• Title/Summary/Keyword: Nitrogen Oxide

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Preparation of ZnO Nanorod Grown on the PAN Surface and Its Sulfur Removal Characteristics (PAN 섬유 표면에서 성장하는 ZnO 나노로드의 제조 및 이를 이용한 황화합물 제거 특성)

  • LEE, JAEYOUNG;HAN, KYEONGSIK;JEONG, INSOO;LEE, HONGKI
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.3
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    • pp.243-250
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    • 2018
  • Zinc oxide (ZnO) nanorods were grown on a palladium (Pd) activated polyacrylonitrile (PAN) fiber where Pd activation was carried out in advance by the following dry process: palladium(II) bis(acetylacetonate), $Pd(acac)_2$ was sublimed, penetrated into the surface of PAN fiber and spontaneously reduced to Pd nanoparticles at $180^{\circ}C$ for various times under a nitrogen atmosphere. ZnO nanorod morphology was observed by a scanning electron microscopy (SEM) and the elemental composition was confirmed by energy-dispersive X-ray spectroscopy (EDS). The crystalline structure of ZnO nanorods was analyzed by X-ray diffraction (XRD) analysis showing Wurtzite structure consisting of hexagonal lattice. Sulfur removal characteristics were evaluated.

Device Characteristics and Hot Carrier Lifetime Characteristics Shift Analysis by Carbon Implant used for Vth Adjustment

  • Mun, Seong-Yeol;Kang, Seong-Jun;Joung, Yang-Hee
    • Journal of information and communication convergence engineering
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    • v.11 no.4
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    • pp.288-292
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    • 2013
  • In this paper, a carbon implant is investigated in detail from the perspectives of performance advantages and side effects for the thick n-type metal-oxide-semiconductor field-effect transistor (n-MOSFET). Threshold voltage ($V_{th}$) adjustment using a carbon implant significantly improves the $V_{th}$ mismatch performance in a thick (3.3-V) n-MOS transistor. It has been reported that a bad mismatch occurs particularly in the case of 0.11-${\mu}m$ $V_{th}$ node technology. This paper investigates a carbon implant process as a promising candidate for the optimal $V_{th}$ roll-off curve. The carbon implant makes the $V_{th}$ roll-off curve perfectly flat, which is explained in detail. Further, the mechanism of hot carrier injection lifetime degradation by the carbon implant is investigated, and new process integration involving the addition of a nitrogen implant in the lightly doped drain process is offered as its solution. This paper presents the critical side effects, such as Isub increases and device performance shifts caused by the carbon implant and suggests an efficient method to avoid these issues.

Preparation and characterization of TiO2 membrane on porous 316 L stainless steel substrate with high mechanical strength

  • Mohamadi, Fatemeh;Parvin, Nader
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.251-262
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    • 2015
  • In this work the preparation and characterization of a membrane containing a uniform mesoporous Titanium oxide top layer on a porous stainless steel substrate has been studied. The 316 L stainless steel substrate was prepared by powder metallurgy technique and modified by soaking-rolling and fast drying method. The mesoporous titania membrane was fabricated via the sol-gel method. Morphological studies were performed on both supported and unsupported membranes using scanning electron microscope (SEM) and field emission scanning microscope (FESEM). The membranes were also characterized using X-ray diffraction (XRD) and $N_2$-adsorption / desorption measurement (BET analyses). It was revealed that a defect-free anatase membrane with a thickness of $1.6{\mu}m$ and 4.3 nm average pore size can be produced. In order to evaluate the performance of the supported membrane, single-gas permeation experiments were carried out at room temperature with nitrogen gas. The permeability coefficient of the fabricated membrane was $4{\times}10^{-8}\;lit\;s^{-1}\;Pa^{-1}\;cm^{-1}$.

