• 제목/요약/키워드: Ni variation

검색결과 409건 처리시간 0.029초

분말야금 스테인리스 스틸의 산화특성에 미치는 조성 및 조직변화의 영향 (The Effects of Composition and Microstructure Variation on the Oxidation Characteristics of Stainless Steels Manufactured by Powder Metallurgy Method)

  • 이종필;홍지현;박동규;안인섭
    • 한국분말재료학회지
    • /
    • 제22권1호
    • /
    • pp.52-59
    • /
    • 2015
  • As well-known wrought stainless steel, sintered stainless steel (STS) has excellent high-temperature anti-corrosion even at high temperature of $800^{\circ}C$, and exhibits good corrosion resistance in air. However, when temperature increases above $900^{\circ}C$, the corrosion resistance of STS begins to deteriorate and dramatically decreases. In this study, the effects of phase and composition of STS on high-temperature corrosion resistances are investigated for STS 316L, STS 304 and STS 434L above $800^{\circ}C$. The morphology of the oxide layers are observed. The oxides phase and composition are identified using X-ray diffractometer and energy dispersive spectroscopy. The results demonstrate that the best corrosion resistance of STS could be improved to that of 434L. The poor corrosion resistance of the austenitic stainless steels is due to the fact that $NiFe_2O_4$ oxides forming poor adhesion between the matrix and oxide film increase the oxidation susceptibility of the material at high temperature.

울산화강암 및 인접 사문암 중 주/미량 원소의 거동에 관한 지화학적 연구 (A Geochemical Study on the Behaviors of Major and Trace Elements in the Ulsan Granite and Its Contact Serpentinite)

  • 이재영;이인호
    • 자원환경지질
    • /
    • 제28권1호
    • /
    • pp.53-67
    • /
    • 1995
  • Geochemical characteristics of iron-related Ulsan granite was studied in comparison with the Cretaceous granitoids from the metallogenic provinces of copper, lead-zinc and lead-zinc/molybdenum in the Gyeongsang Basin, and the variation of cheminal compositions at the Ulsan granite/serpentinite contact was investigated. Ulsan granite is plotted in the regions of granite and granodiorite of Streckeisen's diagram. It shows differentiation trend of calc-alkali magma, and the magmatic evolution from granodiorite to granite is consistant with the general crystallization path of the Cretaceous the granitoids in Gyeongsang Basin. Differentiation index(D.I.) of Ulsan granite is 86~95, which is higher than those of Jindong granites (D.I.=45~70) and Onjongri granites (D.I.=67~84), and there are differences in the content of some major and trace elements between Ulsan granite and other Cretaceous granitoids. At the Ulsan granite/serpentinite contact $SiO_2$, $K_2O$, $Na_2O$, $Al_2O_3$, Rb, Sr, Ba which are abundant in Ulsan granite decrease toward serpentinite, while T.Fe, MgO, Ni, Cr which are abundant in serpentinite decrease toward Ulsan granite. Therefore, the geochemical characteristics of Ulsan granite is applicable to distinguish iron province from different metallogenic provinces where other Cretaceous granitoids occur in the Gyeongsang Basin, and it is possible to find serpentinite which was intruded by granite on the basis of chemical variations.

  • PDF

Hot-filament 화학기상 증착법에 의한 탄소나노튜브의 성장 및 표면 특성 (Synthesis and Surface Characterization of Carbon Nanotubes by Hot-Filament Plasma Enhanced Chemical Vapor Deposition)

  • 최은창;김정태;박용섭;최원석;홍병유
    • 한국진공학회지
    • /
    • 제16권3호
    • /
    • pp.187-191
    • /
    • 2007
  • 본 연구에서는 실리콘 웨이퍼 위에 마그네트론 스퍼터링 시스템을 이용하여 Ni 촉매 층을 증착시키고, $NH_3$$C_2H_2$ gas를 이용하여 탄소나노튜브를 성장시켰다. Hot-filament 플라즈마 화학기상 증착법으로 탄소나노튜브의 성장 온도는 350, 450, 550, $650^{\circ}C$로 변화시켰으며, 성장되어진 탄소나노튜브는 field emission scanning electron microscope(FESEM) 분석을 하여 관찰하였고, 접촉각 측정법을 이용하여 탄소나노튜브 층의 특성을 분석하였다. 결과적으로 성장 온도는 탄소나노튜브의 성장 특성을 변화시키는 중요한 요소이다.

