Fig. 1. Illustration of the “top-down” and “bottom-up” approaches in nanotechnology. Adapted from Sobolev and Gutiérrez 2005
Fig. 2. Characteristics of nano-SiO2 particles. Adaped from Jo et al.(2007)
Fig. 3. Properties of MWCNT illustrated by SEM
Fig. 4. Representation of (a) graphene, (b) graphene oxide (GO), (c) reduced graphene oxide (rGO) and (d) graphene nanoplatelets (GNPs). Adapted from Vinayan(2016)
Fig. 5. TEM image of nano-BN: (a) 120nm; (b) 500nm; (c) 1μm. Adapted from Zhang(2018)
References
- Li, H., Xiao, H.G., Ou, J.P. (2004). A study on mechanical and pressure-sensitive properties of cement mortar with nanophase materials, Cement and Concrete Research, 34(3), 435-438. https://doi.org/10.1016/j.cemconres.2003.08.025
- Alberti, M.G., Enfedaque, A., Galvez, J.C. (2017). Fiber reinforced concrete with a combination of polyolefin and steel-hooked fibers, Composite Structures, 171(1), 317-325. https://doi.org/10.1016/j.compstruct.2017.03.033
- Lin, C., Wei, W., Hu, Y.H. (2016). Catalytic behavior of graphene oxide for cement hydration process, Journal of Physics and Chemistry of Solids, 89, 128-133. https://doi.org/10.1016/j.jpcs.2015.11.002
- Sanchez, F., Sobolev, K. (2010). Nanotechnology in concrete-a review, Construction and Building Materials, 24(11), 2060-2071. https://doi.org/10.1016/j.conbuildmat.2010.03.014
- Jennings, H.M., Bullard, J.W., Thomas, J.J., Andrade, J.E., Chen, J.J., Scherer, G.W. (2008). Characterization and modeling of pores and surfaces in cement paste: correlations to processing and properties, Journal of Advanced Concrete Technology, 6(1), 5-29. https://doi.org/10.3151/jact.6.5
- Sanchez, F., Borwankar, A. (2010). Multi-scale performance of carbon microfiber reinforced cement-based composites exposed to a decalcifying environment, Materials Science and Engineering: A, 527(13-14), 3151-3158. https://doi.org/10.1016/j.msea.2010.01.084
- Singh, N.B., Kalra, M., Saxena, S.K. (2017). Nanoscience of Cement and Concrete, Materialstoday: Proceedings, 4(4), 5478-5487.
- Abdoli, H., Farnoush, H.R., Asgharzadeh, H., Sadrnezhaad, S.K. (2011). Effect of high energy ball milling on compressibility of nanostructured composite powder, Powder Metallurgy, 54(1), 24-29. https://doi.org/10.1179/003258909X12573447241662
- Drexler, K.E., Peterson, C., Pergamit, G. (1991). Unbounding the Future: the Nanotechnology Revolution, William Morrow and Company, New York.
- Jankowska, E., Zatorski, W. (2009). Emission of nanosize particles in the process of nanoclay blending, in: Third International Conference on Quantum, Nano and Micro Technologies.
- Sobolev, K., Gutierrez, M.F. (2005). How nanotechnology can change the concrete world: Part 1, American Ceramic Society Bulletin, 84(11), 113-116.
- Norhasri, M.M., Hamidah, M.S., Fadzil, A.M. (2017). Applications of using nano material in concrete: A review, Construction and Building Materials, 133(15), 91-97. https://doi.org/10.1016/j.conbuildmat.2016.12.005
- Feynman, R.P. (1960). There's plenty of room at the bottom(reprint from speech given at annual meeting of the american physical society), Engineering and Science, 23, 22-36.
- NSTC. (2007). The National Nanotechnology Initiative - Strategic Plan, December 2007. Executive Office of the President of the United States.
