• Title/Summary/Keyword: Natural organic carbon

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Effects of Aging and Soil Texture on Composting of Diesel-Contaminated Soil (디젤오염기간 및 토성이 오염토양 콤포스팅 처리에 미치는 영향)

  • Choi, Jung-Young;Namkoong, Wan;Park, Joon-Seok;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.132-139
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    • 2002
  • This study was carried out to investigate the effects of aging and soil texture on composting of diesel-contaminated soil. The soils used for this study were silt loam and sand. Target contaminant, diesel oil, was spiked at 10,000mgTPH/kg of dry soil. Aging times of diesel-contaminated soils were 15days and 60days, respectively. Fresh diesel-contaminated soil was also investigated. Moisture content was controlled to 70% of soil field capacity. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was below 2% of initial concentration. n-Alkanes lost by volatilization were mainly by the compounds of C10 to C17. Diesel in contaminated soil was mainly removed by biodegradation mechanism. First order degradation rate constant of TPH in sandy soil was ranged from 0.081 to 0.094/day, which is higher than that in silt loam(0.056-0.061/day). From fresh to 60day-aged soils, there was little difference of TPH biodegradation rate between the soils. Carbon recovery ranged from 0.61 to 0.89. TPH degradation rate was highly correlated with $CO_2$ production rate.

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A Study on Phosphorus and Nitrogen Removal with Unit Operation in the Ferrous Nutrient Removal Process (철전기분해장치(FNR)에서 단위공정에 따른 질소와 인의 제거)

  • Kim, Soo Bok;Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.39 no.1
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    • pp.83-89
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    • 2013
  • Objectives: The purpose of this experiment was to illuminate the relationship between the phosphorus removal rate of unit operation and the phosphorus removal rate of phosphorus volume loading in the Ferrous Nutrient Removal process, which consists of an anoxic basin, oxic basin, and iron precipitation apparatus. Methods: This study was conducted in order to improve the effect of nitrogen and phosphorus removal in domestic wastewater using the FNR (Ferrous Nutrient Removal) process which features an iron precipitation reactor in anoxic and oxic basins. The average concentration of TN and TP was analyzed in a pilot plant ($50m^3/day$). Results: The removal rate of T-N and T-P were 66.5% and 92.8%, respectively. The $NH_3-N$ concentration of effluent was 2.62 mg/l with nitrification in the oxic basin even though the influent was 17.7 mg/l. The $NO_3$-N concentration of effluent was 5.83 mg/l through nitrification in oxic basin even though the influent and anoxic basin were 0.82 mg/l and 1.00 mg/l, respectively. The specific nitrification of the oxic basin ($mg.NH_3$-Nremoved/gMLVSSd) was 16.5 and specific de-nitrification ($mg.NO_3$-Nremoved/gMLVSSd) was 90.8. The T-P removal rate was higher in the oxic basin as T-P of influent was consumed at a rate of 56.3% in the anoxic basin but at 90.3% in the oxic basin. The TP removal rate (mg.TP/g.MLSS.d) ranged from 2.01 to 4.67 (3.06) as the volume loading of T-P was increased, Conclusions: The test results showed that the electrolysis of iron is an effective method of phosphorus removal. Regardless of the temperature and organic matter content of the influent, the quality of phosphorus in the treated water was both relatively stable and high due to the high removal efficiency. Nitrogen removal efficiency was 66.5% because organic matter from the influent serves as a carbon source in the anoxic basin.

Composting and Fertilizing Characteristics of Poultry Manure Mixture with Compressed Expansion Rice Hull as Bulking Agent (수분조절제로서 팽화왕겨를 이용한 계분 발효 특성 및 시비 효과)

  • Kim, Young-Sun;Cho, Sung-Hyun;Lee, Hoon-Soo;Lee, Geung-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.5-13
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    • 2020
  • This study was conducted to evaluate effects of compressed expansion rice hull (CERH) as bulking agent on physicochemical properties of composting poultry manure (PM) and of its fertilization on lettuce and pak choi growth. Treatments were designed as follows; sawdust treatment (90% PM + 10% sawdust; SP), peatmoss treatment (90% PM + 10% peatmoss; PP), and CERH treatments [PCR1 (90% PM + 10% CERH 1.3 mm) and PCR2 (90% PM + 10% CERH 3.0 mm)]. Physicochemical properties such as temperature, water content, pH, and total carbon of composted poultry piles for 31 days were unaffected by various bulking agents. However, total nitrogen content in compost pile was higher in PP and PCR1 than that of SP or PCR2. After composting for 31 days, content ranges of N, P2O5, and K2O in the composting PM piles were 19.1~19.7%, 47.6~51.6%, 2.76~3.65%, and 2.53~2.90%, respectively. As compared to SP treatment, dry weight of lettuce treated with PP and PCR1 increased by more than 10%, but only in PP for pak choi. These results indicated that CERH 1.3 could be used as bulking agents for composting PM on behalf of peatmoss or sawdust.

