• Title/Summary/Keyword: Nano-surface Treatment

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Involvement of F-Actin Cytoskeleton for Microvilli Formation of Jurkat T Lymphocyte (F-actin cytoskeleton이 Jurkat T 림파구의 microvilli 형성에 미치는 영향)

  • Lee, Jae-Seol;Kim, Hae-Young;Son, Gi-Ae;Kim, Ji-Eun;Moon, Kyoung-Mi;Kim, Kwang-Hyeon;Choi, Woo-Bong;Lee, Jong-Hwan
    • Journal of Life Science
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    • v.21 no.10
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    • pp.1401-1406
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    • 2011
  • Morphological changes in immune cells occur due to pathogen infection and natural circulation. T cells produce uropod, filopodia, lamellipodia, and microvilli for inflammation, immunosurvelliance, migration, and diapedesis. Short finger-like microvilli cover the surfaces of circulating mammalian immune cells. The surface features of monocytes and neutrophils are quite different, containing membrane ruffles as their predominant structure. In this study, we present the involvement of actin cytoskeleton regarding T lymphocyte microvilli. From analysis of scanning electron micrographs, Jurkat T lymphocyte microvilli was observed to rapidly disassemble when exposed to the actin-sequestering molecule, cytochalasin D. In contrast to cytochalasin D treatment, we found that median microvillar thickness was enlarged on Jurkat T lymphocytes treated with PMA via Lin-11, Isl-1, Mec-3 Kinase (LIMK) and cofilin signaling. In addition, actin cytoskeleton was involved in polarity formation in EL4 T lymphocytes. These results suggest that microvilli formation or polarity of T lymphocytes are involved in actin cytoskeleton dynamics.

Synthesis and Physical Properties of MO·Fe12O18 (M/Ba and Sr) Nanoparticles Prepared by Sol-Gel Method Using Propylene Oxide (Propylene Oxide를 이용한 졸-겔법에 의한 MO·Fe12O18 (M/Ba, Sr) 나노 분말의 합성과 물리적 특성)

  • Lee, Su Jin;Choe, Seok Burm;Gwak, Hyung Sub;Paik, Seunguk
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.420-425
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    • 2006
  • Nano sized mixed metal hexagonal ferrite powders with improved magnetic properties have been prepared by sol-gel method using propylene oxide as a gelation agent. To obtain the desired ferrite, two different metal ions were used. One of the ions has only +2 formal charge. The key step in the processes is that hydrated $Ba^{2+}$ or $Sr^{2+}$ ions are hydrolyzed and condensed at the surface of the previously formed $Fe_{2}O_{3}$ gel. In this processes, all the reaction can be finished within a few minutes. The magnetic properties of the produced powder were improved by heat treatment. The highest values of the magnetic properties were achieved at temperature $150^{\circ}C$ lower than those of the previously published values. The highest observed values of coercivity and the saturation magnetization of Sr-ferrite and Ba-ferrite powder were 6198 Oe, 5155 Oe and 74.4 emu/g, 68.1 emu/g, respectively. The ferrite powder annealed at $700^{\circ}C$ showed spherical particle shapes. The resulting spheres which were formed by the aggregation of nanoparticles with size 3~5 nm have diameter around 50 nm. The powder treated at $800^{\circ}C$ showed hexagonal-shaped grains with crystallite size above 500 nm.

Study on the Hollow Fiber Nano-composite Membrane Preparation onto the Porous PVDF Membrane Surfaces using the Interfacial Polymerization (다공성 PVDF 막의 polyamide 계면중합법처리를 통한 나노 중공사 복합막 제조 연구)

  • Kang, Su Yeon;Cho, Eun Hye;Kim, Ihl hyung;Kim, Cheong Sik;Rhim, Ji Won
    • Membrane Journal
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    • v.24 no.2
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    • pp.107-112
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    • 2014
  • The composite membranes were prepared on the surface of hydrophobic porous poly (vinylidene fluoride) (PVDF) hollow fiber membranes through the interfacial polymerization. The preparation variables were the concentrations of piperazine (PIP), trimesoyl chloride (TMC) and the contents of polyethylene glyco l (PEG). The separation characterization of the resulting membranes were carried out for aqueous 100 ppm solution of NaCl, $CaSO_4$, and $MgCl_2$ and also mixed 300 ppm solution of NaCl and $CaSO_4$ in terms of the flux and rejection. Both the flux and rejection were the highest when the interfacial polymerization was conducted using TMC. When TMC concentration was 0.1 wt%, the flux and rejection were shown 48.3 LMH ($L/m^2{\cdot}hr$) and 59%, respectively. To improve the flux, the annealing post-treatment and the addition of PEG into piperazine were done. As expected, the overall flux was enhanced while the rejection was reduced.

