• Title/Summary/Keyword: Ni 용해

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의료용 Ti-Ni 합금의 개발 동향

  • Nam, Tae-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.7-7
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    • 2010
  • 형상기억합금은 합금이 갖는 형상기억효과 및 초탄성효과 때문에 학문적으로 공업적으로 큰 흥미를 끌어왔다. 형상 기억효과는 Au-Cd 합금과 Cu-Zn 합금에서 최초로 발견되었지만 당시에는 크게 주목을 받지 못하였다. 그 후 1962년 Ti-Ni 합금에서 형상기억효과가 발견된 이래로 크게 주목을 받게 되었고, 곧바로 상용화를 위한 노력이 이어져 리벳, 열엔진, 커플링, 회로차단기 등에 적용이 시도되었다. 현재까지 약 300여종에 이르는 형상기억합금이 개발되어 있지만 형상기억효과의 안정성, 우수성, 내식성, 가공성, 내피로성, 내마모성이 우수한 Ti-Ni 합금이 가장 실용화에 적합한 합금으로 인식되고 있다. Ti-Ni합금은 1960년대에 개발되었지만 의료분야에 적용되기 시작한 것은 1980년대이고, 그 후 미국의 FDA가 Ti-Ni 합금으로 제조된 몇몇 3급(Class III) 임플란트를 인증하면서 시장규모도 폭발적으로 증가하고 있다. 일본의 경우 1980년대 초부터 Ti-Ni 합금을 치과용 임플란트로써 사용하여 왔, 독일, 중국, 러시아도 1980년대부터 임상에 적용해 왔다. 우리나라는 2004년 식약청(식품의약안정청)으로부터 제조 및 판매가 허가되어 현재 실제 임상에 적용되고 있다. 이와 같이 Ti-Ni 합금이 의료용 금속재료로서 널리 쓰이게 된 가장 근본적인 이유는 말할 나위 없이 합금이 갖는 형상기억효과 및 초탄성효과 때문이다. 본 강연에서는 Ti-Ni 합금을 의료용 금속재료의 입장에서 재조명해보고, 본 합금이 의료용 금속재료로서 어떠한 장점이 있으며, 그러한 장점을 의료분야에서 어떻게 응용하고 있는가에 대해 소개하고자 한다. 또한 의료용 Ti-Ni 합금에서 향후 개선되어야 할 요소에 대해서도 논의하고자 한다.

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A study on the effect of alumina coating on NiO dissolution in molten carbonate fuel cell (용융탄산염형 연료전지의 NiO 공기극의 용해거동에 미치는 알루미나 코팅효과에 대한 연구)

  • Ryu B. H.;Yoon S. P.;Han J;Nam S. W.;lim T.-H.;Hong S.-A.
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.64-71
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    • 2005
  • The stability of alumina-coated NiO cathodes was studied in $Li_{0.62}/K_{0.38}$ molten carbonate electrolyte. Alumina was effectively coated on the porous Ni plate using galvanostatic pulse plating method. The deposition mechanism of alumina was governed by the concentration of hydroixde ions near the working electrode, which was controlled by the temperature of bath solution. Alumina-coated NiO cathodes were formed to $A1_2O_3-NiO$ solid solution by the oxidation process and their Ni solubilities were were than that of NiO up to the immersion time of 100h. However, their Ni solubilities increased and were similar to that of the bare NiO cathode after 100h. It was because aluminum into the solid solution was segregated to $\alpha-LiAlO_2$ on the NiO and its Product did not Play a role of the Physical barrier against NiO dissolution.

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The Effects of Current Density on the Grain Size of Electroplated Thick Film Nickel(Ni) by Using Ni Metal Powder Dissolved Chloride Bath (금속분말 Ni을 용해 한 Chloride Bath로 도금된 니켈후막의 입자크기에 대한 전류밀도 영향)

  • Park, Keun Yung;Uhm, Young Rang;Choi, Sun Ju;Park, Deok-Yong
    • Journal of the Korean Magnetics Society
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    • v.23 no.1
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    • pp.12-17
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    • 2013
  • Nanocrystalline nickel (Ni) tick films were synthesized by direct current electrodeposition at current density from 1 to $30mA/cm^2$ and pH = 4. The basic composition of the bath, which was prepared by dissolving Ni metal particles in HCl, was 0.2M Ni ions. The effects of the current density on the average grain size of Ni deposits were investigated by XRD and SEM techniques. The results showed that the surface roughness was decreased as the saccharin addition was increased up to 2 g/l. The experimental results showed that the increase in the current density had a considerable effect on the average grain size of the Ni deposits. The perpendicular magnetization was raised as the thickness of coating layer was increased.