Evaluation of Groundwater Quality Characteristics around Uncontrolled Closed Valley Landfill (사용종료 비위생매립지 주변 지하수의 수질변화 특성)

  • Park, Joung-Ku;Kim, Tae-Dong;Choi, Dong Hyuk;Lee, Jin-Yong
    • Journal of Soil and Groundwater Environment
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    • v.12 no.3
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    • pp.75-80
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    • 2007
  • This study evaluated groundwater quality around an uncontrolled landfill in W sity, Korea, which was monitored for about two years (2005-2006). Parameters of concern include redox-sensitive indicators such as pH, DO, EC, ORP, DOC (dissolved organic carbon), NH3, NO3 and SO4. About 10 years have elapsed after closing dumping of municipal wastes in the landfill. Leachates showed widely varying concentrations in COD(136${\sim}$263 mg/L), T-N(121${\sim}$186 mg/L), and NH3-N(14${\sim}$369 mg/L). Groundwater at the immediate downgradient of the landfill showed weakly acidic pH condition but very high levels of EC (3,000-4,000 ${\mu}S/cm$), which indicated that the groundwater was largely affected by the landfill leachate. Cl, a conservative ion, showed over 200 mg/L at the landfill border, but a gradually decreasing level with distance from the landfill, representing dispersion and dilution (natural attenuation) due to mixing with surrounding groundwater and replenished rainwater. Redox potential showed negative value at the landfill border but it increased up to 350 mV at downgradient wells, which indicated conversion of redox condition from reducing oxic ones. Ammonia, was largely enriched at most of the monitoring wells and its level greatly exceeded drinking water standard. In summary, all the parameters evidenced occurrence of natural attenuation with distance and with time but further monitoring is still required.

Advanced Water Treatment of High Turbidity Source by Hybrid Process of Ceramic Microfiltration and Activated Carbon Adsorption: Effect of Water-back-flushing Time and Period (세라믹 정밀여과 및 활성탄 흡착 혼성공정에 의한 고탁도 원수의 고도정수처리: 물 역세척 시간 및 주기의 영향)

  • Park, Jin-Yong;Lee, Hyuk-Chan
    • Membrane Journal
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    • v.19 no.1
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    • pp.7-18
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    • 2009
  • In this study, we used the hybrid module that was composed of granular activated carbons (GAC) packing between module inside and outside of tubular ceramic microfiltration membrane for advanced drinking water treatment. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, modified solution was prepared with humic acid and kaolin. We were investigated effect of water-back-flushing time (BT) and water-back-flushing period (FT) to minimize membrane fouling and to enhance permeate flux (J) in the hybrid process, and tried to find the optimal operating conditions. As a result, resistance of membrane fouling ($R_f$) was slightly decreased according to increasing BT. Also, the shorter FT was the more effective to reduce $R_f$ and to enhance J because of frequent water-back-flushing. However, the optimal BT and FT conditions were 10 sec and 8 min respectively when operating costs were considered. Then, the optimal conditions derived from our experiments of modified solution were applied to lake water treatment. As a result, average treatment efficiencies of turbidity, $UV_{254}$ absorbance, and $COD_{Mn}$ were very high as 99.11%, 91.40% and 89.34%, respectively, but that of TDS was low as 30.05%.

Variations of Biogenic Components in the Region off the Lutzow-Holm Bay, East Antarctica during the Last 700 Kyr (지난 70만 년 동안 동남극 Lutzow-Holm만 주변 해역의 생물기원 퇴적물 함량 변화)

  • Kim, Yeo-Hun;Katsuki, Kota;Suganuma, Yusuke;Ikehara, Minoru;Khim, Boo-Keun
    • Ocean and Polar Research
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    • v.33 no.3
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    • pp.211-221
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    • 2011
  • Contents of biogenic components [opal, $CaCO_3$, TOC (total organic carbon)] were measured in Core LHB-3PC sediments collected off Lutzow-Holm Bay, in order to understand glacial-interglacial cyclic variation of the high-latitude surface-water paleoproductivity, in the Indian Sector of the Southern Ocean. An age model was established from the correlation of ARM/IRM ratios of Core LHB-3PC with LR04 stack benthic ${\delta}^{18}O$ records, in complement with radiocarbon isotope ages and biostratigraphic Last Appearance Datum (LAD). The core-bottom age was estimated to be about 700 ka. Although the $CaCO_3$ content is very low less than 1.0% throughout the core, the opal and TOC contents show clear glacial-interglacial cyclic variation such that they are high during the interglacial periods (7.2-50.3% and 0.05-1.00%, respectively) and low during the glacial periods (5.2-25.2% and 0.01-0.68%, respectively). According to the spectral analysis, the variation of opal content is controlled mainly by eccentricity forcing and subsequently by obliquity forcing during the last 700 kyrs. The opal contents of Core LHB-3PC also represent the apparent Mid-Pleistocene Transition (MPT)-related climatic variation in the glacial-interglacial cycles. In particular, the orbital variation of the opal contents shows increasing amplitudes since marine isotope stage (MIS) 11, which defines one of the important paleoclimatic events during the late Quaternary, called the "Mid-Brunhes Event". Based on the variation of the opal contents in Core LHB-3PC, we suggest that the surface-water paleoproductivity in the Indian Sector of the Southern Ocean followed the orbital (glacial-interglacial) cycles, and was controlled mainly by the extent of sea ice distribution during the last 700 kyrs.

