• Title/Summary/Keyword: Nanoscale Structure

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Recent Research Progress on the Atomic Layer Deposition of Noble Metal Catalysts for Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지용 촉매 소재 개발을 위한 원자층증착법 연구 동향)

  • Han, Jeong Hwan
    • Journal of Powder Materials
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    • v.27 no.1
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    • pp.63-71
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    • 2020
  • It is necessary to fabricate uniformly dispersed nanoscale catalyst materials with high activity and long-term stability for polymer electrolyte membrane fuel cells with excellent electrochemical characteristics of the oxygen reduction reaction and hydrogen oxidation reaction. Platinum is known as the best noble metal catalyst for polymer electrolyte membrane fuel cells because of its excellent catalytic activity. However, given that Pt is expensive, considerable efforts have been made to reduce the amount of Pt loading for both anode and cathode catalysts. Meanwhile, the atomic layer deposition (ALD) method shows excellent uniformity and precise particle size controllability over the three-dimensional structure. The research progress on noble metal ALD, such as Pt, Ru, Pd, and various metal alloys, is presented in this review. ALD technology enables the development of polymer electrolyte membrane fuel cells with excellent reactivity and durability.

Electrochemical characteristic of CoOx ambigel electrode in various electrolyte for supercapacitor (Supercapacitor용 CoOx ambigel의 전해질에 따른 전기화학적 특성)

  • 이희우;김한주;김성호;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.749-752
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    • 2001
  • Very fine cobalt oxide xerogel and ambigel powder were prepared using a unique solution chemistry associated with the sol-gel process. The mesoporous structure of the initial gel is maintained by removing fluid under conditions where the capillary forces that result extraction are either low or no existent, are either low or nonexistent. Controlling both the pore and solid architecture on the nanoscale offers a strategy for the design of supercapacitor. The results materials determine by using electrode that mixed ketjen black and PVdF. But CoO$\_$x/ have the low voltage, so we experimente to change electrolyte and various concentration.

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Effect of Bilayer Thickness on Hardness of Ag/Ni Nanoscale Multilayers (Ag/Ni 나노다층박막의 경도에 미치는 Bilayer 두께의 영향)

  • Kang Bong Cheol;Kim Hee Yeoun;Kwon Oh Yeol;Lim Byung Kyu;Hong Soon Hyung
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.23-26
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    • 2004
  • Ag/Ni multilayers with different bilayer thickness between 3 and 100 nm produced by DC magnetron puttering have been studied by cross-sectional TEM and nanoindentation. The micrograph shows perfect layered structure with sharp interfaces between Ag and Ni layers. Absolute hardness is calculated as a reference value to compare hardness of specimens regardless of indent depth. A hardness enhancement of nearly $100\%$ over the rule-of-mixtures values, calculated from the measured hardness of single Ag and Ni thin films, is observed. The hardness increases with decreasing bilayer thickness until 8nm. This enhancement shows a good agreement with Hall-Petch relation using grain size (one half of the bilayer thickness) confined within a layer. The deformation behavior can be explained by dislocation pile-up in smaller grains.

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Electrochemical characteristics of Co/PVA composite electrode for supercapacotor (수퍼커패시터용 Co/PVA복합전극의 전기화학적특성)

  • Lee, Hee-Woo;Kim, Han-Joo;Ohsaka, Takeo;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.577-580
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    • 2001
  • Very fine cobalt oxide ambigel powder were prepared using a unique solution chemistry associated with the sol-gel process. The mesoporous structure of the initial gel is maintained by removing fluid under conditions where the capillary forces that result extraction are either low or no existent, are either low or nonexistent. Controlling both the pore and solid architecture on the nanoscale offers a strategy for the design of supercapacitor. But $CoO_x$ have the low voltage, so we experiment using Co/PVA composite electrode.

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Graphene-matrix nanotopography as a biomimetic scaffold for engineering structure and function of stem cells

  • Park, Seon-Ho;Kim, Jang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.82-82
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    • 2017
  • It is a great challenge to design and develop biologically inspired hierarchical platforms composed of nano and sub-nanopatterned topography for cell and tissue engineering. In this work, we have developed the novel platforms as a synthetic extracellular matrix using graphene and nanopatterned substrates for promoting functions of cells. Monolayer graphene was coated on the nanopatterned matrix with various nanoscale parallel ridges and grooves as scaffolds with hierarchical structures. Strictly, it was found that graphene-matrix nanotopography platforms could promote the functions of cells including stem cells, osteoblast cells, and endothelial cells through the synergically controlled cell-substrate and cell-cell interactions. Our results proposed that the graphene-based nanopatterned scaffolds would allow us to set up an efficient strategy for designing advanced biomimetic engineering systems toward stem cell-based tissue regeneration.

