• Title/Summary/Keyword: Nitrogen fraction

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Effect of Silicon Oxynitride Matrix on the Optical Properties of Au Nanoparticles Dispersed Composite Film (실리콘 산화질화물 기지상 적용에 따른 Au 나노입자 분산 복합체 박막의 광학적 특성)

  • Cho, Sung-Hun;Lee, Kyeong-Seok
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.637-643
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    • 2009
  • In this study, we analyzed the effect of silicon oxynitride matrix on the optical properties of Au nanoparticles dispersed on composite film and explored the effectiveness of the silicon in fine tuning the refractive index of the composite film for applications in optical waveguide devices. The atomic fraction of nitrogen in $SiO_xN_y$ films was controlled by varying the relative flow ratio of nitrogen gas in reactive sputtering and was evaluated optically using an effective medium theory with Bruggeman geometry consisting of a random mixture between $SiO_2$ and $Si_3N_4$. The Au nanoparticles were embedded in the $SiO_xN_y$ matrix by employing the alternating deposition technique and clearly showed an absorption peak due to the excitation of surface plasmon. With increasing nitrogen atomic fraction in the matrix, the surface plasmon resonance wavelength shifted to a longer wavelength (a red-shift) with an enhanced resonance absorption. These characteristics were interpreted using the Maxwell-Garnett effective medium theory. The formation of a guided mode in a slab waveguide consisting of 3 $\mu$m thick Au:$SiO_xN_y$ nanocomposite film was confirmed at the telecommunication wavelength of 1550 nm by prism coupler method and compared with the case of using $SiO_2$ matrix. The use of $SiO_xN_y$ matrix provides an effective way of controlling the mode confinement while maintaining or even enhancing the surface plasmon resonance properties.

Serial Particle Size Fractionation and Water Quality in a Recirculating Aquaculture System for Eel

  • Lee, Jin-Hwan
    • Fisheries and Aquatic Sciences
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    • v.13 no.2
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    • pp.133-139
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    • 2010
  • The effects of suspended solids size on culture water quality were determined in a commercial recirculating aquaculture system (RAS) for Japanese eel, Anguilla japonica. The particulate phase of the culture water was serially divided into six size fractions using 300, 200, 100, 75, 45, and 26 ${\mu}m$ pore size stainless sieves. The total, dissolved, and particulate nitrogen and phosphorus, and suspended solids for each fraction were determined. The concentration ranges in the fractions were: total nitrogen, 164-148 mg $L^{-1}$; total phosphorus, 20.4-15.5 mg $L^{-1}$; and total suspended solids, 8.1-6.1 mg $L^{-1}$. The concentration of total nitrogen and total phosphorus decreased significantly (P<0.05) with a 26 ${\mu}m$ and 200 ${\mu}m$ filter pore size, respectively. Nutrients from dissolved organic substances were much higher than from particulates. Analysis of particle size fractionation and its effects on water quality is useful to estimate removal efficiencies of a commercial effluent screening device for solid management and development of solid removal systems.

Differentiation in Nitrogen-Converting Activity and Microbial Community Structure between Granular Size Fractions in a Continuous Autotrophic Nitrogen Removal Reactor

  • Qian, Feiyue;Chen, Xi;Wang, Jianfang;Shen, Yaoliang;Gao, Junjun;Mei, Juan
    • Journal of Microbiology and Biotechnology
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    • v.27 no.10
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    • pp.1798-1807
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    • 2017
  • The differentiations in nitrogen-converting activity and microbial community structure between granular size fractions in a continuous completely autotrophic nitrogen removal over nitrite (CANON) reactor, having a superior specific nitrogen removal rate of $0.24g/(g\;VSS{\cdot}h)$, were investigated by batch tests and high-throughput pyrosequencing analysis, respectively. Results revealed that a high dissolved oxygen concentration (>1.8 mg/l) could result in efficient nitrite accumulation with small granules (0.2-0.6 mm in diameter), because aerobic ammonium-oxidizing bacteria (genus Nitrosomonas) predominated therein. Meanwhile, intermediate size granules (1.4-2.0 mm in diameter) showed the highest nitrogen removal activity of $40.4mg/(g\;VSS{\cdot}h)$ under sufficient oxygen supply, corresponding to the relative abundance ratio of aerobic to anaerobic ammonium-oxidizing bacteria (genus Candidatus Kuenenia) of 5.7. Additionally, a dual substrate competition for oxygen and nitrite would be considered as the main mechanism for repression of nitrite-oxidizing bacteria, and the few Nitrospira spp. did not remarkably affect the overall performance of the reactor. Because all the granular size fractions could accomplish the CANON process independently under oxygen limiting conditions, maintaining a diversity of granular size would facilitate the stability of the suspended growth CANON system.

