• Title/Summary/Keyword: Natural minerals

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Synthesis of Hectorite by Hydrothemal Method (저온 수열법에 의한 헥토라이트 합성)

  • Jang, Young-Nam;Chae, Soo-Chun;Ryu, Gyoung-Won;Kim, You-Dong;Jang, Hee-Dong;Bae, In-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.1 s.51
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    • pp.1-6
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    • 2007
  • Hectorite was synthesized by a two-step hydrothermal process from $Mg(OH)_{2}$, water glass (${\sim}30\;wt%\;SiO_{2}$) and Li-compound at $90{\pm}5^{\circ}C$. The product shows excellent dispersion and swelling properties. The mixture of the starting materials was heated in a glass vessel for the first reaction with continuous stirring and the pH of the solution was adjusted to $6{\sim}8$, resulting in the formation of a precursor of hectorite. The excess salt components were washed out from the resulting slurry and then was matured in the glass vessel for the 2nd reaction. Li compound was added during the reaction. After a 10 h retention, the gel of hectorite was formed. The XRD pattern of the synthesized one was coincided with that of natural hectorite and SEM study revealed uniform grains 50 m in diameter. The d001 basal spacing of the product moved from 12 to $17.4\;{\AA}$ after glycolation treatment. The measured value of CEC and the swelling capacity was 90 cmol/kg and $60{\sim}70\;mL/2\;g$, respectively.

Quantitative X-ray Diffraction Analysis of the Gyeonggi Bay Surface Sediments (경기만 표층퇴적물의 X선 광물정량분석)

  • Moon, Dong-Hyeok;Cho, Hyen-Goo;Kim, Soon-Oh;Yi, Hi-Il;Do, Jin-Young
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.4
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    • pp.279-288
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    • 2009
  • Mineral compositions of the Gyeonggi Bay surface sediments were determined using the high resolution X-ray diffractometer and Siroquant v. 3.0 program. Surface sediments are composed of rock forming minerals (quartz 63.8%, plagioclase 12.9%, alkali feldspar 11.7%, muscovite 4.3%, amphibole 1.2%, biotite 0.5% on average), clay minerals (illite 2.4%, chlorite 1.4%, kaolinite 0.4%) and carbonate minerals (calcite 0.1%, aragonite 0.3%). Coarse sediments are high in the northern, southern and central parts of the study area, whereas fine sediments are high in the northern and southern parts of the central area. Coarse sediments have relatively a high quartz content in the northern part, and relatively high plagioclase and muscovite contents in the southern part of the study area. In the southern part and the northern part of central area, fine sediments have relatively a high illite content, and chlorite and kaolinite contents, respectively.

Effects of Cirsium setidens nakai on In Vitro Growth and Osteogenic Differentiation of Human Bone-Derived Mesenchymal Stem Cells

  • Kim, Hye-Been;Cheong, Kyu Min;Seo, Yu Ri;Lim, Ki-Taek
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.109-109
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    • 2017
  • Cirsium setidens nakai belonging to cirsium has been reported to have various physiological activities including anticancer activity because it contains polyphenols, dietary fiber, minerals and vitamins. Despite these positive positive efficacies, however, no studies have studied cirsium setidens nakai products as biomaterials such as cellular metabolism and bone formation. Thus, the aim of this study was evaluate of osteogenesis differentiation a natural material extracted from cirsium setidens nakai. The natural materials in this studys in this studywere created by 40% ethanol extraction process and then dried. FabricatedFabricatedpowders were added to a medium at various concentrations (0.01, 0.05, 0.1, 0.2, and $0.25{\mu}g/mL$), and pure medium was used as a control. The natural material caused positive increases in cell metabolic activity and mineralized bone formation without cytotoxicity. In addition, we observed higher expression of genes such as ALP, BSP, Runx2 and COL1 in cirsium setidens nakai treatment cells. As a result, this study produced and investigated cirsium setidens nakai extracts and the natural materials showed potential biomaterials. In this research indicated that the cirsium setidens nakai extracts might have promising applications in areas of agricultural, biological and food engineering as a biomaterial.

