• Journal of Magnetics
• /
• 제22권1호
• /
• pp.100-103
• /
• 2017

We studied the microstructure and magnetic properties of Fe nanosized powder synthesized by the pulsed wire evaporation method. The x-ray diffraction spectrum confirmed that this powder had a pure ${\alpha}$-Fe phase. Scanning electron microscope and transmission electron microscope measurements indicated that the prepared powder had uniform spherical shape with core-shell structure. The mean powder size was about 35 nm and the thickness of the surface passivation layer was about 5 nm. Energy dispersive X-ray spectroscopy measurement indicated that the surface passivation layer was iron oxide. Magnetic field dependent magnetization measurement at room temperature showed that the maximum magnetization of the prepared powder was 177.1 emu/g at 1 T.

• 한국분말재료학회지
• /
• 제10권3호
• /
• pp.186-189
• /
• 2003

A chemical vapor condensation (CVC) process using the pyrolysis of metal-organic precursors was applied to produce the nanosized $WO_3$ powders. Morphology and phase changes of the synthesized $WO_3$ powder as a function of CVC parameters were investigated by XRD, BET and TEM. The agglomerated nanosized monoclinic $WO_3$ powders with nearly spherical shape and 10-38 nm in mean diameter could be obtained. Conditions to produce the $WO_3$ nanopowders are presented in this paper.

• 한국분말재료학회지
• /
• 제20권2호
• /
• pp.100-106
• /
• 2013

Ultra-fine zirconium carbide (ZrC) powder with nano-sized primary particles was synthesized by the carbothermal reduction method by using nano-sized $ZrO_2$ and nano-sized graphite powders mixture. The synthesized ZrC powder was well dispersed after simple milling process. After heat-treatment at $1500^{\circ}C$ for 2 h under vacuum, ultra-fine ZrC powder agglomerates (average size, $4.2{\mu}m$) were facilely obtained with rounded particle shape and particle size of ~200 nm. Ultra-fine ZrC powder with an average particle size of 316 nm was obtained after ball milling process in a planetary mill for 30 minutes from the agglomerated ZrC powder.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 1998년도 춘계학술대회 및 발표대회 강연 및 발표논문 초록집
• /
• pp.7-7
• /
• 1998

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 1999년도 춘계학술대회 및 발표대회 강연 및 발표논문 초록집
• /
• pp.14-14
• /
• 1999

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
• /
• pp.625-626
• /
• 2006

In the present study, the focus is on the synthesis of nanosized WC powder by the chemical vapor condensation proces. The synthesized W-C system powder by the CVC process shows W2C, W, WO3 phases and can not shows WC phase. After recarburization heat treatment under mixture gas atmosphere of argon and hydrogen gases, the synthesized W-C system powder fully transformed to the pure WC. The synthesized WC powder after recarburization heat treatment has an average particle size of 20 nm. The nano-sized WC powder can be prepared by the combination of the CVC process and heat treatment methods.

• 한국분말재료학회지
• /
• 제9권3호
• /
• pp.174-181
• /
• 2002

Nanosized tungsten carbide powders were synthesized by the chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl($W(CO)_6$). The effect of CVC parameters on the formation and the microstructural change of as-prepared powders were studied by XRD, BET and TEM. The loosely agglomerated nanosized tungsten-carbide($WC_{1-x}$) particles having the smooth rounded tetragonal shape could be obtained below $1000^{\circ}C$ in argon and air atmosphere respectively. The grain size of powders was decreased from 53 nm to 28 nm with increasing reaction temperature. The increase of particle size with reaction temperature represented that the condensation of precursor vapor dominated the powder formation in CVC reactor. The powder prepared at $1000^{\circ}C$ was consisted of the pure W and cubic tungsten-carbide ($WC_{1-x}$), and their surfaces had irregular shape because the pure W was formed on the $WC_{1-x}$ powders. The $WC_{1-x}$ and W powders having the average particles size of about 5 nm were produced in vacuum.

• 한국분말재료학회지
• /
• 제21권6호
• /
• pp.415-421
• /
• 2014

W-10vol.%ZrC composites reinforced by micrometric and nanosized ZrC particles were prepared by hot-pressing of 25 MPa for 2 h at $1900^{\circ}C$. The effect of ZrC particle size on microstructure and mechanical properties at room temperature and elevated temperatures was investigated by X-ray diffraction analysis, scanning electron microscope and transmission electron microscope observations and the flexural strength test of the W-ZrC composite. Microstructural analysis of the W-ZrC composite revealed that nanosized ZrC particles were homogeneously dispersed in the W matrix inhibiting W grain growth compared to W specimen with micrometric ZrC particle. As a result, its flexural strength was significantly improved. The flexural strength at room temperature for W-ZrC composite using nanosized ZrC particle being 740 MPa increased by around 2 times than that of specimen using micrometric ZrC particle which was 377 MPa. The maximum strength of 935 MPa was tested at $1200^{\circ}C$ on the W composite specimen containing nanosized ZrC particle.

• 한국세라믹학회지
• /
• 제36권7호
• /
• pp.742-750
• /
• 1999

화학기상응축법을 이용한 TiO2 나노분말합성시 전구체 주입속도 및 산소 반응기체유량의 변화에 따른 나노입자의 형성과정을 분말특성의 관점에서 조사하였다. 기상합성반응의 주요 열역학, 동역학적 인자인 과포화도, 충돌율, 체류시간의 상기 두 공정변수에 대한 의존성을 이론적으로 평가하였고, 이를 0.376, 0.742 m//min의 두 전구체 주입속도 조건에서 산소유량을 1에서 2slm까지 변화시키며 합성한 TiO2 나노분말의 특성과 관련하여 분석하였다 모든 조건에서 합성된 TiO2 분말은 20~30 nm의 크기를 갖는 미세한 anatase 상과 극소량의 rutilc상이 혼합되어 서로 느슨한 결합을 하고 있었다 전구체 주입속도가 0.376m//min의 경우, 전반적인 입도와 응집도는 0.742 m//min에 비해 작았으며, 산소유량이 증가할수록 체류시간과 충돌율이 감소하여 형성된 TiO2 분말의 입도는 감소하였다. 또한 산소유량 증가에 따른 과포화도의 감소는 분말형성과정과 기구에 영향을 미치는 것으로 판단되나, 정확한 분석을 위해서는 각각의 독립적인 열역학 및 동역학적 변수 조건하에서의 면밀한 고찰이 요구되었다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
• /
• pp.2057-2059
• /
• 2005

Silver nanosized powder have been synthesized using wire explosion technology. The discharge system of 10kw (10uF, 20kV, 0.5 shots/s) was set up for mass production of 300g/h. The high purity silver powder was collected and separated by cyclone and fabric filters.