한반도 서해안 배경지역 미세입자의 화학적 특성 연구 (Study on the Chemical Characteristics of $PM_{10}$ at Background Area in Korean Peninsula)

  • 방소영;백광욱;정진도;남재철
    • 한국환경보건학회지
    • /
    • 제30권5호
    • /
    • pp.455-468
    • /
    • 2004
  • The purpose of this paper is to understand the time series and origin of a chemical component and to compare the difference during yellow sand episodes for analysis $PM_{10}$ chemical components in the region of west in Korean Peninsula, 1999-2001. An annual mean concentration of $PM_{10}$ is $29.1\;{\mu}g/m^3$. A monthly mean and standard deviation of $PM_{10}$ concentration are very high in spring but there is no remarkably seasonal variation. Also, water soluble ionic component of $PM_{10}$ be influenced by double more total anion than total cation, be included $NO_{3}^-\;and\;SO_{4}^{2-}$ for the source of acidity and $NH_{4}^+$ to neutralize. Tracer metals of $PM_{10}$ slowly increases caused by emitted for soil and ocean (Fe, Al, Ca, Mg, Na) and Zn, Pb, Cu, Mn for anthropogenic source. According to method of enrichment factor (E.F) and statistics, assuming that the origin of metal component in $PM_{10}$ most of element in the Earth's crust e.g. Mg, Ca, Fe originates soil and Cu, Zn, Cd, Pb derives from anthropogenic sources. The ionic component for $Na^{+}\;Cl^-,\;Mg^{2+}\;and\;Ca^{2+}$ and Mg, Al, Ca, Fe originated by soil component largely increase during yellow sand period and then tracer metal component as Pb, Cd, Zn decrease. According to factor analysis, the first group is ionic component ($Na^+,\;Mg^{2+},\;Ca^{2+}$) and metal component (Na, Fe, Mn and Ni) be influenced by soil. The second group, Mg, Cr also be influenced by soil particle.

춘천시 대기 중 PM2.5 및 금속성분의 장기간 농도 특성 (Long-term Characteristics of PM2.5 and Its Metallic Components in Chuncheon, Korea)

  • 변진여;조성환;김현웅;한영지
    • 한국대기환경학회지
    • /
    • 제34권3호
    • /
    • pp.406-417
    • /
    • 2018
  • In this study, $PM_{2.5}$ samples were collected during approximately 3 years in Chuncheon, a small residential and tourist city, in Korea. The average $PM_{2.5}$ concentration was $26.9{\mu}g/m^3$, exceeding the annual national air quality standard. $PM_{2.5}$ showed typical seasonal variation, having higher concentration in winter and lower concentration in summer. Sixteen metallic elements in $PM_{2.5}$ were also analyzed, and K was the highest contributor especially in late fall and winter. In addition, K considerably increased for the top 10% of $PM_{2.5}$ samples and showed the highest correlation coefficient with $PM_{2.5}$ among all other metallic elements. These results suggest that the combustion of agricultural residue and other biomass, the major source of K was likely to be important to high $PM_{2.5}$ concentration events in this city. Crustal elements including Al, Fe, Si, Ti, Mg showed high concentration in spring while Cr, Cu and Ni were relatively consistent throughout a year. Principal component analysis was used to trace the sources, and soil re-suspension, combustion of biomass and fossil fuels, and asphalt concrete production were identified as the main sources of $PM_{2.5}$.

