• 한국식품영양과학회지
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• 제26권6호
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• pp.1028-1032
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• 1997

Low-temperature crystallization method silver nitrate-impregnated silicic acid column chromatography were applied for the isolation of pure $\alpha$-linolenic acid(ALA) from perilla seed oil. ALA or 78% in purity(HALA; yield, 83%) was obtained from the fatty acid mixture(ALA, 65.7%) derived from perilla oil by the low-temperature crystallization method, when the mixture was frozen at -8$0^{\circ}C$ for 210min. ALA over 90% in purity(yield, 71%) was also obtained from HALA ethyl esters(ALA, 78%) by the silver nitrate-impregnated silicic acid column(100cm$\times$10cm, i.d.) chromatography. In addition, the silver nitrate-impregnated silicic acid could be semipermanently used for isolation of ALA, because $Ag^{+}$ ion was not dissociated from the stationary phase.

• 공업화학
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• 제22권3호
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• pp.255-260
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• 2011

$K^{+}-{\beta}^{{\prime}{\prime}}$-alumina pellet를 이온교환 매체인 ammonium nitrate 수용액과 용융염으로 각각 이온교환하여, 고온형 PEMFC 전해질로 기대되는 무기소재인 $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina를 제조하였다. 고압반응기의 실험조건으로 온도는 130, 150, 170, $200^{\circ}C$ 에서, 시간은 2 h 간격으로 2 h에서 8 h까지 수열반응을 실시하였으며 이 때의 수용액의 농도는 5 M과 10 M을 사용하였다. 또한 $200^{\circ}C$의 가열기 위에서 ammonium nitrate를 완전히 녹여 용융염 상태의 ammonium nitrate를 이용하여 2 h 간격으로 2 h에서 8 h까지 이온교환을 실시하였다. 이온교환반응의 반복횟수에 따른 영향을 알아보기 위하여 재이온교환반응을 3차까지 반복해서 실험하였다. 이후 이온교환 된 $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina 구조체의 상 안정성, 이온교환율을 각각 X선 회절기(Rigaku Rint 2000, Japan)와 ICP-AES (Spectro, Modular EOP)를 사용하여 분석하였다.

• 한국대기환경학회지
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• 제26권3호
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• pp.265-275
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• 2010

Mass and ion concentrations of $PM_{10}$ and $PM_{2.5}$ were measured in Yongin, downwind of the Seoul metropolitan area. Twenty-four hour average samples were collected daily for a month or so in spring and fall of both 2007 and 2008. Asian dust occurred twice in each period except in the fall of 2007. During the Asian dust period, nitrate in fine particles decreased since large amount of cations in coarse particles of Asian dust absorbed it. In spring 2008, sulfate as well as ammonium also increased in coarse particles. In spite of occasional Asian dust events, the influence of secondary formation was dominant over the period. Excessive ammonium over sulfate was enough to neutralize nitrate as well. High correlation coefficients between $K^+$ and sulfate, nitrate, and ammonium indicate a close relationship between secondary formation and biomass burning. Biomass burning and open burning are considered to be important sources of chloride.

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1814-1822
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• 2013

By using density functional theory calculations, we have performed a systemic study on the electronic structures and topological properties of interactions between N-butylpyridinium nitrate ($[BPY]^+[NO_3]^-$) and thiophene (TS), benzothiophene (BT), dibenzothiophene (DBT), naphthalene (NAP). The most stable structure of $[BPY]^+[NO_3]^-$ ion pair indicates that hydrogen bonding interactions between oxygen atoms on $[NO_3]^-$ anion and C2-H2 on pyridinium ring play a dominating role in the formation of ion pair. The occurrence of hydrogen bonding, ${\pi}{\cdots}$H-C, and ${\pi}{\cdots}{\pi}$ interactions between $[BPY]^+[NO_3]^-$ and TS, BT, DBT, NAP has been corroborated at the molecular level. But hydrogen bonding and ${\pi}{\cdots}{\pi}$ interactions between $[BPY]^+[NO_3]^-$ and NAP are weak in terms of structural properties and NBO, AIM analyses. DBT is prior to adsorption on N-butylpyridinium nitrate ionic liquid.