- Hanus, M.J., Harris, A.T. (2013). Nanotechnology innovations for the construction industry, Progress in Materials Science, 58(7), 1056-1102. https://doi.org/10.1016/j.pmatsci.2013.04.001
- Bjornstrom, J., Martinelli, A., Matic, A., Borjesson, L., Panas, I. (2004). Accelerating effects of colloidal nano-silica for beneficial calcium-silicate-hydrate formation in cement, Chemical Physics Letters, 392(1-3), 242-248. https://doi.org/10.1016/j.cplett.2004.05.071
-
Lin, K.L., Chang, W.C., Lin, D.F., Luo, H.L., Tsai, M.C. (2008). Effects of nano-
$SiO_2$ and different ash particle sizes on sludge ash-cement mortar, Journal of Environmental Management, 88(4), 708-714. https://doi.org/10.1016/j.jenvman.2007.03.036 -
Jo, B.W., Kim, C.H., Tae, G.H., Park, J.B. (2007). Characteristics of cement mortar with nano-
$SiO_2$ particles, Construction and Building Materials, 21(6), 1351-1355. https://doi.org/10.1016/j.conbuildmat.2005.12.020 - Ding, S., Ruan, Y., Yu, X., Han, B., Ni, Y.Q. (2019). Self-monitoring of smart concrete column incorporating CNT/NCB composite fillers modified cementitious sensors, Construction and Building Materials, 201, 127-137. https://doi.org/10.1016/j.conbuildmat.2018.12.203
- Konsta-Gdoutos, M.S., Metaxa, Z.S., Shah, S.P. (2010). Highly dispersed carbon nanotube reinforced cement based materials, Cement and Concrete Research, 40(7), 1052-1059. https://doi.org/10.1016/j.cemconres.2010.02.015
- Chuah, S., Pan, Z., Sanjayan, J.G., Wang, C.M., Duan, W.H. (2014). Nano reinforced cement and concrete composites and new perspective from graphene oxide, Construction and Building Materials, 73, 113-124. https://doi.org/10.1016/j.conbuildmat.2014.09.040
- Al-Rub, R.K.A., Ashour, A.I., Tyson, B.M. (2012). On the aspect ratio effect of multi-walled carbon nanotube reinforcements on the mechanical properties of cementitious nanocomposites, Construction and Building Materials, 35, 647-655. https://doi.org/10.1016/j.conbuildmat.2012.04.086
- Liu, Q., Zhao, H.Q., Li, L., He, P.P., Wang, Y.X., Yang, H.Y., Hu, Z.H., Mu. Y. (2018). Effect of surface modification on carbon nanotubes (CNTs) catalyzed nitrobenzene reduction by sulfide, Journal of Hazardous Materials, 357, 235-243. https://doi.org/10.1016/j.jhazmat.2018.05.060
-
Ismael, R., Silva, J.V., Carmo, R.N.F., Soldado, E., Lourenco, C., Costa, H., Julio, E. (2016). Influence of nano-
$SiO_2$ and nano-$Al_2O_3$ additions on steel-to-concrete bonding, Construction and Building Materials, 125, 1080-1092. https://doi.org/10.1016/j.conbuildmat.2016.08.152 -
Ortega-Villar, R., Lizarraga-Mendiola, L., Coronel-Olivares, C., Lopez-Leon, L.D., Bigurra-Alzati, C.A., Vazquez-Rodriguez, G.A. (2019). Effect of photocatalytic
$Fe_2O_3$ nanoparticles on urban runoff pollutant removal by permeable concrete, Journal of Environmental Management, 242, 487-495. https://doi.org/10.1016/j.jenvman.2019.04.104 -
Han, B., Li, Z., Zhang, L., Zeng, S., Yu, X., Han, B., Ou, J. (2017). Reactive powder concrete reinforced with nano
$SiO_2$ -coated$TiO_2$ , Construction and Building Materials, 148, 104-112. https://doi.org/10.1016/j.conbuildmat.2017.05.065 - Vallee, F. (2004). Cementitious materials for self-cleaning and depolluting facade surfaces, RILEM International Symposium on Environment-Conscious Materials and Systems for Sustainable Development, 337-346.