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Use of Bentonite and Organobentonite as Alternatives of Partial Substitution of Cement in Concrete Manufacturing

  • Lima-Guerra, D.J.;Mello, I.;Resende, R.;Silva, R.
    • International Journal of Concrete Structures and Materials
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    • v.8 no.1
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    • pp.15-26
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    • 2014
  • In order to study the capacities of a new occurrence of Brazilian clay samples as partial replacements of cement, a bentonite sample was selected for utilization in the natural and modified forms for present study. The natural bentonite (BBT) was modified by anchorament of 3-aminopropyltrietoxisilane ($BBT_{APS}$) and 3,2-aminoethylaminopropyltrimetoxisilane (BBTAEAPS) in the surface of component minerals of bentonite sample. The original and organo-bentonite samples were characterized by elemental analysis, scanning electron microscopic and textural analyses. The values of micropore area were varying from $7.2m^2g^{-1}$ for the BBT to $12.3m^2g^{-1}$ for the $BBT_{AEAPS}$. The bentonite samples were characterized by the main variable proportion of bentonite in the natural and intercalated forms (2, 5, 10, 15, 20, 25, 30, and 35 % by weight of cement) in the replacement mode whiles the amount of cementations material. The workability, density of fresh concrete, and absorption of water decreased as the substitution of ordinary Portland cement by perceptual of natural and modified bentonite increased. The results reveal that workability decreased with decrease of the amount of natural bentonite in the concrete, same behavior is observed for bentonite functionalized, varying from 49 to 28 mm. The energetic influence of the interaction of calcium nitrate in the structure of blends was determined through the calorimetric titration procedure.

A study on the Problems and Improvement Proposals on Legal Definitions in Regards to Herbs, Herbal Drugs, Crude Drugs and Natural Products (한약, 한약재, 생약과 천연물의 법규상 개념 및 정의의 문제점과 개선안)

  • Eom, Seok-Ki
    • Journal of Korean Medical classics
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    • v.27 no.2
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    • pp.77-95
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    • 2014
  • Objectives : This study was to analyze the definitions of herbs, herbal drugs, crude drugs and natural products in the relevant laws and regulations, understand the related problems, and propose directions for improvement. Methods : I analyzed the legal definitions in respect of herbs, herbal drugs, crude drugs and natural products in relevant laws and regulations since 1945, explained the problems, and suggested the solution-considering the academic stance of Traditional Korean Medicine and the dualistic medical and pharmaceutical system. Results : Herbs are defined as "refined things that are cut and dried in their most original state". The definition of crude drugs includes herbs and the "cell contents, secretion, extracts, minerals and other parts of animals and plants that are used medicinally". The concept of natural products is expanded to adding tissue cultures to the definition of crude drugs. Conclusions : The definition of herbs should at least include all products that are "processed, extracted and prepared" as well as contents that consist of various forms of hospital-prepared herbs. The term "herbal drug" corresponds to a traditional term of "drug", and this should be established as a concept to explain "drugs in raw materials that are used to prepare herbs and/or manufacture herbal medicine". The legal definition of herbs should include the concept of crude drugs. Herbal drug preparations and crude drugs should be included in the definition of herbal drugs.

Raman Spectroscopic Study for Investigating the Spatial Distribution and Structural Characteristics of Mn-bearing Minerals in Non-spherical Ferromanganese Nodule from the Shallow Arctic Ocean (북극해 천해저 비구형 망가니즈단괴 내 광물종 분포 및 구조적 특성 규명을 위한 라만 분광분석 연구)

  • Sangmi, Lee;Hyo-Jin, Koo;Hyen-Goo, Cho; Hyo-Im, Kim
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.4
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    • pp.409-421
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    • 2022
  • Achieving a highly resolved spatial distribution of Mn-bearing minerals and elements in the natural ferromanganese nodules can provide detailed knowledge of the temporal variations of geochemical conditions affecting the formation processes of nodules. While a recent study utilizing Raman spectroscopy has reported the changes in the manganate mineral phases with growth for spherical nodules from the Arctic Sea, the distributions of minerals and elements in the nodules from the shallow Arctic Sea with non-spherical forms have not yet fully elucidated. Here, we reported the micro-laser Raman spectra with varying data acquisition points along three different profiles from the center to the outermost rim of the non-spherical ferromanganese nodules collected from the East Siberian Sea (~73 m). The elemental distributions in the nodule (such as Mn, Fe, etc.) were also investigated by energy dispersive X-ray spectroscopy (EDS) analysis to observe the internal structure and mineralogical details. Based on the microscopic observation, the internal structures of a non-spherical nodule can be divided into three different regions, which are sediment-rich core, iron-rich substrate, and Mn-Fe layers. The Raman results show that the Mn-bearing mineral phases vary with the data acquisition points in the Mn-Fe layer, suggesting the changes in the geochemical conditions during nodule formation. In addition, we also observe that the mineral composition and structural characteristics depend on the profile direction from the core to the rim. Particularly, the Raman spectra obtained along one profile show the lack of Fe-(oxy)hydroxides and the noticeably high crystallinity of Mn-bearing minerals such as birnessite and todorokite. On the other hand, the spectra obtained along the other two profiles present the presence of significant amount of amorphous or poorly-ordered Fe-bearing minerals and the low crystallinity of Mn-bearing minerals. These results suggest that the diagenetic conditions varied with the different growth directions. We also observed the presence of halite in several layers in the nodule, which can be evidence of the alteration of seawater after nodule formation. The current results can provide the opportunity to obtain detailed knowledge of the formation process and geochemical environments recorded in the natural non-spherical ferromanganese nodule.