Culture Conditions for Glucoamylase Production and Ethanol Productivity of Heterologous Transformant of Saccharomyces cerevisiae by Glucoamylase Gene of Saccharomyces diastaticus (Transformant의 Glucoamylase 생성조건과 Ethanol 발효성)

  • Kim, Young-Ho;Jung-Hwn Seu
    • Microbiology and Biotechnology Letters
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    • v.16 no.6
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    • pp.494-498
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    • 1988
  • The optimum conditions for glucoamylase production, and ethanol productivity of the transformant TSD-14 were investigated as compared with the parental strains. The properties of TSD-14 were comparatively similar to the donor S. diastaticus IFO 1046 as regards the conditions of glucoamylase production and ethanol productivity. The soluble starch was the most effective carbon source for the glucoamylase production. While inorganic nitrogen sources did not prompt cell growth and enzyme production, the organic nitrogen sources generally enhanced both cell growth and glucoamylase production. The metal salts such as FeSO$_4$, MgSO$_4$, MnCl$_2$, and NiSO$_4$were favorable to the enzyme production. And the optium temperature and initial pH for glucoamylase production were 3$0^{\circ}C$ and 5. The transformant TSD-14 produced 8.3%(v/v) ethanol from 15% sucrose medium, 4.8%(v/v) ethanol from 15% soluble starch medium, and 7.5%(v/v) ethanol from 15% liquefied potato starch medium. The corresponding fermentation efficiency were 84% , 45% and 70%, respectively.

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Prevailing Subsurface Chlorophyll Maximum (SCM) Layer in the East Sea and Its Relation to the Physico-Chemical Properties of Water Masses (동해 전역에 장기간 발달하는 아표층 엽록소 최대층과 수괴의 물리 화학적 특성과의 상관관계)

  • Rho, TaeKeun;Lee, Tongsup;Kim, Guebuem;Chang, Kyung-Il;Na, TaeHee;Kim, Kyung-Ryul
    • Ocean and Polar Research
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    • v.34 no.4
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    • pp.413-430
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    • 2012
  • To understand the scales of the spatial distribution and temporal duration of the subsurface chlorophyll-a maximum (SCM) observed in the Ulleung Basin of the East Sea, we analyzed physical and chemical data collected during the East Asian Seas Time-series-I (EAST-I) program. The SCM layer occurred at several observation lines from the Korea Strait to $37.9^{\circ}N$ in the Ulleung Basin during August of 2008 and 2011. At each observation line, the SCM layer extended from the coast to about 200 km off the coast. The SCM layer was observed between 30 and 40 m depth in the Ulleung Basin as well as in the northwestern Japan Basin along $132.3^{\circ}E$ from $38^{\circ}N$ to $42.3^{\circ}N$ during July 2009, and was observed around 50 m depth in the northeastern Japan Basin ($135-140^{\circ}E$ and $40-45^{\circ}N$) during July 2010. From these observed features, we hypothesize that the SCM layer observed in the Ulleung Basin may exist in most of the East Sea and may last for at least half-year (from the early May to late October). The nutrient supply mechanism for prolonged the SCM layer in the East Sea was not known, but it may be closely related to the horizontal advection of the nutrient rich and low oxygen waters observed in the Korea Strait between a 50 m depth to near the bottom. The prolonged development of the SCM layer in the Ulleung Basin may result in high primary production and would also be responsible for the high organic carbon content observed in the surface sediment of the region.

