• Title/Summary/Keyword: Nano-oil

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Self-Supported NiSe/Ni Foam: An Efficient 3D Electrode for High-Performance Supercapacitors

  • Zhang, Jingtong;Zhao, Fuzhen;Du, Kun;Zhou, Yan
    • Nano
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    • v.13 no.11
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    • pp.1850136.1-1850136.12
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    • 2018
  • Three-dimensional (3D) mixed phases NiSe nanoparticles growing on the nickel foam were synthesized via a simple one-step hydrothermal method. A series of experiments were carried out to control the morphology by adjusting the amount of selenium in the synthetic reaction. Meanwhile, the as-prepared novel column-acicular structure NiSe exist three advantages including ideal electrical conductivity, high specific capacity and high cycling stability. It delivered a high capacitance of $10.8F\;cm^{-2}$ at a current density- of $5mA\;cm^{-2}$. An electrochemical capacitor device operating at 1.6 V was then constructed using NiSe/NF and activated carbon (AC) as positive and negative electrodes. Moreover, the device showed high energy density of $31W\;h\;kg^{-1}$ at a power density of $0.81kW\;kg^{-1}$, as well as good cycling stability (77% retention after 1500 cycles).

Surface-modified Cellulose Nanofibril Surfactants for Stabilizing Oil-in-Water Emulsions and Producing Polymeric Particles (표면 개질된 나노피브릴화 셀룰로오스를 이용한 에멀젼 안정화 및 고분자 입자 제조)

  • Kim, Bo-Young;Moon, Jiyeon;Yoo, Myong Jae;Kim, Seonmin;Kim, Jeongah;Yang, Hyunseung
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.110-116
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    • 2021
  • In this work, the surface of hydrophilic cellulose nanofibrils (CNFs) was modified precisely by varying amounts of cetyltrimethylammonium bromide (CTAB) to produce CNF-based particle surfactants. We found that a critical CTAB density was required to generate amphiphilic CTAB-grafted CNF (CNF-CTAB). Compared to pristine CNF, CNF-CTAB was highly efficient at stabilizing oil-in-water Pickering emulsions. To evaluate their effectiveness as particle surfactants, the surface coverage of oil-in-water emulsion droplets was determined by changing the CNF-CTAB concentration in the aqueous phase. Furthermore, styrene-in-water stabilized by CNF-CTAB surfactants was thermally polymerized to produce CNF-stabilized polystyrene (PS) particles, offering a great potential for various applications including pharmaceuticals, cosmetics, and petrochemicals.

Nanocarbon synthesis using plant oil and differential responses to various parameters optimized using the Taguchi method

  • Tripathi, Suman;Sharon, Maheshwar;Maldar, N.N.;Shukla, Jayashri;Sharon, Madhuri
    • Carbon letters
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    • v.14 no.4
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    • pp.210-217
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    • 2013
  • The synthesis of carbon nanomaterials (CNMs) by a chemical vapor deposition method using three different plant oils as precursors is presented. Because there are four parameters involved in the synthesis of CNM (i.e., the precursor, reaction temperature of the furnace, catalysts, and the carrier gas), each having three variables, it was decided to use the Taguchi optimization method with the 'the larger the better' concept. The best parameter regarding the yield of carbon varied for each type of precursor oil. It was a temperature of $900^{\circ}C$ + Ni as a catalyst for neem oil; $700^{\circ}C$ + Co for karanja oil and $500^{\circ}C$ + Zn as a catalyst for castor oil. The morphology of the nanocarbon produced was also impacted by different parameters. Neem oil and castor oil produced carbon nanotube (CNT) at $900^{\circ}C$; at lower temperatures, sphere-like structures developed. In contrast, karanja oil produced CNTs at all the assessed temperatures. X-ray diffraction and Raman diffraction analyses confirmed that the nanocarbon (both carbon nano beads and CNTs) produced were graphitic in nature.

A Study on the Flow Characteristic for Changing of Flow Region of the Motor Inserted Oil Pump (내부 유로 변경에 따른 전동기 일체형 유압펌프 내부의 유동특성에 관한 연구)

  • Choi, Y.H.;Lee, T.K.;Lee, Y.W.
    • Journal of Power System Engineering
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    • v.16 no.5
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    • pp.26-31
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    • 2012
  • A numerical study has been carried out to investigate the heat and mass transfer of an oil pumping system with a variable shape of the housing using the CFD method. Especially, the electric motor and the pump combined together, accomplishes a research about the oil supplying system. In this study, the temperature and velocity distribution of the oil pumping system by varying the flow rate of supplying oil have been investigated. The temperature changes with each five conditions(flow rate of supply oil : 2, 4, 8, 12, and 16 liter/min) have also been studied. The numerical results show that the exhaust temperature decreases as the flow rate of the supplying oil increases. It also reveals that the temperatures change differently with the housing shape.

