• Title/Summary/Keyword: Negative capacitance

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An Omnidirectional Planar Antenna with Four Stepped L-shape slots (4개의 계단형 L-슬롯 구조를 갖는 전방향성 평면 안테나)

  • Nam, Sung-Soo;Lee, Hong-Min
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.1 no.3
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    • pp.3-8
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    • 2008
  • In this paper, an planar antenna which has omnidirectional radiation pattern in H-plane and low profile is proposed. By adding inductance elements of an ENG shell structure, a capacitance element of an electrically small antenna is easily achieved with impedance matching. An ENG shell structure is consist of a inductive loading structure which has symmetrical four stepped L-shape slots. The simulated result shows, the impedance bandwidth of the proposed antenna is 150MHz (2.5 ~ 2.65GHz). The simulated maximum radiation gain of proposed antenna is 1.12 dBi at center frequency 2.56GHz. Omnidirectional radiation pattern is achieved. The proposed antenna will be applied to wireless lan access point system.

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Dependency of the Device Characteristics on Plasma Nitrided Oxide for Nano-scale PMOSFET (Nano-scale PMOSFET에서 Plasma Nitrided Oixde에 대한 소자 특성의 의존성)

  • Han, In-Shik;Ji, Hee-Hwan;Goo, Tae-Gyu;You, Ook-Sang;Choi, Won-Ho;Park, Sung-Hyung;Lee, Heui-Seung;Kang, Young-Seok;Kim, Dae-Byung;Lee, Hi-Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.569-574
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    • 2007
  • In this paper, the reliability (NBTI degradation: ${\Delta}V_{th}$) and device characteristic of nano-scale PMOSFET with plasma nitrided oxide (PNO) is characterized in depth by comparing those with thermally nitrided oxide (TNO). PNO case shows the reduction of gate leakage current and interface state density compared to TNO with no change of the $I_{D.sat}\;vs.\;I_{OFF}$ characteristics. Gate oxide capacitance (Cox) of PNO is larger than TNO and it increases as the N concentration increases in PNO. PNO also shows the improvement of NBTI characteristics because the nitrogen peak layer is located near the $Poly/SiO_2$ interface. However, if the nitrogen concentration in PNO oxide increases, threshold voltage degradation $({\Delta}V_{th})$ becomes more degraded by NBT stress due to the enhanced generation of the fixed oxide charges.

Self-Supported NiSe/Ni Foam: An Efficient 3D Electrode for High-Performance Supercapacitors

  • Zhang, Jingtong;Zhao, Fuzhen;Du, Kun;Zhou, Yan
    • Nano
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    • v.13 no.11
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    • pp.1850136.1-1850136.12
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    • 2018
  • Three-dimensional (3D) mixed phases NiSe nanoparticles growing on the nickel foam were synthesized via a simple one-step hydrothermal method. A series of experiments were carried out to control the morphology by adjusting the amount of selenium in the synthetic reaction. Meanwhile, the as-prepared novel column-acicular structure NiSe exist three advantages including ideal electrical conductivity, high specific capacity and high cycling stability. It delivered a high capacitance of $10.8F\;cm^{-2}$ at a current density- of $5mA\;cm^{-2}$. An electrochemical capacitor device operating at 1.6 V was then constructed using NiSe/NF and activated carbon (AC) as positive and negative electrodes. Moreover, the device showed high energy density of $31W\;h\;kg^{-1}$ at a power density of $0.81kW\;kg^{-1}$, as well as good cycling stability (77% retention after 1500 cycles).

Design of 9 kJ/s High Voltage LiPo Battery based 2-stage Capacitor Charger (배터리 기반 2단 충전 9 kJ/s 고전압 충전기 설계)

  • Cho, Chan-Gi;Jia, Ziyi;Ryoo, Hong-Je
    • The Transactions of the Korean Institute of Power Electronics
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    • v.24 no.4
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    • pp.268-272
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    • 2019
  • A lithium polymer battery-based 9 kJ/s high-voltage capacitor charger, which comprises two stages, is proposed. A modified LCC resonant converter and resonant circuit are introduced at the first and second stages, respectively. In the first stage, the methods for handling low-voltage and high-current batteries are considered. Delta-wye three-phase transformers are used to generate a high output voltage through the difference between the phase and line-to-line voltages. Another method is placing the series resonant capacitor of the LCC resonant components on the transformer secondary side, which conducts considerably low current compared with the transformer primary side. On the basis of the stable operation of the first charging stage, the secondary charging stage generates final output voltage by using the resonance. This additional stage protects the rectifying diodes from the negative voltage when the output capacitor is discharged for a short time. The inductance and capacitance of the resonance components are selected by considering the resonance charging time. The design procedure for each stage with the aforementioned features is suggested, and its performance is verified by not only simulation but also experimental results.

