• Electronics and Telecommunications Trends
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• v.36 no.3
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• pp.76-86
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• 2021

Technologies for lithium secondary batteries are now increasingly expanding to simultaneously improve the safety and higher energy and power densities of large-scale battery systems, such as electric vehicles and smart-grid energy storage systems. Next-generation lithium batteries, such as lithium-sulfur (Li-S) and lithium-air (Li-O₂) batteries by adopting solid electrolytes and lithium metal anode, can be a solution for the requirements. In this analysis of battery technology trends, solid electrolytes, including polymer (organic), inorganic (oxides and sulfides), and their hybrid (composite) are focused to describe the electrochemical performance achievable by adopting optimal components and discussing the interfacial behaviors that occurred by the contact of different ingredients for safe and high-energy lithium secondary battery systems. As next-generation rechargeable lithium batteries, Li-S and Li-O₂ battery systems are briefly discussed coupling with the possible use of solid electrolytes. In addition, Electronics and Telecommunications Research Institutes achievements in the field of solid electrolytes for lithium rechargeable batteries are finally introduced.

• Ceramist
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• v.21 no.4
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• pp.312-330
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• 2018

Energy storage/conversion has become crucial not only to meet the present energy demand but also more importantly to sustain the modern society. Particularly, electrical energy storage is critical not only to support electronic, vehicular and load-levelling applications but also to efficiently commercialize renewable energy resources such as solar and wind. While Li-ion batteries are being intensely researched for electric vehicle applications, there is a pressing need to seek for new battery chemistries aimed at stationary storage systems. In this aspect, Zn-ion batteries offer a viable option to be utilized for high energy and power density applications since every intercalated Zn-ion yields a concurrent charge transfer of two electrons and thereby high theoretical capacities can be realized. Furthermore, the simplicity of fabrication under open-air conditions combined with the abundant and less toxic zinc element makes aqueous Zn-ion batteries one of the most economical, safe and green energy storage technologies with prospective use for stationary grid storage applications. Also, Zn-ion batteries are very safe for next-generation technologies based on flexible, roll-up, wearable implantable devices the portable electronics market. Following this advantages, a wide range of approaches and materials, namely, cathodes, anodes and electrolytes have been investigated for Zn-ion batteries applications to date. Herein, we review the progresses and major advancements related to aqueous. Zn-ion batteries, facilitating energy storage/conversion via $Zn^{2+}$ (de)intercalation mechanism.

• Asian Journal of Innovation and Policy
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• v.12 no.3
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• pp.345-362
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• 2023

As the widespread adoption and proliferation of electric vehicles continue, the secondary battery market is experiencing rapid growth. However, lithium-ion batteries, which constitute a majority of secondary batteries, present high risks of fire and explosion. Solid-state batteries are thus garnering attention as the next-generation batteries since they eliminate fire hazards and significantly reduce the risk of explosions. Against this background, the study aimed to analyze research trends and provide insights by examining 2,927 domestic papers related to solid-state batteries over the past decade (2013-2022). Specifically, we used topic modeling to extract major keywords associated with solid-state batteries research and to explore the network characteristics across major topics. The changes in research on solid-state batteries were analyzed in-depth by calculating topic dominance by year. The findings provide an overview of the emerging trends in domestic solid-state battery research, and might serve as a valuable reference in shaping long-term research directions.

• Journal of Information Technology Applications and Management
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• v.30 no.1
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• pp.1-9
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• 2023

Interest in the future of the battery market is growing as Tesla announces plans to increase production of electric vehicles and to produce batteries. Tesla announced an action plan to reduce battery prices by 56% through 'Battery Day', which included expansion of factories to internalize batteries and improvement of materials and production technology. In the trend of automobile electrification, the expansion of the battery market, which accounts for 40% of the cost of electric vehicles, is inevitable, and the size of the electric vehicle battery market in 2026 is expected to increase more than five times compared to 2016. With the development of materials and process technology, the energy density of electric vehicle batteries is increasing while the price is decreasing. Soon, electric vehicles and internal combustion locomotives are expected to compete on the same line. Recently, the mileage of electric vehicles is approaching that of an internal combustion locomotive due to the installation of high-capacity batteries. In the EV battery market, Korean, Chinese and Japanese companies are fiercely competing. Based on market share in the first half of 2020, LG Chem, CATL, and Panasonic are leading the EV battery supply, and the top 10 companies included 3 Korean companies, 5 Chinese companies, and 2 Japanese companies. All-solid, lithium-sulfur, sodium-ion, and lithium air batteries are being discussed as the next-generation batteries after lithium-ion, among which all-solid-state batteries are the most active. All-solid-state batteries can dramatically improve stability and charging speed by using a solid electrolyte, and are excellent in terms of technology readiness level (TRL) among various technology alternatives. In order to increase the competitiveness of the battery industry in the future, efforts to increase the productivity and economy of electric vehicle batteries are also required along with the development of next-generation battery technology.

• Journal of the Korean Electrochemical Society
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• v.13 no.1
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• pp.45-49
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• 2010

The rechargeable Zn-air battery is considered as one of the potential candidates for the next generation secondary batteries due to its many advantages. However, its further applications and commercialization have been limited by the complexity of the reactions on air electrode which are oxygen reduction and evolution reactions (ORR/OER) upon discharging and charging processes, respectively. In the present study, lanthanum was impregnated into a commercial Pt/C gas diffusion electrode, and it clearly verified significantly enhanced cycling stability and reversibility. The results presented in this study show the possibility of repeated charge/discharge processes for Zn-air batteries with a La-loaded air electrode, and they demonstrate the potential as a promising next generation secondary battery.

