• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.16-17
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• 2006

In this paper, Ni-V alloy was studied with different structures and thickness. In case of Ni-V and Ni-V/Co/TiN, low resistive Ni silicide was formed after one step RTP (Rapid Thermal Process) with temperature range from $400^{\circ}C$ to $600^{\circ}C$ for 30sec in vacuum. After furnace annealing with temperatures range from $550^{\circ}C$ to $650^{\circ}C$ for 30min in nitrogen ambient, Ni-V single structure shows the best thermal stability compare with the other ones. To enhance the thermal stability up to 650oC and find the optimal thickness of Ni silicide, different thickness of Ni-V was studied in this work. Stable sheet resistance was obtained through Ni-V single structure with optimal Ni-V thickness.

• 한국수소및신에너지학회논문집
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• 제6권1호
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• pp.1-9
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• 1995

$V_{0.9}Ti_{0.1}$ 합금은 많은 양의 수소를 흡수할 수 있으나 KOH 전해질내에서 방전이 되지 않기 때문에 Ni-MH 전지의 음극재료로 사용할 수 없었다. 이와 같은 $V_{0.9}Ti_{0.1}$ 합금을 전해질내에서 수소흡수/방출에 대한 촉매효과를 갖도록 Ni 분말과 소결하였다. Ni 분말과 소결한 모든 시편은 KOH 전해질내에서 10 Cycle 이내에 활성화 되었다. 방전용량은 소결시 첨가된 Ni 분말의 양에 따라 maximum 거동을 보였다. 가장 높은 방전용량을 보여준 전극의 경우는 소결시 첨가된 Ni 분말의 양이 25wt.%이며 그 방전용량은 302mAh/g이었다. SEM과 EDS 그리고 XRD 분석결과 소결시 $VNi_3$가 형성됨을 알 수 있었다. $V_{0.9}Ti_{0.1}$ 합금의 표면에 형성된 $VNi_3$는 전극의 최적방전조건과 밀접한 관련이 있음을 알 수 있었다. Brewer-Engel 이론에 의하면 $VNi_3$는 수소의 evolution에 대한 전기적 촉매효과가 매우 높다고 보고하고 있으며, 이러한 효과는 본 실험결과 교환전류밀도의 증가와 방전시 과전압의 감소로써 나타났다. 본 연구에서는 수소의 저장용량은 크나 KOH 전해질내에서 방전되지 않는 합금을 사용하여 Ni-MH 전지용 음극개발을 하기 위해 Ni분말과 소결하여 합금의 표면을 변화시키는 새로운 방법을 제안하고자 한다.

• 한국재료학회지
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• 제14권12호
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• pp.857-862
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• 2004

Production of titanium powder directly from tantalum oxides ($TiO_2$) pellet through an electronically mediated reaction (EMR) by calciothermic reduction has been investigated. Feed material ($TiO_2\;pellet$) and reductant (Ca-Ni alloy) were charged into electronically isolated locations in a molten calcium chloride ($CaCl_2$) bath at $950^{\circ}C$. The current flow through an external circuit between the feed (cathode) and reductant (anode) locations was monitored during the reduction of $TiO_2$. The current approximately 3.2A was measured during the reaction in the external circuit connecting cathode and anode location. After the reduction experiment, pure titanium powder with low nickel content was obtained even though Ca-Ni alloy was used as a reductant. These results demonstrate that titanium powder can be produced without direct physical contact between the feed and reductant. In certain experimental conditions, pure titanium powder with approximately $99.5\;mass\%$ purity was successfully obtained.

