• Title/Summary/Keyword: Ni plating

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Electrochemical aspects of electroless nickel-boron plating (무전해 Ni 도금의 전기화학적 고찰)

  • 김영기;이원해
    • Journal of Surface Science and Engineering
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    • v.26 no.4
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    • pp.175-182
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    • 1993
  • Electroless plating of nickel was studied electrochemically in the presence of complexing agents. Nickel sulfate solution with dimethylamine borance(DMAB) as the reducing agent was used. Effects of temperature pH, concentration and complexing agents-citric acid, EDTA, tartaric acid-were studied.Experimental meas-urements showed that the rate of electroless nickel deposition was closely related to electrochemical parame-ters such as temdperature, pH, concentration and the properties of complexing agets.

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Effect of Phosphorous Acid Concentration on Mechanical Properties of Ni-P Electrodeposits (니켈-인 도금 층의 기계적 성질에 미치는 아인산 농도의 영향)

  • Kang, Soo Young;Yang, Seung gi;Hwang, Woon suk
    • Journal of Surface Science and Engineering
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    • v.48 no.3
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    • pp.100-104
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    • 2015
  • The nickel alloys gets a great deal of attention due to their good mechanical, chemical and magnetic properties. Especially Ni-P alloy systems are very attractive due to their good corrosion resistance and the wear resistance in important technological applications. In this study, the effects of phosphorus acid concentration in plating solution on composition of Ni-P alloy coatings were studied. The Ni-P electrodeposits of the various P contents were investigated in order to understand effect of the composition on mechanical properties of Ni-P electrodeposits. The mechanical properties of electrodeposits increased as the P content in electrodeposits increase. The results of mechanical properties were explained by grain size and P solid solution effect. The effects of heat treatment on mechanical properties of Ni-P alloy coatings were also studied.

An Improvement in the Properties of MH Electrode of Ni/MH Battery by the Copper Coating (Ni/MH 전지에서 Cu 도금에 의한 음극활물질의 전극 특성 향상)

  • Cho, Jin Hun;Kim, In Jung;Lee, Yun Sung;Nahm, Kee Suk;Kim, Ki Ju;Lee, Hong Ki
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.568-574
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    • 1997
  • The effect of microencapsulation of maetal hydride (MH) with copper on the electrode performance of a Ni/MH battery has been investigated. The MH electrodes were prepared with a combination of cold press and paste methods. The discharge capacity of the electrode increased with an addition of small amounts if CMC into the electrode, but decreased when heat-treated in an oxygen-free nitrogen flow. The capacity of a Cu-coated $LaNi_5$ electrode was higher than that of LaNi5electrode. The discharge capacity of the electrode prepared with Cu-coated $LaNi_5$ increased with the increase of copper content in the electrode. It is considered that the increase of copper content enhanced the current density on the electrode surface, leading to the increase of the discharge capacity The MH electrode coated by an acidic electroless plating method showed much higher discharge capacity than that using an alkaline electroless plating method. The discharge capacity of the $LaNi_{4.5}Al_{0.5}$ electrode was higher than that of the $LaNi_5$ electrode. Also, the effect of microencapsulation on the deactivation of $LaNi_5$ was studied using an absorption-desorption cycle in CO-containing hydrogen.

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A Study on the Manufacturing Process of Fe-Ti Type Electrode for Ni/MH Secondary Battery (Ni/MH 2차전지용 Fe-Ti계 전극 제조공정에 대한 연구)

  • Joung, Sang-sik;Kim, Ki-won;Ahn, Hyo-jun;Joung, Soon-dol
    • Journal of Hydrogen and New Energy
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    • v.9 no.2
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    • pp.65-75
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    • 1998
  • Five different processes were selected and tested to find an useful method of manufacturing Fe-Ti type electrode. Initially, FeTi alloy was prepared by melting in plasma arc furnace and then powdered for shaping. Electroless Ni plating on these powder particles before shaping improved the discharge characteristics. The effects of heat-treatments on the electrode characteristics were also investigated. The discharge capacities of electrods were increased with the increasing heat-treatment temperatures. When heat treated at $1000^{\circ}C$ after shaping, the best results were acquired in the discharge capacity and cycle life. Both electroless Ni plating and heat-treatment were appeared to be crucial for the performance improvement of FeTi type electrode. Fe-Ti -Mn electrodes were prepared according to the process suggested in this study and tested to verify the promising effects of that.

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Fabrication and Characteristics of Electroless Ni Bump for Flip Chip Interconnection (Flip Chip 접속을 위한 무전해 니켈 범프의 형성 및 특성 연구)

  • Jeon, Yeong-Du;Im, Yeong-Jin;Baek, Gyeong-Ok
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1095-1101
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    • 1999
  • Electroless Ni plating is applied to form bumps and UBM layer for flip chip interconnection. Characteristics of electroless Ni are also investigated. Zincate pretreatment is analyzed and plated layer characteristics are investigated according to variables like temperature, pH and heat treatment. Based on these observations, characteristics dependence to each variables and optimum electroless Ni plating conditions for flip-chip interconnection are suggested. Electroless Ni has 10wt% P, $60\mu\Omega$-cm resistivity, 500HV hardness and amorphous structure. It changes crystallized structure and hardness increases after heat treatment After interconnection of electroless Ni bumps by ACF flip chip method, we show their advantages and possibility in microelectronic package applications.

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