The Development of ZVZCS type Battery Charger for High Speed Trail Car with Ni-Cd Battery Charging Algorithm (Ni-Cd전지용 충전 알고리즘을 이용한 고속전철용 ZVZCS형 충전장치개발)

  • 최욱돈;이종필;이재문;김연준
    • The Transactions of the Korean Institute of Power Electronics
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    • v.5 no.5
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    • pp.493-500
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    • 2000
  • The battery charger for high speed trail car is very important power source for the purpose of safety and system stability It provides control power of VVVF, CVCF, DC/DC converter and inverter for traction motor. This paper included power circuit of the ZVZCS type battery charger for high speed trail car and battery charging algorithm. Also the optimum parallel operation of 50kW battery charger for high speed trail car, and charring control method of Ni-Cd battery illustrates validity and effectiveness through the experiments.

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Railway system standby power Nickel metal hydride battery (철도시스템비상전원용 니켈수소(NiMH)전지)

  • Park, Dong-Pil
    • Proceedings of the KSR Conference
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    • 2006.11b
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    • pp.636-645
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    • 2006
  • In order to use railway system standby power, produced 160Ah NiMH battery that would be able to substitute the lead acid battery or NiCd battery form which contain the toxic material in environment, using parallel connected 80Ah NiMH battery. And in order to develop proper electrode in the 160Ah NiMH battery, tested high rate discharge performance of the ternary electrolyte. 160Ah NiMH battery evaluated the various test in order to use railway system standby power.

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State-of-the-Art of the Ni-bearing Ferritic Steels for LNG Storage Facilities (액화천연가스 저장용 폐라이트계 Ni 첨가강의 물성 및 개발 동향)

  • Han Seung Zeon;Kim Hyoung-Sik;Hong Seong-Ho;Kim Sung-Joon
    • Journal of the Korean Institute of Gas
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    • v.2 no.3
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    • pp.78-87
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    • 1998
  • The mechanical properties, heat treatment and the history for the development of Ni-bearing ferritic steels for the application at low temperatures are reviewed. Ni-bearing ferritic steels are classified into $2-3\%$ Ni steels, $5.5\%$ Ni steel, $9\%$ Ni steel and $13\%$ Ni steel., of which $9\%$ Ni steels are most widely used for the large LNG storage tanks owing to their encellent fracture toughness up to $-196^{\circ}C$. The effect of retained austenite on the tensile properties and toughness was precisely discussed. As the size of LNG storage tank increases, thicker plates are needed. Thus, the recent efforts for the improvement of low temperature toughness and homogeneity are also introduced.

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Crystal Structure of $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves Phase Alloys for MH Battery Application (MH전지용 $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves합금의 결정구조)

  • Kim, Won-Baek;Seo, Chang-Yeol;Choe, Guk-Seon;Kim, In-Gon
    • Korean Journal of Materials Research
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    • v.7 no.3
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    • pp.234-243
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    • 1997
  • The crystal structure of arc melted $ZrV_{x}Mn_{1-x}Ni_{1.0},\;ZrV_{x}Mn_{0.8-x}Ni_{1.2},\;ZrV_{x}Mn_{0.6-x}Ni_{1.4}$ alloys which are known to have AB2 type Laves structure was investigated. They had mixed phases of C14 and C15. The radius ratio ($r_{A}/r_{B}$) of atoms in A site to that of B site was found to be an important parameter in explaining the omposition dependence of the crystal structure The C15 structure showed a linear increase with the ratio in as-cast conditions. However, the annealed alloys revealed a definite ratio at which the stability of both phases are divided distinctly. The composition of the alloys could be closely controlled by maintaining the argon pressure in the chamber over 1 arm during arc melting. In contrast, the alloy ingot melted in VIM showed a significant loss of hln.

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Railway System Standby Power Nickel Metal Hydride Battery (철도시스템비상전원용 니켈수소(NiMH)전지)

  • Kim, Sung-Yong;Park, Dong-Pil
    • Journal of the Korean Society for Railway
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    • v.12 no.6
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    • pp.873-877
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    • 2009
  • In order to use railway system standby power, produced 160Ah NiMH battery that would be able to substitute the lead acid battery or NiCd battery form which contain the toxic material in environment, using parallel connected 80Ah NiMH battery. And in order to develop proper electrode in the 160Ah NiMH battery, tested high rate discharge performance of the ternary electrolyte. 160Ah NiMH battery evaluated the various test in order to use railway system standby power.