Petrographic Analysis for the Alkali-aggregate Reactivity (알칼리 골재의 반응성에 관한 광물학적 분석)

  • 김해인;이장화;심재황;임명혁
    • Proceedings of the Korea Concrete Institute Conference
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    • 1989.10a
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    • pp.1-4
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    • 1989
  • Recently, as the natural aggregates are exhausted, using the crashed stones bring the possibility of the alkali-aggregate reactivity. In this study, the samples are collected from the stony moutains chosen by using a geoligical survey map and analyzed in terms of the amount and the shape of the reaction minerals by a polarization microscope and X-ray diffraction which beling to the petrographic examination of aggregates for concrete. From this study, most samples of the sedimentary rocks and the granitte of the ignious rocks show the possibility of the alkali-aggregate reactivity.

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Comparison of watertightness and durability of mortar with waterproof admixture for concrete (천연무기광물계 구체방수재를 사용한 모르타르의 수밀성과 내구성비교)

  • Kim, Jae-Young;Shin, Jin-Yong;Chae, Eun-Jin;Suh, Jeong-Kwon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.65-68
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    • 2006
  • In this study, comparison of setting time, compressive strength, watertightness and durability of between reference mortar with mortar using waterproof admixtures based on natural inorganic minerals. Test results shows that waterproof admixtures does not change setting time of mortar, but strongly improve compressive strength, permeability, absorption and durability of mortar. Especially early strength of mortar increased about 40% of reference.

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Chemical Composition of Korean Natural Honeys and Sugar Fed Honeys (천연꿀과 사양꿀의 성분 분석)

  • Kim, Se Gun;Hong, In Phyo;Woo, Soon Ok;Jang, Hye Ri;Jang, Jae Seon;Han, Sang Mi
    • The Korean Journal of Food And Nutrition
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    • v.30 no.1
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    • pp.112-119
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    • 2017
  • In this study, we investigated and compared some chemical properties of Korean natural honeys and sugar-fed honeys for their quality characteristics. The natural honey samples were monofloral from chestnut and acacia flowers, and the sugar-fed honey samples were collected from honeybees feeding on sugar cane and sugar beet. The chemical properties of the honey samples, such as moisture, total protein, total lipids, ash, carbohydrate, minerals, vitamins, and free amino acids were determined. The moisture content was $18.5{\pm}0.9%$ in natural acacia honey, $17.2{\pm}0.9%$ in natural chestnut honey, $19.6{\pm}0.9%$ in sugar cane-fed honey, and $24.8{\pm}%$ in sugar beet-fed honey. The total protein and ash contents were the highest in natural chestnut honey. Maltose and sucrose were not detected in natural honeys but were detected at 2~7% in sugar-fed honeys. The vitamin, mineral, and free amino acids contents of natural honeys were higher than sugar-fed honeys. The natural chestnut honey is the highest in honeys. These results confirmed that the quality of natural honey was better than that of sugar-fed honey. Also, the vitamin, mineral, and free amino acids contents are potential characteristics for distinguishing between natural and sugar-fed honeys.

Removal Effects of Pb(II) using Natural Clays from Domestic (국내산 천연점토를 이용한 Pb(II)의 제거효과)

  • Oh, Se-Young;Hwang, Seong-Kwy;Yoon, Cheol-Hun;Lee, Ki-Chang;Jang, Kwan-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.3
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    • pp.13-19
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    • 1998
  • This study was carried out to investigate characteristics and Pb(II) removal effect of natural Muan, Seosan, Kangjin clays in the batch mode test to develope the low-priced treatment agent of wastewater which contain heavy metals in order structural, optical properties and chemical compositions of natural clays from domestic have been investigated to have high specific surface area and have minerals such as $SiO_2$ and $Al_2O_3$. As a result, removal effects of Pb(II) ions on clays were reached at equilibrium in aqueous solutions by stirring about 20minutes. The removal effect of Pb(II) ions was best for Seosan clay than Muan or Kangjin clays in terms of fixed time. The results show the possibility of continuous treatment system of wastewater which contain heavy metals by using natural clays from domestic.