Antioxidative and Hepatoprotective Effects of Acer tegmentosum M. Extracts (산겨릅나무 추출물의 항산화 및 간 기능 보호효과)

  • Kwon, Ha-Na;Park, Jyung-Rewng;Jeon, Jeong-Ryae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.11
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    • pp.1389-1394
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    • 2008
  • This study was carried out to investigate antioxidative and hepatoprotective effects of Acer tegmentosum M. (ATM) extracts. Content of total polyphenol of EtOAc fraction was the highest amount among fractions. Electron donating abilities of all fractions were increased as concentrations of each fraction were increased. ATM BuOH fraction showed the highest SOD like activity at low concentration (<$250\;{\mu}g/mL$). To investigate the protective effect of ATM on hepatotoxicity, ATM BuOH fraction was administered to mice for 7 consecutive days, and then lipopolysaccharide (LPS) was injected at a dosage of 1 mg/kg. The LPS led to increase of aspartate aminotransferase (AST), alanine aminotransferase (ALT), and blood urea nitrogen (BUN). However, pretreatment with BuOH fraction prior to LPS injection significantly decreased plasma hepatospecific enzyme levels. Histological findings demonstrated that pretreatment with BuOH fraction resulted in an attenuation of LPS induced liver damages.

Effects of Various Nitrogen Compounds for the Growth of Barley Roots and Transaminase Activity (대맥근(大麥根)의 생장(生長)과 Transaminase의 활성(活性)에 미치는 몇 가지 질소화합물(窒素化合物)의 영향(影響))

  • Kim, K.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.3 no.1
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    • pp.43-48
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    • 1970
  • In order to investigate the inter-relation with the growth of the barley root and GOT and GPT activities the growth of root and GOT, GPT activities were measured those which have been supplied various nitrogen compounds ($NO_3-N$, $NH_4-N$, Urea, and Amino acid). The results obtained are summarized as follows: 1. Growth of barley root supplied with $NH_4-N$ is generally increased in length and weight compared with that of the root fertilized by $NH_4-N$. 2. The above-mentioned root with $NH_4-N$ is not only decreased in its weight and length but also is apt to inhibited its growth, in compared with the root provided with $NO_3-N$. 3. The activities of GOT and GPT for the root fertilized by $NH_4-N$, the badly grown root is generally increased, while of the root supplied with $NO_3-N$ is decreased compared with that of the root fertilized by $NH_4-N$. 4. The activities of GOT and GPT for the root provided with amino acid known as the considerable growth inhibiting compound for rice is generally decreased, while that of the badly known-grown root is increased. 5. The activities of GOT and GPT in the supernatant fraction of the barley is for the most part, high and low in the mitocondrial fraction.

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Effect of Outer Edge Flame on Flame Extinction in Counterflow Diffusion Flames (대향류 확산화염에서 에지화염이 화염소화에 미치는 영향)

  • Chung, Yong-Ho;Park, Dae-Geun;Park, Jeong;Yun, Jin-Han;Kwon, Oh-Boong;Keel, Sang-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.2
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    • pp.181-188
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    • 2012
  • The present study on nitrogen-diluted non-premixed counterflow flames with finite burner diameters experimentally investigates the important role of the outer edge flame in flame extinction. Flame stability diagrams mapping the flame extinction response of nitrogen-diluted non-premixed counterflow flames to varying global strain rates in terms of the burner diameter, burner gap, and velocity ratio are explored. There exists a critical nitrogen mole fraction beyond which the flame cannot be sustained, and also the curves of the critical nitrogen mole fraction versus the global strain rate have C-shapes in terms of burner diameter, burner gap, and velocity ratio. In flames with sufficiently high strain rates, the curves of the critical nitrogen mole fractions versus global strain rate collapse into one curve, and the flames can have the 1-D flame response of typical diffusion flames. Three flame extinction modes are identified: flame extinctions through the shrinkage of the outer edge flame with and without an oscillation of the outer edge flame prior to the extinction and flame extinction through a flame hole at the flame center. The measured flame surface temperature and a numerical evaluation of the fractional contribution of each term in the energy equation show that the radial conductive heat loss at the flame edge destabilizes the outer edge flame, and the conductive and convection heat addition to the outer edge from the trailing diffusion flame stabilizes the outer edge flame. The radial conductive heat loss at the flame edge is the dominant extinction mechanism acting through the shrinkage of the outer edge flame.

