• Bulletin of the Korean Chemical Society
• /
• v.34 no.2
• /
• pp.629-632
• /
• 2013

Many properties of inorganic compounds are sensitive to changes in the point-defect concentrations. In minerals, such changes are influenced by temperature, pressure, and chemical impurities. Olivines form an important class of minerals and are magnesium-rich solid solutions consisting of the orthosilicates forsterite $Mg_2SiO_4$ and the fayalite $Fe_2SiO_4$. Orthosilicates have an orthorhombic crystal structure and exhibit anisotropic electronic and ionic transport properties. We examined the anisotropy of the electrical conductivity of $Fe_2SiO_4$ under the assumption that the electronic conduction in $Fe_2SiO_4$ occurs via a small polaron hopping mechanism. The anisotropic electrical conductivity is well explained by the electron transfer integrals obtained from the spin dimer analysis based on tight-binding calculations. The latter analysis is expected to provide insight into the anisotropic electrical conductivities of other magnetic insulators of transition metal oxides.

• Journal of the Semiconductor & Display Technology
• /
• v.15 no.1
• /
• pp.22-26
• /
• 2016

Extreme ultraviolet (EUV) pellicle is one of the most concerned research in the field of EUV lithography (EUVL). Imaging performance of EUV mask with pellicle should be investigated prior to high volume manufacturing (HVM) of EUVL. In this paper, we analyzed the relationship between standoff distance and imaging performance of EUV mask to verify the influences of relative standoff distance on imaging performance. As a result, standoff distance of EUV pellicle has no effect on imaging performance of EUV mask such as critical dimension (CD), normalized image log slope (NILS) and image contrast. Therefore, pellicle support structure can be flexibly designed and modified in diverse ways to complement the thermal limitation of EUV pellicle membrane.

• Journal of Powder Materials
• /
• v.8 no.1
• /
• pp.49-54
• /
• 2001

The synthesis and characteristics of W-Ni-Fe nanocomposite powder by hydrogen reduction of ball milled W-Ni-Fe oxide mixture were investigated. The ball milled oxide mixture was prepared by high energy attrition milling of W blue powder, NiO and $Fe_2O_3$ for 1 h. The structure of the oxide mixture was characteristic of nano porous agglomerate composite powder consisting of nanoscale particles and pores which act as effective removal path of water vapor during hydrogen reduction process. The reduction experiment showed that the reduction reaction starts from NiO, followed by $Fe_2O_3$ and finally W oxide. It was also found that during the reduction process rapid alloying of Ni-Fe yielded the formation of $\gamma$-Ni-Fe. After reduction at 80$0^{\circ}C$ for 1 h, the nano-composite powder of W-4.57Ni-2.34Fe comprising W and $\gamma$-Ni-Fe phases was produced, of which grain size was35nm for W and 87 nm for $\gamma$-Ni-Fe, respectively. Sinterability of the W heavy alloy nanopowder showing full density and sound microstructure under the condition of 147$0^{\circ}C$/20 min is thought to be suitable for raw material for powder injection molding of tungsten heavy alloy.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.278.1-278.1
• /
• 2013

Among the prerequisites for stable neural interfacing are the long-term stability of electrical performance of and the excellent biocompatibility of conducting materials in implantable neural electrodes. Reduced graphene oxide offers a great potential for a variety of biomedical applications including biosensors and, particularly, neural interfaces due to its superb material properties such as high electrical conductivity, decent optical transparency, facile processibility, and etc. Nonetheless, there have been few systematic studies on the graphene-based neural interfaces in terms of biocompatibility of electrode materials and long term stability in electrical characteristics. In this research, we prepared the primary culture of rat hippocampal neurons directly on reduced graphene oxide films which is chosen as a model electrode material for the neural electrode. We observed that the viability of primary neuronal culture on the present structure is minimally affected by nanoscale graphene flakes below. These results implicate that the multilayer films of reduced graphene oxides can be utilized for the next-generation neural interfaces with decent biocompatibility and outstanding electrical performance.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.141-141
• /
• 2013

Shape control of metal nanocrystals has broad applications, including catalysis, plasmonics, and sensing. It was found that controlling the atomic arrangement on metal nanocrystal surfaces affects many properties, including the electronic dipole or work function. Tuning the surface structure of exposed facets of metal nanocrystals was enabled by shape control. We investigated the effect of shape on nanomechanical properties, including friction and adhesion forces. Two nanoparticles systems, high-index {321} and low-index {100}, were used as model nanoparticle surfaces. Scanning force microscopy was used to probe nanoscale friction and adhesion. Because of the abundant presence of high-density atomic steps and kinks, high-index faceted nanoparticles have a higher surface energy than low-index faceted cubic nanoparticles. Due to this high surface energy, high-index faceted particles have shown stronger adhesion and higher friction than low-index nanoparticles. We discuss the results in light of the differences in surface energy as well as the effect of capping layers in the measurement.