- Ghafari, E., Costa, H., Julio, E. (2015). Review on eco-efficient ultra high performance concrete enhanced with nano-materials, Construction and Building Material, 101, 201-208. https://doi.org/10.1016/j.conbuildmat.2015.10.066
-
Lee, B.Y., Jayapalan, A.R., Kurtis, K.E. (2013). Effects of nano-
$TiO_2$ on properties of cement-based materials, Magazine of Concrete. Research, 65(21), 1293-1302. https://doi.org/10.1680/macr.13.00131 -
Vohra, M.S., Tanaka, K. (2003). Photocatalytic degradation of aqueous pollutants using silica-modified
$TiO_2$ , Water Research, 37(16), 3992-3996. https://doi.org/10.1016/S0043-1354(03)00333-6 - Jayapalan A.R., Lee B.Y., Kurtis K.E. (2009). Effect of Nano-sized Titanium Dioxide on Early Age Hydration of Portland Cement, In Nanotechnology in Construction 3 Springer, Berlin, Heidelberg
-
Meng, T., Yu, Y., Qian, X., Zhan, S., Qian, K. (2012). Effect of nano-
$TiO_2$ on the mechanical properties of cement mortar, Construction and Building. Materials, 29, 241-245. https://doi.org/10.1016/j.conbuildmat.2011.10.047 -
Haruehansapong, S., Pulngern, T., Chucheepsakul, S. (2014). Effect of the particle size of nano silica on the compressive strength and the optimum replacement content of cement mortar containing nano-
$SiO_2$ , Construction and Building Materials, 50, 471-477. https://doi.org/10.1016/j.conbuildmat.2013.10.002 -
Nazari, A., Riahi, S., Riahi, S., Shamekhi, S.F., Khademno, A. (2010). Improvement the mechanical properties of the cementitious composite by using
$TiO_2$ nanoparticles, Journal of American Science, 6(4), 98-101. - Li, H., Zhang, M.H., Ou, J.P. (2007). Flexural fatigue performance of concrete containing nano-particles for pavement, International Journal of Fatigue, 29(7), 1292-1301. https://doi.org/10.1016/j.ijfatigue.2006.10.004
- Li, Z., Wang, H., He, S., Lu, Y., Wang, M. (2006), Investigations on the preparation and mechanical properties of the nanoalumina reinforced cement composite, Materials Letters, 60(3), 356-359. https://doi.org/10.1016/j.matlet.2005.08.061
-
Ortega-Villar, R., Lizarraga-Mendiola, L., Coronel-Olivares, C., Lopez-Leon, L.D., Bigurra-Alzati, C.A., Vazquez-Rodriguez, G.A. (2019). Effect of photocatalytic
$Fe_2O_3$ nanoparticles on urban runoff pollutant removal by permeable concrete, Journal of Environmental Management, 242, 487-495. https://doi.org/10.1016/j.jenvman.2019.04.104 -
Jo, B.W., Kim, C.H., Tae, G.H., Park, J.B. (2007). Characteristics of cement mortar with nano-
$SiO_2$ particles, Construction and Building Materials, 21, 1351-1355. https://doi.org/10.1016/j.conbuildmat.2005.12.020 - Li, H, Xiao, H.G., Yuan, J., Ou, J. (2004). Microstructure of cement mortar with nano-particles, Composites Part B: Engineering, 35(2), 185-189. https://doi.org/10.1016/S1359-8368(03)00052-0
-
Ji, T. (2005). Preliminary study on the water permeability and microstructure of concrete incorporating nano-
$SiO_2$ , Cement and Concrete Research, 35(10), 1943-1947. https://doi.org/10.1016/j.cemconres.2005.07.004 -
Richardson, I.G. (2004). Tobermorite/jennite- and tobermorite/ calcium hydroxide-based models for the structure of C-S-H: applicability to hardened pastes of tricalcium silicate,
${\beta}$ -dicalcium silicate, Portland cement, and blends of Portland cement with blast-furnace slag, metakaolin, or silica fume, Cement and Concrete Research, 34(9), 1733-1777. https://doi.org/10.1016/j.cemconres.2004.05.034 -
Jo, B.W., Kim, C.H., Tae, G.H., Park, J.B. (2007). Characteristics of cement mortar with nano-
$SiO_2$ particles, Construction and Building Materials, 21(6), 1351-1355. https://doi.org/10.1016/j.conbuildmat.2005.12.020 - Kroyer, H., Lindgreen, H., Jacobsen, H.J., Skibsted, J. (2003). Hydration of Portland cement in the presence of clay minerals studied by 29Si and 27Al MAS NMR spectroscopy, Advanced Cement Research, 15(3), 103-112. https://doi.org/10.1680/adcr.2003.15.3.103
