(NO_x)$ in exhaust gas by the reduction method using ammonia. At the relative humidity of 60%, 50 ppm of $NO_x$ was decomposed at the rate of 1% per hour in the reaction chamber. On the other hand, by adding $NH_3$ which was 5 times more concentrated than NOx, the decomposition rate increased to 6% per hour for 50 ppm $NO_x$ and 10% per hour for 20ppm $NO_x$. Within the actual exhausted gases, the decomposition rate of $NO_x$ reached the maximum 15% per hour because of coexisted reducing gases, such as hydrocarbon and carbon monoxide, and excess humidity containing trace metal ions. In the presence of acidic $SO_2$ gas, the decomposition rate of $NO_x$ decreased. The decomposition of $NO_x$ seems to be caused by the mist which is added to the system, and $NH_3$ in the mist which reduces $NO_x$.

  • PDF

Complexity Estimation Based Work Load Balancing for a Parallel Lidar Waveform Decomposition Algorithm

  • Jung, Jin-Ha;Crawford, Melba M.;Lee, Sang-Hoon
    • Korean Journal of Remote Sensing
    • /
    • v.25 no.6
    • /
    • pp.547-557
    • /
    • 2009
  • LIDAR (LIght Detection And Ranging) is an active remote sensing technology which provides 3D coordinates of the Earth's surface by performing range measurements from the sensor. Early small footprint LIDAR systems recorded multiple discrete returns from the back-scattered energy. Recent advances in LIDAR hardware now make it possible to record full digital waveforms of the returned energy. LIDAR waveform decomposition involves separating the return waveform into a mixture of components which are then used to characterize the original data. The most common statistical mixture model used for this process is the Gaussian mixture. Waveform decomposition plays an important role in LIDAR waveform processing, since the resulting components are expected to represent reflection surfaces within waveform footprints. Hence the decomposition results ultimately affect the interpretation of LIDAR waveform data. Computational requirements in the waveform decomposition process result from two factors; (1) estimation of the number of components in a mixture and the resulting parameter estimates, which are inter-related and cannot be solved separately, and (2) parameter optimization does not have a closed form solution, and thus needs to be solved iteratively. The current state-of-the-art airborne LIDAR system acquires more than 50,000 waveforms per second, so decomposing the enormous number of waveforms is challenging using traditional single processor architecture. To tackle this issue, four parallel LIDAR waveform decomposition algorithms with different work load balancing schemes - (1) no weighting, (2) a decomposition results-based linear weighting, (3) a decomposition results-based squared weighting, and (4) a decomposition time-based linear weighting - were developed and tested with varying number of processors (8-256). The results were compared in terms of efficiency. Overall, the decomposition time-based linear weighting work load balancing approach yielded the best performance among four approaches.

The Relationship between the Fractionation Characteristics and Decomposition Rate of Organic Carbon in Nam River and Geumho River (남강 및 금호강에서 유기탄소 존재형태와 분해속도와의 관계)

  • Ho-Sub Kim;Seok-Gyu Kim;Seung-Young Oh
    • Journal of Korean Society on Water Environment
    • /
    • v.39 no.2
    • /
    • pp.131-141
    • /
    • 2023
  • In this study, the relationship between organic carbon distribution characteristics and decomposition rate classified according to the particle size and biological degradation characteristics in water was investigated for the Nam river and Geumho river. The average concentrations of TOC in the Nam river and Geumho river were 2.7±1.2 mg/L and 5.0±1.2 mg/L, respectively, but the composition ratios for each type of organic carbon were similar. An average value of 80.9% of TOC was present as DOC and 72.8% of DOC consisted of Refractory-DOC (RDOC). In addition, the change in the RDOC composition ratio according to temporal and spatial distribution was the smallest. There was no difference in the decomposition rate of organic carbon except for TOC by the site (p≥0.108, one-way ANOVA), and the decomposition rates of Labile-POC (LPOC) and LDOC were similar at 0.139±0.102 and 0.137±0.149 day-1, respectively (p=0.110, paired t-test). The coefficient of variation (CV) of the decomposition rate of DOC (average 8.1%), which had the smallest composition ratio of organic carbon, was 1.1, showing the largest temporal variation. The TOC, POC, and DOC decomposition rates showed a significant correlation with the ratio of the initial concentration to the concentration after 25 days of decomposition (OC25/OC0) (r2=0.89~0.94, p<0.001), and the decomposition rates of LPOC and LDOC were significantly correlated with the ratio of the initial concentration to the concentration after 5 days of decomposition (LOC5/LOC0) (r2=0.67~0.75). This suggests that it is possible to estimate the decomposition rate through the concentration of each type of organic carbon.

A study of decomposition of harmful gases using Composite catalyst by Photocatalytic plasma reactions (복합촉매를 이용한 플라즈마 반응에 의한 유해가스의 제거에 관한 연구)

  • Kim, Gwan-Jung;U, In-Seong;Park, Hwa-Yong;Lee, Hong-Ju
    • Proceedings of the Safety Management and Science Conference
    • /
    • 2012.04a
    • /
    • pp.421-433
    • /
    • 2012
  • The objective of this study is to obtain the optimal process condition and the maximum decomposition efficiency by measuring the decomposition efficiency, electricity consumption, and voltage in accordance with the change of the process variables such as the frequency, maintaining time period, concentration, electrode material, thickness of the electrode, the number of windings of the electrode, and added materials etc. of the harmful atmospheric contamination gases such as NO, $NO_2$, and $SO_2$etc. with the plasma which is generated by the discharging of the specially designed and manufactured $TiO_2$ catalysis reactor and SPCP reactor.

  • PDF

A study of decomposition of harmful gases using Composite catalyst by Photocatalytic plasma reactions (복합촉매를 이용한 플라즈마 반응에 의한 유해가스의 제거에 관한 연구)

  • Park, Hwa-Young;Kim, Kwan-Jung;Woo, In-Sung
    • Journal of the Korea Safety Management & Science
    • /
    • v.15 no.1
    • /
    • pp.121-132
    • /
    • 2013
  • The objective of this study is to maintain the same frequency as the electrode material, concentration, duration of decomposition efficiency, power consumption and voltage measurements using a composite catalyst according to the change of process parameters to obtain the optimum state of the process and the maximum decomposition efficiency. In this paper, known as a major cause of air pollution, such as NO, NO2, SO2, frequency, flow rate, concentration, the material of the electrodes, and using TiO2 catalyst reactor with surface discharge caused by discharging the reactor plasma NOx, SOx decompose the harmful gas want to remove.