Seasonal Variation of Picoplankton Community in Lake Juam (주암호에서 미세조류의 계절적 군집 변화)

  • Cheong, Cheong-Jo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.3
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    • pp.271-277
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    • 2010
  • The purpose of this study is to investigate the seasonal variation of picoplankton community in Lake Juam depending on the change of physico-chemical factors such as rainfall, water depth, DO and pH. The concentration of chlorophyll-a was most high as 18.03 mg/$m^3$ in July when the rainfall and water temperature were highest. The concentration was gradually decreased in October, April and that of January was decreased most low as 1.86 mg/$m^3$. The highest concentration of the Chl-a was shown at 2 and 5 m of water depth than surface, and the concentration was gradually decreased when the water depth becomes deep. Overall, microplankton was the highest rate as 33.9~54.2%, nanoplankton was 24.3~30.5% and picoplankton was 21.6~41.2%. Picoplankton was included as considerable concentration in the water of Juam lake. Therefore it is necessary to remove thoroughly the picoplankton in the water treatment processes such coagulation·sedimentation and sand filtration. The protoplasm released from destruction of picoplankton by chlorine has high possibility to cause regrowth of bacteria and pathogenic microorganism in the distribution system by playing the role of the assimilable organic carbon.

DEVELOPMENT OF NANO-FLUID MOVEMENT MEASURING DEVICE AND ITS APPLICATION TO HYDRODYNAMIC ANALYSIS OF DENTINAL FLUID (미세 물 흐름 측정장치의 개발과 상아세관액의 수력학에의 응용)

  • Lee, In-Bog;Kim, Min-Ho;Kim, Sun-Young;Chang, Ju-Hea;Cho, Byung-Hoon;Son, Ho-Hyun;Back, Seung-Ho
    • Restorative Dentistry and Endodontics
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    • v.33 no.2
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    • pp.141-147
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    • 2008
  • This study was aimed to develop an instrument for real-time measurement of fluid conductance and to investigate the hydrodynamics of dentinal fluid. The instrument consisted of three parts; (1) a glass capillary and a photo sensor for detection of fluid movement, (2) a servo-motor, a lead screw and a ball nut for tracking of fluid movement, (3) a rotary encoder and software for data processing. To observe the blocking effect of dentinal fluid movement, oxalate gel and self-etch adhesive agent were used. BisBlock (Bisco) and Clearfil SE Bond (Kuraray) were applied to the occlusal dentin surface of extracted human teeth. Using this new device, the fluid movement was measured and compared between before and after each agent was applied. The instrument was able to measure dentinal fluid movement with a high resolution (0.196 nL) and the flow occurred with a rate of 0.84 to 15.2 nL/s before treatment. After BisBlock or Clearfil SE Bond was used, the fluid movement was decreased by 39.8 to 89.6%.

Supported Metal Nanoparticles: Their Catalytic Applications to Selective Alcohol Oxidation (금속 나노 촉매를 활용한 선택적 알코올 산화 반응)

  • Hussain, Muhammad Asif;Joseph, Nyanzi;Kang, Onyu;Cho, Young-Hun;Um, Byung-Hun;Kim, Jung Won
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.227-238
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    • 2016
  • This review article highlights different types of nano-sized catalysts for the selective alcohol oxidation to form aldehydes (or ketones) with supported or immobilized metal nanoparticles. Metal nanoparticle catalysts are obtained through dispersing metal nanoparticles over a solid support with a large surface area. The nanocatalysts have wide technological applications to industrial and academic fields such as organic synthesis, fuel cells, biodiesel production, oil cracking, energy conversion and storage, medicine, water treatment, solid rocket propellants, chemicals and dyes. One of main reactions for the nanocatalyst is an aerobic oxidation of alcohols to produce important intermediates for various applications. The oxidation of alcohols by supported nanocatalysts including gold, palladium, ruthenium, and vanadium is very economical, green and environmentally benign reaction leading to decrease byproducts and reduce the cost of reagents as opposed to stoichiometric reactions. In addition, the room temperature alcohol oxidation using nanocatalysts is introduced.

Mechanical Properties of Epoxy Paint using Oxidized Graphene Nanoplatelet as a Reinforcement (산화 그래핀 나노플레이트릿을 강화제로 사용한 에폭시 도료의 역학적 특성)

  • Seo, Won-Woo;Kim, Gyu-Yong;Yoon, Min-Ho;Lee, Bo-Kyeong;Nam, Jeong-Soo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.5
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    • pp.465-471
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    • 2017
  • In this study, oxidized graphene nanoplatelet(GO) was prepared by oxidizing graphene nanoplatelet(GNP) with nitric acid in order to solve the problem of dispersion of GNP, one of nano materials. The surface chemical composition of the prepared GO was analyzed by fourier transform infrared spectroscopy(FT-IR) before incorporation into the epoxy paint, and the dispersibility in the solvent was confirmed. Meanwhile, GNP/Epoxy and GO/Epoxy paint were prepared by mixing GNP, GO with 0.1, 0.3, 0.5 and 1.0wt.% in epoxy paint and the mechanical properties were evaluated. As a result, GNP/Epoxy and GO/Epoxy paints showed better mechanical properties than Neat Epoxy which did not incorporate GNP, GO. Especially, when 0.3wt.% of GO was incorporated into epoxy resin, it showed higher tensile strength than Neat Epoxy. It was confirmed that acid treatment of GNP was effective in improving the mechanical properties of epoxy paint.