A Study on Tribological Characteristics of Sintered Fe-base Low Alloy Powder for Automobile Parts (자동차 부품용 Fe계 저합금 분말 소결품의 마찰마모 특성 연구)

  • Kim, Tae-Hyun;Kim, Sang-Youn;Kim, Tae-Gyu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.6
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    • pp.139-144
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    • 2012
  • In the automobile industry, the various efforts to lower their industrial cost and enhance fuel efficiency have been made through process improvement or weight saving of automobile parts. Gear is one of significant parts of transmission, which is made by cast iron or alloy steel. It is expensive due to complex processing, inferior materials and large machining allowance. In this study, alternative gear cars oil which is based on fluid applications materials is produced by reducing surface induction hardening and carburizing hardened in production. And then, wear characteristic and mechanical properties such as hardness of the sintered alloy which is used as a substitute for small machining allowance is investigated.

A Study on Friction and Wear Characteristics of Nano-size Carbon (나노 사이즈 탄소입자의 마찰마모 특성에 관한 연구)

  • Jung, Kwang-Woo;Choi, Jeong-Kyu;Moon, Seong-Yong;Chung, Keun-Woo
    • Tribology and Lubricants
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    • v.24 no.5
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    • pp.264-268
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    • 2008
  • A large number of additives have been used with the efforts of improving the performance of lubricants used along with the development of internal combustion engine. In this study, nano-sized graphite was used as liquid-lubricant additive. In order to disperse graphite into oil, we esterified the nano-carbon manufactured by our company with various types of alcohol. After measuring the anti-wear in accordance with the types of alcohol and added concentration, it has been found that its anti-wear/friction decrease has been improved in case of adding 0.1% of the sample composed with C12/14 mixed alcohol & hexadecanol.

Preparation and Release Behavior of Atorvastatin Calcuim - Encapsulated Polyoxalate Microspheres (아토르바스타틴 칼슘을 함유한 폴리옥살레이트 미립구의 제조 및 방출거동)

  • Lee, Cheon Jung;Kim, Su Young;Lee, Hyun Gu;Yang, Jaewon;Park, Jin Young;Cha, Se Rom;Lim, Dong-Kwon;Lee, Dongwon;Khang, Gilson
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.656-663
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    • 2014
  • Atorvastatin calcium-loaded polyoxalate (POX) microspheres were prepared by an emulsion solvent-evaporation/ extraction method of oil-in-oil-in-water ($O_1/O_2/W$) for sustained release. We investigated the release behavior according to initial drug ratio, molecular weight ($M_w$) and concentration of POX and concentration of emulsifier. The microsphere was characterized on the surface, the cross-section morphology and the behavior of atorvastatin calcium release for 10 days by scanning electron microscopy (SEM) and high performance liquid chromatography (HPLC). The analysis of crystallization was analyzed to use X-ray diffraction (XRD), differential scanning calorimeter (DSC) and Fourier transform infrared (FTIR). These results showed that the release behaviors can be controlled by preparation conditions.

Potential Application of Radiation Curing of Future Nano and Advanced Composites in Korea (한국의 미래 나노 및 고성능 복합재료에 있어서의 광경화 기술의 응용가능성)

  • 이재락;김영근;박수진;서민강;김영미;이화영;김범룡
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.103-106
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    • 2003
  • In this work the novel potential epoxy resins, were synthesized and acrylated. Their structures were confirmed by means of FTIR, $^1H NMR, and^{13}/C NMR$ spectroscopies. Also, we were to note the effect of W curing on functional group changes of VE/UP blend system after UV curing.

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Fabrication and Filtering Test of Nanoparticle-Stabilized Emulsion to be Suitable for Enhanced Oil Recovery (석유증진회수에 적합한 나노 에멀젼의 제조 및 필터링 시험 분석)

  • Son, Han Am;Lee, Keun Ju;Cho, Jang Woo;Im, Kyung Chul;Kim, Jin Woong;Kim, Hyun Tae
    • Economic and Environmental Geology
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    • v.46 no.1
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    • pp.51-61
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    • 2013
  • Researches on the oil recovery enhancement using the nanotechnology has recently been studied in the United States. The previous researches has focused mainly on the flow characteristics of nanoparticles in porous media, and the stability of the nano-emulsion itself. However, the analysis did not deal with the size effects between a nano-emulsion and the pore size which has an important role when nano-emulsion flows in the porous media. In this research, nano-based emulsion was fabricated which is able to be applied for the enhanced oil recovery techniques and its characteristics was analyzed. In addition, in order to identify the characteristics of nano-emulsions flowing through the porous media, the size effect was analysed by filtering test. According to the results, when the emulsion was fabricated, SCA(Silane Coupling Agent) or PVA(Poly Vinyl Alcohol) are added to improve the stability of emulsion. As the ratio of the decane to water increased, the viscosity of emulsion and the droplet size also increased. For the filtering test at the atmospheric conditions, the droplet did not go through the filter; only the separated water from the emulsion was able to be filtered. This phenomenon occurred because the droplet was not able to overcome the capillary pressure. At the filtering test by suction pressure, most of the emulsion was filtered over the filter size of $60{\mu}m$. However, the ratio of filtration was rapidly degraded at less than $45{\mu}m$ filters. This is caused due to deformation and destruction of the droplet by strong shear stress when passing through the pore. The results from the study on the basic characteristic of nano-emulsion and filtering test will be expected to play as the important role for the fabrication of the stable nano-emulsion or the research on the recovery of residual oil in porous media.