Spatial Distribution and Community Structure of Heterotrophic Protists in the Central Barents Sea of Arctic Ocean During Summer (북극해 하계 중앙 바렌츠해에서 종속영양 원생동물의 군집구조와 공간적 분포)

  • Yang, Eun-Jin;Choi, Joong-Ki;Kim, Sun-Young;Chung, Kyung-Ho;Shin, Hyoung-Chul;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.26 no.4
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    • pp.567-579
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    • 2004
  • To investigate the spatial distribution and community structure of heterotrophic protists, we collected water samples at 23 stations of central Barents Sea in August, 2003. This study area was divided into three area with physico-chemical and chi-a distribution characteristics: Area I of warm Atlantic water mass, Area III of cold Arctic water mass and Area II of mixed water mass. Chl-a concentration ranged from 0.18 to $1.04{\mu}g\;l^{-1}$ and was highest in Area I. The nano-sized chi-a accounted fur more than 80% of the total chi-a biomass in this study area. The contribution of nano-sized chi-a to total chi-a was higher in Area I than in Area II. Communities of heterotrophic protists were classified into three groups such as heterotrophic nanoflagellates (HNF), ciliates and heterotrophic dinoflagellates (HDF). During the study periods, carbon biomass of heterotrophic protists range from 11.3 to $38.7{\mu}gC\;l^{-1}$ (average $21.0{\mu}gC\;l^{-1}$), and were highest in Area I and were lowest in Area III. The biomass of ciliates ranged from 4.2 to $19.3{\mu}gC\;l^{-1}$ and contributed 31.5-66.9% (average 48.1%) to the biomass of heterotrophic protists. Ciliates to heterotrophic protists biomass accounted fur more than 50% in Area I. Heterotrophic dinoflagellates biomass ranged from 5.7 to $18.4{\mu}gC\;l^{-1}$ and contributed 27.1 to 56.3% (average 42.8%) of heterotrophic protists. Heterotrophic dinoflakellates to heterotrophic protists biomass accounted fur about 50% in Area III. Heterotrophic nanoflageltate biomass ranged from 0.5 to $3.4{\mu}gC\;l^{-1}$ and contributed 3.2 to 19.6% (average 9.2%) of heterotrophic protists. Heterotrophic nanoflagellates to heterotrophic protists biomass accounted fur more than 10% in Area III. These results indicate that the relative importance and structure of heterotrophic protists may vary according to water mass. Heterotrophic protists and phytoplankton biomass showed strong positive correlation in the study area The results suggest that heterotrophic protists are important consumers of phytoplankton, and protists might play a pivotal role in organic carbon cycling In the pelagic ecosystem of this study area during the study period.

Soil Physical and Chemical Properties of Kaolinite Opencast Mines and Adjacent Red Pine Forests in Sancheong-gun (산청군 고령토(백토) 노천 광산 채굴지와 인접 소나무 임분의 토양 물리·화학적 성질)

  • Kim, Kyung Tae;Baek, Gyeongwon;Choi, Byeonggil;Ha, Jiseok;Kim, Choonsig
    • Journal of Korean Society of Forest Science
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    • v.109 no.4
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    • pp.382-389
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    • 2020
  • Soil properties in opencast mines are a key factor in reclamation (revegetation) of mining areas. In this study we determined the soil physical and chemical properties of kaolinite tailings, reclaimed areas, and adjacent natural red pine (Pinus densiflora S. et Z.) forests in kaolinite opencast mines in Sancheong-gun, Gyeongsangnam-do. Six sites were chosen for collection of soil samples to determine soil physical and chemical properties at a soil depth of 10 cm. Soil bulk density was significantly higher (P < 0.05) in the kaolinite tailings (1.51 g·cm-3) than in the reclaimed areas (1.19 g·cm-3) and red pine forests (0.93 g·cm-3), whereas air phase in the kaolinite tailings (14.2%) was significantly lower than in the red pine forests (32.6%). Clay content in the red pine forests was significantly higher than in the reclaimed areas (18.7%) or kaolinite tailings (14.8%), whereas soil structural stability index was significantly lower in the reclaimed areas (1.61%) and kaolinite tailings (0.87%) than in the red pine forests (7.75%). Soil pH was significantly higher in the kaolinite tailings (pH 6.68) and reclaimed areas (pH 6.27) than in the red pine forests (pH 5.31). Soil organic carbon and total nitrogen were significantly higher in the red pine forests (C: 36.03 mg·g-1; N: 2.08 mg·g-1) than in the reclaimed areas (C: 5.00 mg·g-1; N: 0.31 mg·g-1) than in the kaolinite tailings (C: 2.12 mg·g-1; N: 0.07 mg g-1). The amount of available phosphorus was not significantly different among the three treatments. The concentration of exchangeable potassium was significantly lower in the kaolinite tailings (0.08 cmolc·kg-1) than in the reclaimed areas (0.21 cmolc·kg-1) and red pine forests (0.30 cmolc·kg-1). These results indicate that, because of high soil bulk density and low soil organic carbon, total nitrogen, available phosphorus, and exchangeable potassium in kaolinite tailings and reclaimed mining areas, soil nutrient management is needed in order to reclaim the vegetation in these type of areas.