Recent Progress in Conductive Polymer-based Membranes (전도성 고분자 분리막의 최근 연구동향)

  • Park, Shinyoung;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.2
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    • pp.101-119
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    • 2021
  • The demand for clean water is virtually present in all modern human societies even as our society has developed increasingly more advanced and sophisticated technologies to improve human life. However, as global climate change begins to show more dramatic effects in many regions in the world, the demand for a cheap, effective way to treat wastewater or to remove harmful bacteria, microbes, viruses, and other solvents detrimental to human health has continued to remain present and remains as important as ever. Well-established synthetic membranes composed of polyaniline (PANI), polyvinylidene fluoride (PVDF), and others have been extensively studied to gather information regarding the characteristics and performance of the membrane, but recent studies have shown that making these synthetic membranes conductive to electrical current by doping the membrane with another material or incorporating conductive materials onto the surface of the membrane, such as allotropes of carbon, have shown to increase the performance of these membranes by allowing the adjustability of pore size, improving antifouling and making the antibacterial property better. In this review, modern electrically conductive membranes are compared to conventional membranes and their performance improvements under electric fields are discussed, as well as their potential in water filtration and wastewater treatment applications.

Effect of composition on the structural and thermal properties of TiZrN thin film (TiZrN 박막의 조성이 구조적 특성 및 열적 특성에 미치는 영향)

  • Choi, Byoung Su;Um, Ji Hun;Seok, Min Jun;Lee, Byeong Woo;Kim, Jin Kon;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.1
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    • pp.37-42
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    • 2021
  • The effect of chemical composition on the structural and thermal properties of TiZrN thin films was studied. As the Zr fraction in the deposited TixZr1-xN (x = 0.87, 0.82, 0.7, 0.6, and 0.28) increased, microstructural changes consisted of reduction in the grain size and a gradual transition from columnar structure to granular structure were observed. In addition, it was also confirmed that a gradual crystal phase transition from TiN to TiZrN has occurred as the Zr fraction increased up to 0.4. After heat treatment at 900℃, Ti0.82Zr0.18N and Ti0.7Zr0.3N layers were converted to a form in which rutile phase TiO2 and TiZrO4 oxides coexist, while Ti0.6Zr0.4N layer was converted to TiZrO4 oxide. Among the five compositions of TiZrN films, the Ti0.6Zr0.4N showed the best high temperature stability and produced a significant enhancement in the thermal oxidation resistance of Inconel 617 through suppressing the surface diffusion of Cr caused by thermal oxidation of the Inconel 617 substrate.

Effective Biodegradation of Polyaromatic Hydrocarbons Through Pretreatment Using $TiO_2$-Coated Bamboo Activated Carbon and UV ($TiO_2$로 코팅된 대나무숯 및 UV의 전처리를 통한 다환방향족탄화수소의 효율적 생분해)

  • Ekpeghere, Kalu I.;Koo, Jin-Heui;Kim, Jong-Hyang;Lee, Byeong-Woo;Yi, Sam-Nyung;Kim, Yun-Hae;Koh, Sung-Cheol
    • Korean Journal of Microbiology
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    • v.47 no.2
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    • pp.137-142
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    • 2011
  • $TiO_2$-coated bamboo activated carbon has been prepared and utilized under UV irradiation as a pretreatment method for an effective biodegradation of the recalcitrant polyaromatic hydrocarbons (PAHs). The anatase $TiO_2$ was successfully coated on the bamboo activated carbon (AC) and it showed the highest photoactivity against methylene blue. In the absence of the PAHs-degrading bacteria PAHs having low molecular weight (i.e., naphthalene, acenaphthylene, acenaphthene, and fluorene) were degraded by 9.8, 76.2, 74.1, and 40.5%, respectively. Higher molecular weight PAHs, however, maintained high residual concentrations of PAHs (400-1,000 ${\mu}g$/L) after the same treatment. On the other hand, the overall concentrations of PAHs became lower than 340 ${\mu}g$/L when the pretreated PAHs were subjected to biodegradation by a PAH-degrading consortium for a week. Herein, phenanthrene, anthracene, fluoranthene, and pyrene were removed by 29.3, 61.4, 27.0, and 44.3%, respectively, indicating the facilitated potential biodegradation of PAHs. Activated carbon coated with $TiO_2$ appeared to inhibit growth of PAH degraders on the surface of AC, indicating planktonic degraders were dominantly involved in the PAH biodegradation in presence of the $TiO_2$-coated bamboo AC. It was proposed that an effective remediation technology for the recalcitrant PAHs could be developed when an optimum pretreatment process is further established.