• Title/Summary/Keyword: Nanomaterials

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Effects of nanomaterials on hydration reaction, microstructure and mechanical characteristics of cementitious nanocomposites: A review

  • Kim, Gwang Mok
    • Journal of Urban Science
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    • v.9 no.1
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    • pp.7-16
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    • 2020
  • Application of nanomaterials to cementitious composites has been attempted with the rapid development of nanotechnology since the 1990s. Various nanomaterials such as carbon nanotube, graphene, nano-SiO2, nano-TiO2, nano-Al2O3, nano-Clay, and nano-Magnetite have been applied to cementitious composites to improve the mechanical properties and the durability, and to impart a variety of functionality. In-depth information on the effect of nanomaterials on the hydration reaction, the microstructure, and the mechanical properties of cementitious nanocomposites is provided in the present study. Specifically, this paper mostly deals with the previous studies on the heat evolution characteristics of cementitious nanomaterials at an early age of curing, and the pore and the compressive strength characteristics of cementitious nanocomposites. Furthermore, the effect of nanomaterials on the cementitious nanocomposites was systematically discussed with the reviews.

Role of Metal Catalyst and Substrate Site for the Growth of Carbon Nanomaterials

  • Manocha, L.M.;Valand, Jignesh;Manocha, S.
    • Carbon letters
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    • v.6 no.2
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    • pp.79-85
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    • 2005
  • The work reported in this paper relates to preparation and characterization of carbon nanomaterials by CVD method on different substrates by decomposition of certain hydrocarbons at 550-$800^{\circ}C$ using a horizontal quartz tube reactor. Monometallic and bimetallic catalyst system of iron and nickel were used for the preparation of different carbon nanomaterials. The influence of various parameters such as substrate/catalyst preparation parameters, the nature of substrate, catalyst concentration, reaction time and temperature on the growth, yield and alignment of carbon nanotubes has been studied. The characterization of carbon nanomaterials has been carried out using SEM, TEM and TGA. The carbon nanomaterials developed were vertically aligned on a large area of flat quartz substrate.

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A Review of Nanomaterials in Cement-Based Composite

  • LI, MAO;Kim, Jin-Man
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.174-186
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    • 2019
  • This paper reviews the development condition of nanomaterials used in concrete over years. The definitions of nanomaterial, nanotechnology, and nano-concrete are reviewed. The impacts of nanomaterials on cementitious material in the point of advantages and disadvantages are analyzed. Moreover, this paper analyzes and classifies the nanomaterials into the extra quality enhancement and modification to plain cementitious composite. Indeed, the outstanding properties of the embedded nanomaterials can be introduced to concrete such as the mechanical improvement, pore structure refinement, hydrate acceleration, and smartness modifying of self-cleaning, and/or self-sensing. Before the full potential of nanotechnology can be realized in concrete applications, various techniques have to be solved including proper dispersion, compatibility of the nanomaterials in cement, processing, manufacturing, safety, handling issues, scale-up, cost, the impact on the environment and human health.

Microscopic analysis of metal matrix composites containing carbon Nanomaterials

  • Daeyoung Kim;Hye Jung Chang;Hyunjoo Choi
    • Applied Microscopy
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    • v.50
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    • pp.4.1-4.10
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    • 2020
  • Metallic matrix composites reinforced with carbon nanomaterials continue to attract interest because of their excellent mechanical, thermal, and electrical properties. However, two critical issues have limited their commercialization. Uniform distribution of carbon nanomaterials in metallic matrices is difficult, and the interfaces between the nanomaterials and matrices are weak. Microscope-based analysis was recently used to quantitatively examine these microstructural features and investigate their contributions to the composites' mechanical, thermal, and electrical properties. The impacts of the microstructure on these properties are discussed in the first section of this review. In the second section, the various microscopic techniques used to study the distribution of carbon nanomaterials in metallic matrices and their interfaces are described.