Variability of measured modal frequencies of a cable-stayed bridge under different wind conditions

  • Ni, Y.Q.;Ko, J.M.;Hua, X.G.;Zhou, H.F.
    • Smart Structures and Systems
    • /
    • 제3권3호
    • /
    • pp.341-356
    • /
    • 2007
  • A good understanding of normal modal variability of civil structures due to varying environmental conditions such as temperature and wind is important for reliable performance of vibration-based damage detection methods. This paper addresses the quantification of wind-induced modal variability of a cable-stayed bridge making use of one-year monitoring data. In order to discriminate the wind-induced modal variability from the temperature-induced modal variability, the one-year monitoring data are divided into two sets: the first set includes the data obtained under weak wind conditions (hourly-average wind speed less than 2 m/s) during all four seasons, and the second set includes the data obtained under both weak and strong (typhoon) wind conditions during the summer only. The measured modal frequencies and temperatures of the bridge obtained from the first set of data are used to formulate temperature-frequency correlation models by means of artificial neural network technique. Before the second set of data is utilized to quantify the wind-induced modal variability, the effect of temperature on the measured modal frequencies is first eliminated by normalizing these modal frequencies to a reference temperature with the use of the temperature-frequency correlation models. Then the wind-induced modal variability is quantitatively evaluated by correlating the normalized modal frequencies for each mode with the wind speed measurement data. It is revealed that in contrast to the dependence of modal frequencies on temperature, there is no explicit correlation between the modal frequencies and wind intensity. For most of the measured modes, the modal frequencies exhibit a slightly increasing trend with the increase of wind speed in statistical sense. The relative variation of the modal frequencies arising from wind effect (with the maximum hourly-average wind speed up to 17.6 m/s) is estimated to range from 1.61% to 7.87% for the measured 8 modes of the bridge, being notably less than the modal variability caused by temperature effect.

니켈박막의 두께에 따른 광투과율변화 (Optical Transmittance Variation to Thickness of Nickel Thin Films)

  • 양기원;손정식;곽호원;이행기;박상철
    • 한국안광학회지
    • /
    • 제13권1호
    • /
    • pp.49-52
    • /
    • 2008
  • 목적: 이 논문은 다양한 두께에 따른 니켈박막에 대한 광투과율을 연구한 논문이다. 방법: 다양한 두께를 가진 니켈박막을 통과하는 광투과율을 측정하였다. 결과: 열증착법으로 만든 니켈박막을 통과하는 광투과율의 두께의존성을 연구하였다. 니켈박막의 두께가 70 nm 이하인 경우에 니켈의 박막두께가 증가할수록 광투과율이 급격히 감소하는 경향을 보였고, 70 nm 이상의 경우에는 박막의 두께가 증가할수록 선형적으로 조금씩 감소하는 모습을 보여주었다. 광분산에 대한 실험에서는 빛의 입사하는 방향으로 대부분의 빛이 투과되었다. 이 결과로부터 니켈박막에서는 빛의 분산현상이 거의 없다는 것을 확인할 수가 있었다. 결론: 니켈박막두께가 증가할수록 광투과율이 급격히 감소하였다.

  • PDF

스발바드군도 스피츠베르겐섬 콩스피요르드에 서식하는 갈조류의 중금속 농도 (Metal Concentrations in some Brown Seaweeds from Kongsfjorden on Spitsbergen, Svalbard Islands)

  • 안인영;최희선;지정연;정호성;김지희
    • Ocean and Polar Research
    • /
    • 제26권2호
    • /
    • pp.121-132
    • /
    • 2004
  • Concentrations of Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn were determined in four arctic brown algae (Laminaria saccharina, L. digitata, Alaria esculenta, Desmarestia aculeata) in an attempt to examine for their metal accumulation capacity and also to assess their contamination levels. Macroalgae were collected from shallow subtidal waters (<20m) of Kongsfjorden (Kings Bay) on Spitsbergen during the period of the late July to early August 2003. Metal concentrations highly varied between sampling sites, species and tissue parts. Input of melt-water laden with terrigenous sediment particles seemed to have a large influence on baseline accumulations of some metals (Al, Fe, Mn, Pb etc.) in the macroalgae, causing a significant spatial variation. There were also significant concentration differences between the young and old tissue parts in L. saccharina, L. digitata and A. esculenta. While Al, Fe, Mn, Pb were higher in the perennial parts (stipes and holdfast below meristematic region), Cd and As concentrations were significantly higher in the young blades above the meristematic region. Zn and Cr, on the other hand, showed little differences between the tissue parts. The highest metal concentrations were found in D. aculeata, which seems to be due to its filamentous fine branches leading to high surface/volume ratios. The lowest concentrations were found in the two Laminaria spp., the blades of which are thicker than D. aculeata and A. esculenta. No distinct signs of contamination were detected in the brown algal species analyzed. Added to this, the results of the present studies suggest the potential utility of L. saccharina, L. digitata and A. esculenta as biomonitors for metal pollution monitoring in this area.