- Lindgreen, H., Geiker, M., Kroyer, H., Springer, N., Skibsted, J. (2008). Microstructure engineering of Portland cement pastes and mortars through addition of ultrafine layer silicates, Cement and Concrete Composites, 30(8), 686-699. https://doi.org/10.1016/j.cemconcomp.2008.05.003
- Korb, J.P. (2009). NMR and nuclear spin relaxation of cement and concrete materials, Current Opinion in Colloid Interface Science, 14(3), 192-202. https://doi.org/10.1016/j.cocis.2008.10.004
- Beaudoin, J.J., Raki, L., Alizadeh, R. (2009). A 29Si MAS NMR study of modified C-S-H nanostructures, Cement and Concrete Composites, 31(8), 585-590. https://doi.org/10.1016/j.cemconcomp.2008.11.004
- Skibsted, J., Hall, C. (2008). Characterization of cement minerals, cements and their reaction products at the atomic and nano scale, Cement and Concrete Research, 38(2), 205-225. https://doi.org/10.1016/j.cemconres.2007.09.010
- Poulsen, S.L., Kocaba, V., Le Saoût, G., Jakobsen, H.J., Scrivener, K.L., Skibsted, J. (2009). Improved quantification of alite and belite in anhydrous Portland cements by 29Si MAS NMR: effects of paramagnetic ions, Solid State Nuclear Magnetic Resonance, 36(1), 32-44. https://doi.org/10.1016/j.ssnmr.2009.05.001
- Cong, X., Kirkpatrick, R.J. (1996). 29Si MAS NMR study of the structure of calcium silicate hydrate, Advanced Cement Based Materials, 3(3-4), 144-156. https://doi.org/10.1016/1065-7355(96)00023-5
- Richardson, I.G. (1999). The nature of C-S-H in hardened cements, Cement and Concrete Research, 29(8), 1131-1147. https://doi.org/10.1016/S0008-8846(99)00168-4
- Korb, J.P., Monteilhet, L., McDonald, P.J., Mitchell, J. (2007). Microstructure and texture of hydrated cement-based materials: a proton field cycling relaxometry approach, Cement and Concrete Research, 37(3), 295-302. https://doi.org/10.1016/j.cemconres.2006.08.002
- Nonat. A. (2004). The structure and stoichiometry of C-S-H, Cement and Concrete Research, 34(9), 1521-1528. https://doi.org/10.1016/j.cemconres.2004.04.035
- Makar, J., Margeson, J., Luh, J. (2005). Carbon nanotube/cement composites-early results and potential application. In: Banthia N, Uomoto T, Bentur A, Shah SP, editors. Proceedings of 3rd international conference on construction materials: performance, innovations and structural implications, 1-10.
- Li, G.Y., Wang, P.M., Zhao, X. (2007). Pressure-sensitive properties and microstructure of carbon nanotube reinforced cement composites, Cement and Concrete Composite, 29(5), 377-82. https://doi.org/10.1016/j.cemconcomp.2006.12.011
- Xie, X.L., Mai, Y.W., Zhou, X.P. (2005). Dispersion and alignment of carbon nanotubes in polymer matrix: a review, Materials Science and Engineering: R: Reports, 49(4), 89-112. https://doi.org/10.1016/j.mser.2005.04.002
- Kang I, Heung, Y.Y., Kim, J.H., Lee, J.W., Gollapudi, R., Subramaniam, S., Narasimhadenara, S., Hurd, D., Kirikera, G.R., Shanov, V., Schulz, M.J., Shi, D., Boerio, J., Mall, S., Ruggles-Wren, M. (2006). Introduction to carbon nanotube and nanofiber smart materials, Composites Part B: Engineering, 37(6), 382-394. https://doi.org/10.1016/j.compositesb.2006.02.011
- Xu, S., Liu, J., Li, Q. (2015). Mechanical properties and microstructure of multi-walled carbon nanotube-reinforced cement paste, Construction and Building Materials, 76, 16-23. https://doi.org/10.1016/j.conbuildmat.2014.11.049
- Kim, H.K., Nam, I.W., Lee, H.K. (2012). Microstructure and mechanical/EMI shielding characteristics of CNT/cement composites with various silica fume contents, UKC 2012 on science, technology, and entrepreneurship.