A Study for Development of a Marine Diesel Engine from a 500Ps Commercial Vehicle Diesel Engine (500Ps급 상용차량 디젤엔진을 이용한 선박용 디젤엔진 개발 연구)

  • Sim, Han-Sub
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.6
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    • pp.125-131
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    • 2013
  • This study was carried out to develop a diesel engine for marine propulsion. This marine diesel engine was developed based on a 500Ps vehicle diesel engine. Many main parts, such as the intercooler, radiator, and engine controller were designed for the marine diesel engine. The intercooler was designed to be of sea water cooling type; inlet air is cooled by sea water. Engine coolant is cooled by sea water in the radiator too. The water cooling heat exchanger has high cooling performance. In the cooling system, consists of the intercooler and the radiator, the sea water passes through the intercooler and then the radiator, in sequence. This process is very effective compared to the reverse method in which sea water passes through the radiator and then the intercooler, in sequence. The control performance of the engine controller and the fuel injection rate were improved using an engine speed controller. This system was tested on an engine dynamometer and an exhaust gas analyzer using the marine diesel engine test method. Test results show that the 500Ps marine diesel engine satisfied the IMO NOx regulations; Tier II.

Sonochemical Synthesis, Thermal Studies and X-ray Structure of Precursor [Zr(acac)3(H2O)2]Cl for Deposition of Thin Film of ZrO2 by Ultrasonic Aerosol Assisted Chemical Vapour Deposition

  • Hussain, Muzammil;Mazhar, Muhammad;Rauf, Muhammad Khawar;Ebihara, Masahiro;Hussain, Tajammal
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.92-96
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    • 2009
  • A new precursor [$Zr(acac)_{3}(H_{2}O)_{2}$] was synthesized by Sonochemical technique and used to deposit thin $ZrO_{2}$ film on quartz and ceramic substrate via ultrasonic aerosol assisted chemical vapour deposition (UAACVD) at 300 ${^{\circ}C}$ in oxygen environment followed by annealing of the sample for 2-3 minutes at 500 ${^{\circ}C}$ in nitrogen ambient. The molecular structure of the precursor determined by single crystal X-ray analysis revealed that the molecules are linked through intermolecular hydrogen bonds forming pseudo six and eight membered rings. DSC and TGA/FTIR techniques were used to determine thermal behavior and decomposition temperature of the precursor and nature of evolved gas products. The optical measurement of annealed $ZrO_{2}$ film with tetragonal phase shows optical energy band gap of 5.01 eV. The particle size, morphology, surface structure and composition of deposited films were investigated by XRD, SEM and EDX.

MICROSTRUCTURAL EVOLUTION OF A HIGH CR FE-BASED ODS ALLOY BY DIFFERENT COOLING RATES

  • Shen, Yin-Zhong;Cho, Hae-Dong;Jang, Jin-Sung
    • Nuclear Engineering and Technology
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    • v.40 no.2
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    • pp.99-106
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    • 2008
  • Through mechanical alloying, hot isostatic pressing and hot rolling, a 9%Cr Fe-based oxide dispersion-strengthened alloy sample was fabricated. The tensile strength of the alloy is significantly improved when the microstructure is modified during the post-consolidation process. The alloy samples were strengthened as the cooling rates increased, though the elongation was somewhat reduced. With a cooling rate of $800^{\circ}C/s$ after normalization at $1150^{\circ}C$, the alloy sample showed a tensile strength of 1450 MPa, which is about twice that of the hot rolled sample; however, at $600^{\circ}C$ the tensile strength dramatically decreased to 620 MPa. Optical microscope and transmission electron microscope were used to investigate the microstructural changes of the specimens. The resultant strengthening of the alloy sample could be mainly attributed to the interstitially dissolved nitrogen, the fraction of the tempered martensite, the fine grain and the presence of a smaller precipitate. The decrease in the tensile strength was mainly caused by the precipitation of vanadium-rich nitride.