• Journal of the Korean Magnetics Society
• /
• v.4 no.1
• /
• pp.1-6
• /
• 1994

The magnetization dynamics was investigated by solving possible origins of overdamped susceptibility observed in ultra-soft magnetic amorphous thin films. The experimental high frequency spectrum and computational spectrum calculated from Gilbert's equation of motion were compared in order to find proper damping factor $\alpha{\approx}20$ and demagnetizing coefficients $D_{x}{\approx}D_{y}{\approx}D_{z}{\approx}0$ for ultra-soft magnetic films. A magnetization vortex mode was, then, proposed to explain the origin of the reversible susceptibility and other anomalies of the ultra-soft magnetic heterogeneous thin films. In this mode it is suggested that there occur, within the nanoscale structural features of the ultra-soft films, incoherent rotational spin motions that are highly damped by the energy transfer from short wavelength spin wave modes and local defect structure mode interactions.

• Journal of the Korean Society of Visualization
• /
• v.19 no.1
• /
• pp.50-56
• /
• 2021

With the advances in recent nanotechnology, mass transport phenomena have been receiving large attention both in academic researches and industrial applications. Nonetheless, it is not clearly determined which parameters are dominant at nanoscale mass transport. Especially, membrane is a kind of technology that use a selective separation to secure fresh water. The development of great separation membrane and membrane-based separation system is an important way to solve existing water resource problems. In this study, glass fiber-based membranes which are treated by graphene oxide (GO), poly-styrene sulfonate (GOP) and sodium dodecyl sulfate (GPS) were fabricated. Mass transport parameters were investigated in terms of material-specific and structure-specific dominance. The 3D structural information of GO, GOP, and GPS was obtained by using synchrotron X-ray nano tomography. In addition, electrostatic characteristic and water absorption rate of the membranes were investigated. As a result, we calculated internal structural information using Tomadakis-Sotrichos model, and we found that manipulation of surface characteristics can improve spacer arm effect, which means enhancement of water permeability by control length of ligand and surface charge functionality of the membrane.

• Journal of the Microelectronics and Packaging Society
• /
• v.26 no.2
• /
• pp.9-14
• /
• 2019

The newly discovered properties of periodic nanoscale patterns have increasingly sparked research interests in various fields. Along this direction, it is worth mentioning that there had been rare studies conducted on interference exposure, a method of creating periodic patterns. Additionally, these few studies seemed to validate the existence of only exact quadrangle shapes and dot patterns. This study asserted the formation of wavy patterns associated to using multiple exposures of the ratio of the first exposure intensity to the second exposure intensity. Such patterns were designed and constructed herein via overlapping of two Gaussian beams relative to certain rotation angles, and with a submicron structure fabricated based on a 360-nm continuous-wave laser. Results confirmed that the proposed double exposure laser interference lithography is able to create circular, elliptical and wavy patterns with no need for complex optical components.

• Computers and Concrete
• /
• v.32 no.6
• /
• pp.567-576
• /
• 2023

In this study, a 3D microstructure-based model is established to simulate the effective thermal conductivity of cement paste, covering varying influencing factors associated with microstructure and thermal transfer mechanisms. The virtual cement paste divided into colloidal C-S-H and heterogeneous paste are reconstructed based on its structural attributes. Using the two-level hierarchical cement pastes as inputs, a lattice Boltzmann model for heat conduction is presented to predict the thermal conductivity. The results suggest that due to the Knudsen effect induced by the nanoscale pore, the thermal conductivity of air in C-S-H gel pore is significantly decreased, maximumly accounting for 3.3% thermal conductivity of air at the macroscale. In the cement paste, the thermal conductivities of dried and saturated cement pastes are stable at the curing age larger than 100 h. The high water-to-cement ratio can decrease the thermal conductivity of cement paste.

• Korean Journal of Materials Research
• /
• v.19 no.10
• /
• pp.517-521
• /
• 2009

Si-C composite with hollow spherical structure was synthesized using ultrasonic treatment of organosilica powder formed by hydrolysis of phenyltrimethoxysilane. The prepared powder was pyrolyzed at various temperatures ranging from 900 to 1300 $^{\circ}C$ under nitrogen atmosphere to obtain optimum conditions for Li-ion battery anode materials with high capacity and cyclability. The XRD and elemental analysis results show that the pyrolyzed Si/C composite at 1100 $^{\circ}C$ has low oxygen and nitrogen levels, which is desirable for increasing the electrochemical capacity and reducing the irreversible capacity of the first discharge. The solid Si-C composite electrode shows a first charge capacity of $\sim$500 mAhg$^{-1}$ and a capacity fade within 30 cycles of 0.93% per cycle. On the other hand, the electrochemical performance of the hollow Si-C composite electrode exhibits a reversible charge capacity of $\sim$540 mAhg$^{-1}$ with an excellent capacity retention of capacity loss 0.43% per cycle up to 30 cycles. The improved electrochemical properties are attributed to facile diffusion of Li ions into the hollow shell with nanoscale thickness. In addition, the empty core space provides a buffer zone to relieve the mechanical stresses incurred during Li insertion.