- Musso, S., Tulliani, J.M., Ferro, G., Tagliaferro, A. (2009). Influence of carbon nanotubes structure on the mechanical behavior of cement composites, Composite Science and Technology, 69(11-12), 1985-1990. https://doi.org/10.1016/j.compscitech.2009.05.002
- Kim, G.M., Park, S.M., Ryu, G.U., Lee, H.K. (2017). Electrical characteristics of hierarchical conductive pathways in cementitious composites incorporating CNT and carbon fiber, Cement and Concrete Composites, 82, 165-175. https://doi.org/10.1016/j.cemconcomp.2017.06.004
- Nam, I.W., Lee, H.K., Jang, J.H. (2011). Electromagnetic interference shielding/absorbing characteristics of CNT-embedded epoxy composites, Composites Part A: Applied Science and Manufacturing, 42(9), 1110-1118. https://doi.org/10.1016/j.compositesa.2011.04.016
- Li, G.Y., Wang, P.M., Zhao, X. (2007). Pressure-sensitive properties and microstructure of carbon nanotube reinforced cement composites, Cement and Concrete Composite, 29(5), 377-382. https://doi.org/10.1016/j.cemconcomp.2006.12.011
- Stallings, J.M., Cousins, T.E., Stafford, T.E. (1996). Effects of Removing Diaphragms from Steel Girder Bridge, Transportation Research Record, 1541(1), 183-188. https://doi.org/10.1177/0361198196154100124
- Yang, X., Zhu, J., Qiu, L., Li, D. (2011). Bioinspired effective prevention of restacking in multilayered graphene films: towards the next generation of high-performance supercapacitors, Advanced Materials, 23(25), 2833-2838. https://doi.org/10.1002/adma.201100261
- Vinayan, B.P. (2016). Heteroatom-doped graphene-based hybrid materials for hydrogen energy conversion, Recent Advances in Graphene Research.
- Alkhateb, H., Al-Ostaz, A., Cheng, A.H.D., Li, X. (2013). Materials genome for graphene-cement nanocomposites, Journal of Nanomechanics and Micromechanics, 3(3), 67-77. https://doi.org/10.1061/(ASCE)NM.2153-5477.0000055
- Rhee, I., Lee, J.S., Kim, Y.A., Kim, J.H., Kim, J.H. (2016). Electrically conductive cement mortar: incorporating rice husk-derived high-surface-area graphene, Construction and Building Materials, 125, 632-642. https://doi.org/10.1016/j.conbuildmat.2016.08.089
- Zhang, W., Han, B., Yu, X., Ruan, Y., Ou, J. (2018). Nano boron nitride modified reactive powder concrete, Construction and Building Materials, 179, 186-197. https://doi.org/10.1016/j.conbuildmat.2018.05.244
- Saggar, R., Porwal, H., Tatarko, P., Dlouhy, I., Reece, M. J. (2015). Boron nitride nanosheets reinforced glass matrix composites, Advances in Applied Ceramics, Structural, Functional and Bioceramics, 114,
- Li, Y., Yin, J., Wu, H., Deng, H., Chen, J., Yan, Y., Liu, X., Huang, Z., Jiang, D. (2015). Enhanced electrical resistivity in SiC-BN composites with highly-active BN nanoparticles synthesized via chemical route, Journal of the European Ceramic Society, 35(5), 1647-1652. https://doi.org/10.1016/j.jeurceramsoc.2014.11.016
- Rafiee, M.A., Narayanan, T.N., Hashim, D.P., Sakhavand, N., Shahsavari, R., Vajtai, R., Ajayan, P.M. (2013). Hexagonal boron nitride and graphite oxide reinforced multifunctional porous cement composites, Advanced. Functional Materials, 23(45), 5624-5630. https://doi.org/10.1002/adfm.201203866
- Zhang, W., Han, B., Yu, X., Ruan, Y., Ou, J. (2018). Nano boron nitride modified reactive powder concrete, Construction and Building Materials, 179, 186-197. https://doi.org/10.1016/j.conbuildmat.2018.05.244