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Fundamental Study on the Formation of Nanostructured Coating Layer (나노구조 용사코팅층의 형성에 관한 기초적 연구)

  • Kim, Y.S.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.90-95
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    • 2005
  • The wire-arc process is a low-cost thermal spray method simply utilizes electrical energy to melt the feedstock wire. It is more userful for field applications, especially to coat large surface area. In this paper, a special Fe-based alloy coatings by using the wire-arc process were developed. Nanoscale composite coatings were achieved either during spraying or through a post heat treatment. As-sprayed Fe-based alloy coatings had been an amorphous matrix structure, after heating to $700^{\circ}C$ for 10 minutes a solid state transformation occurred in the some fraction of amorphous matrix which resulted in the formation of nanostructured recrystallized phase. Scanning electron microscopy (SEM) and field emotional scanning electron microscope(FE-SEM) were applied to analyze the microstructure of the coatings. Additionally hardness and bend resistance of the Fe-based alloy coatings were examined, and these results were compared with those of partially stabilized zirconia(PSZ) coatings by using the plasma spray process.

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Method of manufacturing and characteristics of a functional AFM cantilever (기능성 원자간력 현미경 캔틸레버 제조 방법과 특성)

  • Suh Moon Suhk;Lee Churl Seung;Lee Kyoung Il;Shin Jin-Koog
    • 정보저장시스템학회:학술대회논문집
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    • 2005.10a
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    • pp.56-58
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    • 2005
  • To illustrate an application of the field effect transistor (FET) structure, this study suggests a new cantilever, using atomic force microscopy (AFM), for sensing surface potentials in nanoscale. A combination of the micro-electromechanical system technique for surface and bulk and the complementary metal oxide semiconductor process has been employed to fabricate the cantilever with a silicon-on-insulator (SOI) wafer. After the implantation of a high-ion dose, thermal annealing was used to control the channel length between the source and the drain. The basic principle of this cantilever is similar to the FET without a gate electrode.

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Characterization and Preparation of Electrospun Poly(ethylene terephthalate) (PET) Nonwoven/Polyurethane (PU) composites (전기방사된 PET 부직포/PU 복합체의 제조 및 특성)

  • Kim, Kwan-Woo;Lee, Keun-Hyung;Kim, Chul-Ki;Kim, Hak-Yong;Lee, Sung-Gu;Park, Soo-Jin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.275-276
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    • 2003
  • Electrostatic spinning or electrospinning has been recently paid attention to prepare ultrafine fiber mats which are composed of diameters in a range of submicrons to nanoscale size[l]. Due to small diameters and porous structure, electrosun fibers have a high specific surface area and expected to use for broad applications, such as filters, membranes, wound dressing materials, artificial blood vessels. a nonwoven fabric, a reiforcement of nanocomposites[2,3], etc. (omitted)

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Thermomechanical Local QC Analysis of Nanoscale Structure Considering Surface Effect (표면효과를 고려한 나노 사이즈 구조물의 local QC 열탄성 해석)

  • Yoo, Su-Young;Rhee, Seung-Yun;Cho, Maeng-Hyo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2007.04a
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    • pp.415-420
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    • 2007
  • In analyzing the nano-scale behavior of nano devices or materials, QC method is efficient because it does not treat all the atoms. But for more accurate analysis in QC method, it is important to consider temperature and surface effects. In finite temperature, free energy is considered instead of potential energy. Because the surface area to volume ratio increases as the length scale of a body decreases, the surface effects are more dominant. In this paper, temperature related Cauchy-Born rule and surface Cauchy-Born rule are proposed to configurate the strain energy density. This method is applied to small and homogeneous deformation in two dimensional problem using finite element simulation.

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An Analytical Modeling of Threshold Voltage and Subthreshold Swing on Dual Material Surrounding Gate Nanoscale MOSFETs for High Speed Wireless Communication

  • Balamurugan, N.B.;Sankaranarayanan, K.;Amutha, P.;John, M. Fathima
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.8 no.3
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    • pp.221-226
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    • 2008
  • A new two dimensional (2-D) analytical model for the Threshold Voltage on dual material surrounding gate (DMSG) MOSFETs is presented in this paper. The parabolic approximation technique is used to solve the 2-D Poisson equation with suitable boundary conditions. The simple and accurate analytical expression for the threshold voltage and sub-threshold swing is derived. It is seen that short channel effects (SCEs) in this structure is suppressed because of the perceivable step in the surface potential which screens the drain potential. We demonstrate that the proposed model exhibits significantly reduced SCEs, thus make it a more reliable device configuration for high speed wireless communication than the conventional single material surrounding gate (SMSG) MOSFETs.