• 한국환경과학회지
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• 제20권2호
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• pp.215-222
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• 2011

The adsorption behavior of nitrate nitrogen was investigated from aqueous solution using char prepared from oak chip. The removal rate of nitrate nitrogen was found to be dependent on temperature and it is increased as the temperature increase. Adsorption equilibrium data of nitrate nitrogen on oak char. reasonably fitted Langmuir and Freundlich isotherm models. The adsorption energy obtained from D-R model was 12.5 kJ/mole at $20^{\circ}C$ indicating an ion exchange process as primary adsorption mechanism. Thermodynamic parameters such as ${\Delta}G^o$, ${\Delta}H^o$, and ${\Delta}S^o$ were -23.76 kJ/mole, 26.1 kJ/mole and 89.7 J/K mole at $20^{\circ}C$, respectively, indicated that the nature of nitrate nitrogen adsorption is spontaneous and endothermic.

• 한국미생물·생명공학회지
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• 제24권3호
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• pp.268-273
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• 1996

An extremely cadmium tolerant yeast, Hansenula anomala B-7 used to determine the modification of the intracellular enzyme activities by cadmium ion. The activities of alcohol dehydrogenase, phosphofructokinase, and cytidine deaminase were decreased up to 90%, 40%, and 86% compa- red with the control by 1 mM cadmium nitrate respectively, but the activities of malate dehydrogenase, 6- phosphogluconate dehydrogenase, cytochrome c oxidase, and alkaline phosphatase were increased up to 440%, 136%, 260% and 155% compared with the control by 1 mM cadmium nitrate respectively. These results show that the activities of the enzymes participating in Embden-Mayerhof pathway (e.g. anaerobic metabolism) were reduced by cadmium, but those involved in hexose monophosphate pathway and tricarboxylic acid cycle (e.g. aerobic metabolism) were stimulated in contrast. It has been suggested that the diminished activity of cytidine deaminase in pyrimidine nucleotide dissimilation occured due to the inhibited nucleotide dissimilation by cadmium ion; the enhanced activity of cytochrome c oxidase was specifically required in order to oxidize a raised amount of NADH and NADPH due to the increased aerobic metabolism.

• 한국환경보건학회:학술대회논문집
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• 한국환경보건학회 2005년도 국제학술대회
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• pp.355-358
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• 2005

Nitrate-selective ion exchange resins involving bulky trialkyl amino as functional group were synthesized by the reaction of chloromethylated polystyrene-divinylbenzene copolymer and the corresponding tripropylamine in ethanol. Fundmental properties such as bulk density, water content, effeative diameter, uniformity coefficient, appearance index, exchange capacity and particle size distribution were fully measured. The synthesized resins appeared to be good for nitrate selection.

• 한국대기환경학회지
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• 제1권1호
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• pp.33-41
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• 1985

In order to investigate the Phenomenon of Acid Precipitation, pH value and Anions of Fluroide, chloride, nitrite, phosphate, bromide, nitrate and sulfate were measured from the acid precipitations sampled around 7 districts over seoul area during period of 9 months from January till September, in 1985. From the distribution of pH value gatnered, acid precipitations were noticed during period from January till Aprill, and from as of April 22nd, situation gradually recovered. The average pH value till April showed comparatively low, ranging 4.0-5.0. The pH value of 4.5-5.6 in average over whole year reaches to similar level of those in Japan. Anion analysis revealed that the main factor of pH value in Seoul district attribute mainly to the sulfate ion and nitrate ion. Moreover, these Phenomena of acid precipitation in Seoul area appeared to concentrate on certain districts, and they are slowly moving toward other directions due to such factors as wind-velocity and directions.

• 환경위생공학
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• 제20권4호통권58호
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• pp.1-8
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• 2005

Pocheon is a basin geographically, and the diffusion of air pollutants is very difficult. Thus, it is essential to consider the characteristics of geographical and weather conditions before industrial complex and various air pollution sources are developed in the area. It is recommended that Environmental Impact Statements (EIS) must be carried out before any action is taken. Constantly occurring fog in the Pocheon area absorbs large amounts of acidic gases, and it transformed into the secondary pollutants such as the salts of sulfate and nitrate. Fog, which occurs very often in Pocheon area, was analyzed for its acid components. Conversion from the gaseous sulfur dioxide into sulfate ion is relatively high, $86\~90\%$ while $68\~76\%$ of NOx is converted into nitrate ion form.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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• pp.196-199
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• 1996

In this paper, aging characteristics of outdoor silicone rubber insulator resulting from the acid rain have been investigated with regards to nitrate ion ($NO_3$). For this purpose, silicone rubber was aged by immersing into the nitric solutions with different level ph during 1500 hours and various tests(tracking, contact angle, $tan{\delta}$, breakdown voltage, SEM, EDS, FT-IR) were performed. It was observed that the degradation was increased to ph 2.5 slightly and highly at ph 1.5. And thus, it could be expected that there is certain critical point between ph 1.5 and 2.5, which leads to throught degradation.