An Investigation of Effects of Fuel Stratification and Cooled EGR on DME HCCI Engine's Operating Ranges by Numerical Analysis (농도성층화와 Cooled EGR이 DME HCCI 엔진의 운전영역에 미치는 영향에 관한 수치해석)

  • Jeong, Dong-Won;Amarbayar, D.;Lim, Ock-Taeck
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.2
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    • pp.129-135
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    • 2010
  • Homogeneous charge compression ignition (HCCI) engines have the potential to provide both diesel-like efficiency and very low emissions of nitrogen oxide (NOx) and particulate matter(PM). However, several technical issues still must be resolved before HCCI can see application. Among these, steep pressure-rise rate which leads to narrow operating range of HCCI engine continues to be a major issue. This work investigates the combination of two methods to mitigate the excessive pressure-rise rates at high power output, namely fuel stratification and Cooled exhaust-gas recirculation (Cooled EGR), after identifying the each effects to pressure-rise rate. When applying the fuel stratification to simulation, total fuelling width of 0.15 at BDC is set as a equivalent ratio difference based on the previous research. In order to simulate the effects of cooled EGR, $CO_2$ mole fraction in pre-mixture is changed ranging from 0 to 30%. DME which has a characteristic of two-stage ignition is used as a fuel.

An Experimental Study on the Heat Exchange Performance at Various EGR Cooler Types (EGR 쿨러 Type에 따른 열교환성능에 관한 실험적 연구)

  • Shon, Jungwook;Woo, Seungchul;Park, Jongwook;Chun, Taesoo;Lee, Kihyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.6
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    • pp.608-614
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    • 2015
  • Nitrogen oxide(NOx) emission reductions are required to meet the strict emission regulations for environmental protection. Most of the Exhaust Gas Recirculation(EGR) system applied to a diesel engine can relatively decrease the NOx at a low cost, but it has a disadvantage in that the PM generation is promoted due to the hot intake air temperature. Thus, high heat exchange efficiency of the EGR cooler is required for an effective removal of NOx. In this study, heat exchange efficiency for various types of heat exchangers used in EGR cooler was measured under same conditions, and determined best heat exchange performance shape depending on type of heat exchanger.

Combustion and Emissions Characteristics of a Diesel Engine with the Variation of the HP/LP EGR Proportion (고압/저압 EGR 공급 비율에 따른 디젤 엔진의 연소 및 배기 특성)

  • Park, Youngsoo;Bae, Choongsik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.90-97
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    • 2014
  • The effects of high pressure and low pressure exhaust gas recirculation (HP/LP EGR) portion on diesel engine combustion and emissions characteristics were investigated in a 2.2 L passenger-car diesel engine. The po3rtion of HP/LP EGR was varied from 0 to 1 while fixing the mass flow rate of fresh air. The intake manifold temperature was lowered with the increasing of the portion of LP EGR, which led to the retardation of heat release by pilot injection. The lowered intake manifold temperature also resulted in low nitrogen oxide (NOx) emissions due to decreased in-cylinder temperature and prolonged ignition delay, however, the carbon monoxide (CO) emission showed opposite trend to NOx emissions. The brake specific fuel consumption (BSFC) was decreased as the portion of LP EGR increased due to lowered exhaust manifold pressure by wider open of turbocharger vane. Consequently, the trade-off relationship between NOx and BSFC could be improved by increasing the LP EGR portion.

Effect of EGR and Supercharging on the Diesel HCCI Combustion (디젤 예혼합 압축착화 엔진에서 배기가스 재순환과 과급의 영향)

  • Park, Se-Ik;Kook, Sang-Hoon;Bae, Choong-Sik;Kim, Jang-Heon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.58-64
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    • 2006
  • Homogeneous charge compression ignition(HCCI) combustion is an advanced technique for reducing the hazardous nitrogen oxide(NOx) and particulate matter(PM) in a diesel engine. NOx could be reduced by achieving lean homogeneous mixture resulting in combustion temperature. PM could be also reduced by eliminating fuel-rich zones which exist in conventional diesel combustion. However previous researches have reported that power-output of HCCI engine is limited by the high intensive knock and misfiring. In an attempt to extend the upper load limit for HCCI operation, supercharging in combination with Exhaust Gas Recirculation(EGR) has been applied: supercharging to increase the power density and EGR to control the combustion phase. The test was performed in a single cylinder engine operated at 1200 rpm. Boost pressures of 1.1 and 1.2 bar were applied. High EGR rates up to 45% were supplied. Most of fuel was injected at early timing to make homogeneous mixture. Small amount of fuel injection was followed near TDC to assist ignition. Results showed increasing boost pressure resulted in much higher power-output. Optimal EGR rate influenced by longer ignition delay and charge dilution simultaneously was observed.