Understanding and Application of Stoffenmanager Nano Tool into Synthesis and Packing Process of Nanomaterials (Stoffenmanager nano 컨트롤 밴딩 도구 이해와 나노물질 합성 및 포장 공정 적용 연구)

  • Lee, Naroo;Ahn, Jungho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.1
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    • pp.95-103
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    • 2015
  • Objectives: This study was conducted in order to better understand the conceptual model and Stoffenmanager nano module and apply it to the synthesis and packing processes of nanomaterials. Methods: Site visits were conducted to five nanomaterial production processes. Product and exposure variables were investigated in these workplaces. Hazard banding and exposure classification of the synthesis and packing processes of nanomaterials were conducted using documents and the website of Stoffenmanager Nano. Results: The five sites featured different products, packing tasks, ventilation and local exhaust, and others. The hazards for nano-nickel and copper were classified as E. The hazards for both fumed silica and indium tin oxide were classified as D. The hazard for spherical silica was classified as C. The exposure classes in the synthesis process of nanomaterials ranged from 2 through 4. The exposure classes in the packing process of nanomaterials ranged from 1 through 4. Conclusions: Application of Stoffenmanager nano to the synthesis and packing processes of nanomaterials helped to better understand the control level of the work environment and to suggest appropriate actions. The comparison of each process showed the effect of the production process and handling of solids and ventilation on exposure class.

Research Trends of Food Chain Transfer of Nanomaterials in Freshwater and Marine Ecosystems (담수 및 해양생태계에서 나노물질의 먹이사슬전이 연구추세)

  • Chae, Yooeun;An, Youn-Joo
    • Journal of Korean Society on Water Environment
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    • v.30 no.6
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    • pp.683-690
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    • 2014
  • Nanomaterials are used in a range of fields, including industry, medicine, aerospace, and manufacturing, due to their unique and useful properties. In recent years, nanotechnology has developed rapidly, and the amount of nanomaterials used in various fields has increased consistently. As a result, nanomaterials are released into the aquatic and soil ecosystem, posing potential risks to organisms and environment. These materials can enter the cells and may cause serious damage to organisms. Furthermore, they can be transferred through trophic levels and food web, thereby leading to bioconcentration and biomagnification. In this study, we analyzed the trends in research on food chain transfer of nanomaterials and investigated the techniques used in the research. Although many studies have been underway, there is a need for further advanced studies on higher trophic levels and complex microcosm and mesocosm. Furthermore, study topics should be expanded to include various types of nanomaterials and varied species and trophic levels.

Ecotoxicity Assessment of Silver Nanomaterials with Different Physicochemical Characteristics in Diverse Aquatic Organisms (다양한 특성의 은나노물질이 수생생물에 미치는 독성영향평가)

  • Hong, Nam-Hui;Jung, Youn-Joo;Park, June-Woo
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.183-192
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    • 2016
  • Silver nanomaterials have been intensively applied in consumer products of diverse industrial sectors because of their strong biocidal properties and reported to be hazardous to aquatic organisms once released in the environment. Nanomaterials including sliver, are known to be different in toxicity according to their physicochemical characteristics such as size, shape, length etc. However studies comparing toxicity among silver nanomaterials with different physicochemical characteristics are very limited. Here, toxicities of silver nanomaterials with different size (50, 100, 150 nm), length (10, $20{\mu}m$), shape (wire, sphere), and coating material (polyvinylpyrrolidone, citrate) using OECD test guidelines were evaluated in aquatic species (zebrafish, daphnia, algae) and compared. On a size property, the smaller of silver nanomaterials, the more toxic to tested organisms. Sphered type of silver nanomaterials was less toxic to organisms than wired type, and shorter nanowires were less toxic than longer ones. Meanwhile the toxic effects of materials coated on silver nanomaterials were slightly different in each tested species, but not statistically significant. To the best of our knowledge, it is first investigation to evaluate and compare ecotoxicity of silver nanomaterials having different physicochemical characteristics using same test species and test guidelines. This study can provide valuable information for human and environmental risk assessment of silver nanomaterials and guide material manufacturers to synthesize silver nanomaterials more safely to human and environment.