Nano

SKKU Advanced Institute of Nano Technology (성균관대학교 성균나노과학기술원)
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Self-Supported NiSe/Ni Foam: An Efficient 3D Electrode for High-Performance Supercapacitors

  • Zhang, Jingtong (State Key Laboratory of Heavy Oil Processing China University of Petroleum) ;
  • Zhao, Fuzhen (State Key Laboratory of Heavy Oil Processing China University of Petroleum) ;
  • Du, Kun (College of Science China University of Petroleum) ;
  • Zhou, Yan (State Key Laboratory of Heavy Oil Processing China University of Petroleum)
  • Received : 2018.08.03
  • Accepted : 2018.10.22
  • Published : 2018.11.30
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Abstract

Three-dimensional (3D) mixed phases NiSe nanoparticles growing on the nickel foam were synthesized via a simple one-step hydrothermal method. A series of experiments were carried out to control the morphology by adjusting the amount of selenium in the synthetic reaction. Meanwhile, the as-prepared novel column-acicular structure NiSe exist three advantages including ideal electrical conductivity, high specific capacity and high cycling stability. It delivered a high capacitance of $10.8F\;cm^{-2}$ at a current density- of $5mA\;cm^{-2}$. An electrochemical capacitor device operating at 1.6 V was then constructed using NiSe/NF and activated carbon (AC) as positive and negative electrodes. Moreover, the device showed high energy density of $31W\;h\;kg^{-1}$ at a power density of $0.81kW\;kg^{-1}$, as well as good cycling stability (77% retention after 1500 cycles).

Keywords

Acknowledgement

Supported by : Shandong Provincial Natural Science Foundation, National Natural Science Foundation of China

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