The Contents of Nitrogen, Phosphorus, Silicon Nutrient and Algal Growth Potential (AGP) in the Sediment of Taechong Reservoir (대청호 저토의 N, P및 Si 영양염 함량과 조류생장잠재력)

  • Cho, Kyung-Je;Shin, Jae-Ki
    • Korean Journal of Ecology and Environment
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    • v.34 no.2 s.94
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    • pp.106-118
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    • 2001
  • The chemistry of porewater and exchangeable nutrients of sediment was determined to define potential influence of sediment nutrients on the water quality and the phytoplankton growth in Taechong Reservoir in March and May of 2000. The sediment-water interface showed almost anoxic state, < 0.5 mg $O_2/l$. Conductivity of the porewater was higher 1.9${\sim}$2.6 fold than that of sediment, and its variation was greater in the shallow water. Eh ranged from -12mV to -148 mV and bulk density from $1.17\;g/cm^3$ to $1.30\;g/cm^3$ and they did not differ among stations. The water content in the sediment ranged from 58% to 72% and organics from 8% to 13%, and they were higher toward the lower part of reservoir. Soil texture was in the order of sand>clay>silt and sandy sediment accounted for 97% of the total sediment. The total bacterial numbers and diatom abundance were high in the downstream of the reservoir. In porewater and exchangeable nutrients of sediment, nitrogen and phosphorus were mostly consist of the particulate form. Inorganic nitrogen was mostly composed of $NH_4$. Nitrogen of porewater was mostly an inorganic form while exchangeable nutrients were composed an organic form. However, phosphorus was composed of dissolved organic fraction in the porewater while inorganic fraction in the exchangeable nutrients. Silicon content of sediment was much exchangeable nutrients with 63%, and it was higher than in the porewater. In summary, the sediments of Taechong Reservoir were mostly composed of organics and assessed to be a eutrophic state.

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Temperature Measurement in Concentric Diffusion Flames by Rapid Insertion Technique (급속 삽입법에 의한 화염 내부 온도 분포 측정)

  • Lee, Gyo-Woo;Chung, Young-Rok;Jurng, Jong-Soo
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.75-83
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    • 1999
  • The effect of temperature distributions on soot volume fraction in double-concentric diffusion flames have been investigated experimentally. Using fine thermocouple wires and a rapid insertion mechanism, we have measured temperature without the effect of soot particles attached to the thermocouple junction, which can lower the temperature signal about 100 K by increasing the heat loss from the junction by radiation. The temperature at the flame axis is higher in the double-concentric diffusion flames than in normal co-flow diffusion flames because of the inverse diffusion flame. However, it is almost the same as that at the periphery of normal flames, on which the inverse flame does not have an effect. Thus, the lower soot concentration found in the double-concentric diffusion flame can be explained by the effect of nitrogen diffusion from the central air jet.

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Studies on the Biologic Activities of the Constituents of Ailanthi Cortex Radicis (II) -Acute and Renal Toxicity of Chloroform Fraction- (저근백피(樗根白皮) 성분(成分)의 생리활성(生理活性)에 관한 연구(硏究) (II) -클로로포름분획의 급성 및 신장에 대한 독성-)

  • Kim, Jong;Kim, Hye-Kyung;Park, Soo-Wan;Choi, Jong-Won;Lee, Chung-Kyu
    • Korean Journal of Pharmacognosy
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    • v.25 no.2
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    • pp.140-143
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    • 1994
  • During the serial attempts to identify the chemical and biological characteristics of Ailanthi Cortex Radicis, the root bark of Ailanthus altissima (Simaroubaceae), we find out the serious toxic effect on kidney by chloroform fraction of the methanolic extract of the herb drug. The toxicities were revealed as the increase of urea nitrogen amount in blood and lactate dehydrogenase and ${\gamma}-glutamyltransferase$ activities in urine and the decrease of the concentration of glutathione and both of protein bound and non-protein bound -SH in kidney tissue.

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Fabrication and Mechanical Properties of $SiC_p/Al$ Composites by Pressureless Infiltration Technique (무가압침투법에 의한 $SiC_p/Al$ 복합재료의 제조 및 기계적 특성)

  • Jin, H.G.;Oh, M.S.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.5 no.4
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    • pp.74-81
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    • 2001
  • The infiltration behavior of molten Al-alloy, microstructures, hardness, and the interfacial reactions of $SiC_p/Al$ composites fabricated by the pressureless infiltration technique were investigated. It was made clear that both the weight fraction of SiC reinforcement and additive Mg content considerably influenced on the infiltration behavior of the molten Al-alloy matrix. Complete infiltration of molten Al-alloy achieved under the conditions that weight fraction of SiC content is more than 30wt%, and additive Mg content is more than 9wt%. Interfacial region of Al-alloy matrix and SiC reinforcement phase, $Mg_2Si$ was formed by the reaction between Mg and SiC. Another reaction product AlN was also formed by the reaction between Al-alloy matrix and gas atmosphere nitrogen.

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