• 한국수소및신에너지학회논문집
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• 제2권1호
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• pp.39-46
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• 1990

In order to improve the power of hydride heat pump, prototype heat pump was constructed using $Zr_{0.95}Ti_{0.05}Cr_{0.9}Fe_{1.1}$-$Zr_{0.9}Ti_{0.1}Cr_{0.6}Fe_{1.4}$ which had very good hydrogenation properties. The power changed with operating parameter such as cycle time, air flow rate, and temperature of hot air was investigated. The power shows maximum value with cycle time. The power increased with air flow rate and temperature of hot air. The power of the heat pump was $65-72 Kcal/Kg-alloy{\cdot}h$ under optimum operating condition, which was superior to that the system using $LaNi_{0.9}Al_{0.3}-MmNi_{4.15}Al_{0.66}Fe_{0.2}$ alloy pairs.

• 한국해양공학회지
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• 제8권1호
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• pp.154-164
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• 1994

In this paper, fatigue testing was carried out under the change of aging time(0.5,1.5.10hrs) by electric heating method which is one of the useful method in the application of Robot's actuator. Fatigue degradation behaviors such as cyclic deformation property, amount of deformation, decrease in recovery and variation of transformation temperature for each specimen were examined closely, and the effect of aging time condition was studied on their fatigue degradation behaviors.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2003년도 춘계학술대회 논문집
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• pp.346-351
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• 2003

In the recent years, as the research and the development of micro and precision machinery become active, the interest of micro actuators using SMA(Shape Memory Alloy) has been increased. The dynamic characteristic analysis of SMA is necessary for actuator application and many common researches report the material characteristics of SMA sufficiently. However, the research on dynamic characteristics is very deficient. In this paper, the helical spring are fabricated with NiTi SMA wire of high resistivity. The force, response speed, temperature, and displacement are measured by digital force gauge, infrared thermometer, and laser displacement sensor so that the dynamic characteristics of this SMT is analyzed. Also, bidirectional actuator was fabricated and experimented for its performance

• 한국자동차공학회논문집
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• 제6권6호
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• pp.53-62
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• 1998

A simple analytical and finite element(FE) models are used to study the tensile properties of Al matrix composite with continuous TiNi fibers. The effects of residual stresses caused by the shape momory effects have been compared for various mechanical behaviors as a function of fiber volume fraction and degree of pre-strain and fiber configurations. It is found that both the back stress in the Al matrix induced by stiffness of TiNi fibers and the compressive stress in the matrix are caused of the strengthening mechanisms. Both theoretical and analytical results show quite good agreement and are closed to the experimental data except in high volume content.

• 한국생산제조학회지
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• 제8권5호
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• pp.42-46
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• 1999

The strengthening of a metal matrix composite(MMC) by the shape memory effect(SME) of dispersed TiNi particles was theoretically studied. An analytical model was constructed for the prediction of the average residual stress(<$\delta$>m) on the base of the Eshelby's equivalent inclusion method. The analysis was performed on the TiNi particle/Al metal matrix composites with varying volume fractions and prestrains of the particle. The residual stress caused by the shape memory of predeformed fillers has been predicted to contribute significantly to the strengthening of this composite.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.87-88
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• 2006

The phase transformation behaviors of Ni-Ti shape memory alloys were investigated through a DSC(Differential Scanning Calorimetry). The annealing temperatures were applied from $600^{\circ}C,\;700^{\circ}C,\;800^{\circ}C,\;and\;900^{\circ}C$ for their effects on the phase transformation behaviors. Based on the results of DSC, phase transformation behaviors of shape memory alloys can be predicted by Liang's phase transformation model or Tanaka's phase transformation model.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 1999년도 춘계학술대회 논문집
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• pp.147-152
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• 1999

The strengthening of a metal matrix composite(MMC) by the shape memory effect(SME) of dispersed TiNi particles was theoretically studied. An analytical model was constructed for the prediction of the average residual stress(<$\sigma$>/sub/m) on the base of the Eshelby's equivalent inclusion method. The analysis was performed on the TiNi particle/Al metal matrix composites with varying volume fractions and prestrains of the particle. The residual stress caused by the shape memory of predeformed fillers has been predicted to contribute significantly to the strengthening of this composite.