Surface Chemical Properties of Aqueous Kaolinite and Halloysite: Surface Complexation Modeling (수용액 내 캐올리나이트와 할로이사이트의 표면화학 특성: 표면복합반응 모델링)

  • 장세정;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.157-168
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    • 2004
  • The surface chemical properties of aqueous kaolinite and halloysite were studied using a potentiometric titration experiment and a computer program FITEQL3.2. Among the surface complexation models a constant capacitance model was selected for this study. The 2 sites - 3 p $K_{a}$ s model, in which the surfaces were assumed to have tetrahedral and octahedral sites, was reasonable for the description of the experimental data. The surface charges of both minerals were negative above pH of 4. The higher the pH, the lower the proton surface charge densities of both minerals. The ≡ $SiO^{[-10]}$ site played an important role in cation adsorption in acid and neutral pH range; whereas the ≡ Al $O^{[-10]}$ site was in an alkaline pH range. The optimized intrinsic constants of kaolinite, p $K_{a2(Si)}$$^{int}$, p $K_{al(Al)}$$^{int}$ and p $K_{a2(Al)}$$^{int}$ were 4.436, 4.564, and 8.461 respectively, and those of halloysite were 7.852, 3.885, and 7.084, respectively. The total Si and Al surface sites concentrations of kaolinite were 0.215 and 0.148 mM, and those of halloysite were 0.357 and 0.246 mM. The ratio of Si and Al surface site densities ([≡SiOH]:[≡AlOH]) of both minerals was 1 : 0.69. The total surface site density of kaolinite, 3.774 sites/n $m^2$, was 1.6 times larger than that of halloysite, 2.292 sites/n $m^2$./TEX>.

Electrochemical Characteristics of Setaria viridis-Based Carbon Anode Materials Prepared by Thermal Treatment for Lithium-Ion Secondary Batteries (열처리에 의해 제조된 강아지풀 기반 리튬 이온 이차전지용 탄소 음극재의 전기화학적 특성)

  • Dong Ki Kim;Chaehun Lim;Seongjae Myeong;Naeun Ha;Chung Gi Min;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.140-147
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    • 2024
  • In order to increase the utilization of biomass, an electrochemical performance was considered after manufacturing a carbon anode material (SV-C) for a Setaria viridis-based lithium ion secondary battery through a heat treatment process. When the heat treatment temperature of the Setaria viridis is as low as 750 ℃, the capacitance (1003.3 mAh/g, at 0.1 C) is high due to the negative (-) charge of oxygen present on the surface attracting lithium, along with the low crystallinity and high specific surface area (126 m2/g), but the capacity retention rate is believed to be as low as 61.0% (at 500 cycles and 1 C). In addition, it was confirmed that when the heat treatment temperature increased to 1150 ℃, the carbon layer was condensed to be excellent in arrangement, and the structural defects were reduced, resulting in a significant reduction in the specific surface area (32 m2/g) of the pores. Furthermore, when the surface defects of the anode material are reduced and the crystallinity is increased, the capacity retention rate is as high as 89.7% (at 500 cycles and 1 C), but the degree of defects is small, the active point is reduced, and the specific capacity is considered to be very low at 471.7 mAh/g. In the scope of this study, it was found that in the case of the Setaria viridis-based carbon anode material manufactured according to the heat treatment temperature, the surface oxygen content and crystallinity have higher reliability on the electrochemical properties of the anode material than the specific surface area.