북서태평양의 표층엽록소 변동성 (Variability of Surface Chlorophyll Concentration in the Northwest Pacific Ocean)

  • 박지수;석문식;윤석;유신재
    • Ocean and Polar Research
    • /
    • 제30권3호
    • /
    • pp.277-287
    • /
    • 2008
  • We collected information on seasonal and interannual variability of surface chlorophyll a concentration between 1997-2007 from the Northwest Pacific Ocean. Satellite data were used to acquire chlorophyll a and sea surface temperature from six regions: East Sea/Ulleung Basin, East China Sea, Philippin Sea, Warm Pool region, Warm Pool North region, and Warm Pool East region. Mixed layer depth (MLD) was calculated from temperature profiles of ARGO floats data in four of the six regions during 2002-2007. In the East Sea/Ulleung Basin, seasonal variability of chlorophyll a concentration was attributed to seasonal change of MLD, while there was no significant relationship between chlorophyll a concentration and MLD in the Warm Pool region. Interannual anomaly in sea surface temperature were similar among the East Sea, East China Sea, Philippin Sea, and Warm Pool North region. The anomaly pattern was reversed in the Warm Pool East region. However, the anomaly pattern in the Warm Pool region was intermediate of the two patterns. In relation to chlorophyll a, there was a reversed interannual anomaly pattern between Warm Pool North and Warm Pool East, while the anomaly pattern in the Warm Pool region was similar to that of Warm Pool North except for the El $Ni\tilde{n}o$ years (1997/1998, 2002/2003, 2006/2007). However, there was no distinct relationship among other seas. Interestingly, in the Warm Pool and Warm Pool East regions, sea surface temperature showed a pronounced inverse pattern with chlorophyll a. This indicates a strong interrelationship among sea surface temperature-MLD-chlorophyll a in the regions. In the Warm Pool and Warm Pool East, zonal distribution of chlorophyll a concentration within the past 10 years has shown a good relationship with sea surface temperature which reflects ENSO variability.

Modeling of temperature distribution in a reinforced concrete supertall structure based on structural health monitoring data

  • Ni, Y.Q.;Ye, X.W.;Lin, K.C.;Liao, W.Y.
    • Computers and Concrete
    • /
    • 제8권3호
    • /
    • pp.293-309
    • /
    • 2011
  • A long-term structural health monitoring (SHM) system comprising over 700 sensors of sixteen types has been implemented on the Guangzhou Television and Sightseeing Tower (GTST) of 610 m high for real-time monitoring of the structure at both construction and service stages. As part of this sophisticated SHM system, 48 temperature sensors have been deployed at 12 cross-sections of the reinforced concrete inner structure of the GTST to provide on-line monitoring via a wireless data transmission system. In this paper, the differential temperature profiles in the reinforced concrete inner structure of the GTST, which are mainly caused by solar radiation, are recognized from the monitoring data with the purpose of understanding the temperature-induced structural internal forces and deformations. After a careful examination of the pre-classified temperature measurement data obtained under sunny days and non-sunny days, common characteristic of the daily temperature variation is observed from the data acquired in sunny days. Making use of 60-day temperature measurement data obtained in sunny days, statistical patterns of the daily rising temperature and daily descending temperature are synthesized, and temperature distribution models of the reinforced concrete inner structure of the GTST are formulated using linear regression analysis. The developed monitoring-based temperature distribution models will serve as a reliable input for numerical prediction of the temperature-induced deformations and provide a robust basis to facilitate the design and construction of similar structures in consideration of thermal effects.