• Journal of the Semiconductor & Display Technology
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• v.22 no.1
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• pp.28-32
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• 2023

Recently, the use of stable lithium nanostructures as substrates and electrodes for secondary batteries can be a fundamental alternative to the development of next-generation system semiconductor devices. However, lithium structures pose safety concerns by severely limiting battery life due to the growth of Li dendrites during rapid charge/discharge cycles. Also, enabling long cyclability of high-voltage oxide cathodes is a persistent challenge for all-solid-state batteries, largely because of their poor interfacial stabilities against oxide solid electrolytes. For the development of next-generation system semiconductor devices, solid electrolyte nanostructures, which are used in high-density micro-energy storage devices and avoid the instability of liquid electrolytes, can be promising alternatives for next-generation batteries. Nevertheless, poor lithium ion conductivity and structural defects at room temperature have been pointed out as limitations. In this study, a low-dimensional Graphene Oxide (GO) structure was applied to demonstrate stable operation characteristics based on Li+ ion conductivity and excellent electrochemical performance. The low-dimensional structure of GO-based solid electrolytes can provide an important strategy for stable scalable solid-state power system semiconductor applications at room temperature. The device using uncoated bare NCA delivers a low capacity of 89 mA h g-1, while the cell using GO-coated NCA delivers a high capacity of 158 mA h g−1 and a low polarization. A full Li GO-based device was fabricated to demonstrate the practicality of the modified Li structure using the Li-GO heterointerface. This study promises that the lowdimensional structure of Li-GO can be an effective approach for the stabilization of solid-state power system semiconductor architectures.

• Journal of Powder Materials
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• v.31 no.4
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• pp.293-301
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• 2024

All-solid-state lithium batteries (ASSLBs) are receiving attention as a prospective next-generation secondary battery technology that can reduce the risk of commercial lithium-ion batteries by replacing flammable organic liquid electrolytes with non-flammable solid electrolytes. The practical application of ASSLBs requires developing robust solid electrolytes that possess ionic conductivity at room temperature on a par with that of organic liquids. These solid electrolytes must also be thermally and chemically stable, as well as compatible with electrode materials. Inorganic solid electrolytes, including oxide and sulfide-based compounds, are being studied as promising future candidates for ASSLBs due to their higher ionic conductivity and thermal stability than polymer electrolytes. Here, we present the challenges currently facing the development of oxide and sulfide-based solid electrolytes, as well as the research efforts underway aiming to resolve these challenges.

• Ceramist
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• v.22 no.4
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• pp.402-416
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• 2019

The development of next-generation secondary batteries, including lithium-ion batteries (LIB), requires performance enhancements such as high energy/high power density, low cost, long life, and excellent safety. The discovery of new materials with such requirements is a challenging and time-consuming process with great difficulty. To pursue this challenging endeavor, it is pivotal to understand the structure and interface of electrode materials in a multiscale level at the atomic, molecular, macro-scale during charging / discharging. In this regard, various advanced material characterization tools, including the first-principle calculation, high-resolution electron microscopy, and synchrotron-based X-ray techniques, have been actively employed to understand the charge storage- and degradation-mechanisms of various electrode materials. In this article, we introduce and review recent advances in in-situ synchrotron-based x-ray techniques to study electrode materials for LIBs during thermal degradation and charging/discharging. We show that the fundamental understanding of the structure and interface of the battery materials gained through these advanced in-situ investigations provides valuable insight into designing next-generation electrode materials with significantly improved performance in terms of high energy/high power density, low cost, long life, and excellent safety.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.287-293
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• 2015

This paper discusses quantitative analyses of patents published for cathode active materials for lithium secondary batteries based on layer structure. Numbers of the patents analyzed were 356, 1628, 2915, 439, and 611 for Korea, USA, Japan, Europe, and PCT (WO), respectively. Trends of improved technologies and alternative technologies concerning lithium cobalt, from 1991 to 2012 were examined and the patent shares distribution of each principal countries about lithium secondary battery technologies were also scrutinized. The number of patents for the mixed structure technology and next-generation lithium secondary battery technology increased numerously in 2000. Particularly in 2005, lots of patents were also published and SANYO (34.5%), SONY (17.5%), LG (7%), and SAMSUNG (5.5%) possessed leading patent applicants. Finally, the research focus on cathode active materials for lithium secondary batteries was confirmed by bubble chart distributions for component-by-step process.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.2
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• pp.215-222
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• 2024

Ni-rich cathode materials have been developed as the most promising candidates for next-generation cathode materials for lithium-ion batteries because of their high capacity and energy density. In particular, the electrochemical performance of lithium-ion batteries could be enhanced by increasing the contents of nickel ion. However, there are still limitations, such as low structural stability, cation mixing, low capacity retention and poor rate capability. Herein, we have successfully developed the nanorod-type Ni-rich cathode materials by using co-precipitation method. Particularly, the nanorod-type primary particles of LiNi_0.7Co_0.15Mn_0.15O₂ could facilitate the electron transfer because of their longitudinal morphology. Moreover, there were holes at the center of secondary particles, resulting in high permeability of the electrolyte. Lithium-ion batteries using the prepared nanorod-type LiNi_0.7Co_0.15Mn_0.15O₂ achieved highly improved electrochemical performance with a superior rate capability during battery cycling.