NH3 분위기 후열처리에 따른 SiC 기판 위에 성장된 HfO2 박막의 계면 변화 연구

  • Gwon, Se-Ra;Park, Hyeon-U;Choe, Min-Jun;Jeong, Gwon-Beom
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.299-299
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    • 2016
  • SiC는 넓은 에너지갭 (Eg=~3.4 eV)을 갖는 반도체로써, 고전압, 고온에서 동작이 가능하여 기존의 Si기반의 파워디바이스를 대체하기 위한 물질로 많은 연구가 이루어지고 있다. 파워 디바이스의 성능 향상을 위해서는 기판과 절연체 사이의 계면에 생성되는 계면 결함을 감소시켜야 한다. 따라서 본 연구에서는 SiC 기판에 high-k 물질인 HfO2를 증착하여 HfO2/SiC 계면에 유도된 결함을 분석하고 이를 감소시킬 수 있는 방법에 대한 연구를 수행하였다. HfO2 박막은 atomic-layer-deposition (ALD) 방법을 이용하여 SiC 기판 위에 $200^{\circ}C$에서 증착하였다. HfO2 박막 증착 후 NH3 분위기에서 rapid thermal annealing 방법을 이용하여 $600^{\circ}C$에서 1분 동안 열처리 진행하였다. Current-voltage (I-V) 측정을 통해 열처리 전 HfO2/SiC의 절연파괴 전압이 약 8.3 V 임을 확인하였다. NH3 열처리 후 HfO2/SiC의 절연파괴 전압이 10 V로 증가하였으며 누설 전류가 크게 감소하는 것을 확인하였다. 또한 capacitance-voltage (C-V) 측정을 통해 열처리 후 flat band voltage가 negative 방향에서 positive 방향으로 이동함을 확인하였고, 이를 통해 NH3 열처리 방법이 HfO2/SiC 계면에 존재하는 결함을 감소시킬 수 있음을 확인하였다. 전자 구조상의 conduction band edge에 존재하는 결함 준위를 분석하기 위해 x-ray absorption spectroscopy (XAS) 분석을 실시하였고, 열처리 전 HfO2/SiC 계면에 많은 결함 준위가 존재함을 확인하였으며, x-ray photoelectron spectroscopy (XPS) 분석을 통해 이 결함 준위가 oxygen deficiency state과 관련됨을 알 수 있었다. NH3 열처리 후 결과와 비교해보면, oxygen deficiency state가 감소함을 확인하였으며 이로 인해 conduction band edge에 존재하는 결함 준위가 감소함을 알 수 있었다. 따라서, NH3 열처리 방법을 이용하여 HfO2/SiC 계면에 존재하는 결함을 감소시킬 수 있으며, HfO2/SiC의 물리적, 전기적 특성을 향상시킬 수 있다는 결과를 도출하였다.

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Non-Foster Matching Circuit Design to Improve VHF- and UHF-Band Small Antenna Impedance Matching (VHF 및 UHF 대역 소형 안테나 매칭성능 개선을 위한 비 포스터 정합회로 설계)

  • Go, Jong-Gyu;Chung, Jae-Young
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.3
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    • pp.159-166
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    • 2018
  • Herein, a non-Foster matching circuit is designed to improve the impedance matching characteristics of small antennas in the VHF and UHF bands. The proposed non-Foster circuit is designed to operate with negative capacitance in a wide frequency band from 50 MHz to 1,000 MHz for use in various communication bands. To ensure the stability of the non-Foster circuit with conditional stability, the open-circuit stability condition of Linvill was satisfied, and the circuit was fabricated using the FR-4 substrate. The fabricated non-Foster circuit was combined with a small antenna to verify its performance by measuring the return loss and received power in the FM, DMB, and GSM bands. The measured return loss was improved from -6 dB to -30 dB, and the measured received power was improved from 0.5 dBm to 5.2 dBm.

Electrical characteristics of 4H-SiC MIS Capacitors With Ni/CNT/SiO2 Structure (Ni/CNT/SiO2 구조의 4H-SiC MIS 캐패시터의 전기적 특성)

  • Lee, Taeseop;Koo, Sang-Mo
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.620-624
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    • 2014
  • In this study, the electrical characteristics of Ni/CNT/$SiO_2$ structures were investigated in order to analyze the mechanism of carbon nanotubes in 4H-SiC MIS device structures. We fabricated 4H-SiC MIS capacitors with or without carbon nanotubes. Carbon nanotubes were dispersed by isopropyl alcohol. The capacitance-voltage (C-V) is characterized at 300 to 500K. The experimental flat-band voltage ($V_{FB}$) shift was positive. Near-interface trapped charge density and oxide trapped charge density values of Ni/CNT/$SiO_2$ structure were less than values of reference samples. With increasing temperature, the flat-band voltage was negative. It has been found that its oxide quality is related to charge carriers or defect states in the interface of 4H-SiC MIS capacitors. Gate characteristics of 4H-SiC MIS capacitors can be controlled by carbon nanotubes between Ni and $SiO_2$.

Impedance Characteristics of the Gel Type VRLA Battery at the Various State-of-Charge (겔식 납축 전지의 충전상태에 따른 임피던스 특성 연구)

  • An, Sang-Yong;Jeong, Euh-Duck;Won, Mi-Sook;Shim, Yoon-Bo
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.33-36
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    • 2008
  • In the present study, impedance spectrometry has been used for predicting State-of-Charge (SoC) of gel type, Valve Regulated Lead Acid (VRLA), battery. The impedance measurements of VRLA battery (2V/1.2 Ah) at various SoC were made over the frequency range from 100kHz to 10mHz with an amplitude 10 mV. The impedance parameters have been evaluated by the analysis of the data using an equivalent circuit and a complex non-linear least squares (CNLS) fitting method. The charge transfer resistance values and double layer capacitance values of the positive electrode were higher than those of the negative electrode. The gel resistance values increased with decreasing in SoC. This indicates that the gel resistance is an important parameter for predicting SoC of VRLA battery.