• Title/Summary/Keyword: Nano-level

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Temperature-dependent photoluminescence study on aluminum-doped nanocrystalline ZnO thin films by sol-gel dip-coating method

  • Nam, Giwoong;Park, Hyunggil;Yoon, Hyunsik;Kim, Soaram;Leem, Jae-Young
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.131-133
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    • 2012
  • The photoluminescence (PT) properties of Al-doped ZnO thin films grown by the sol-gel dip-coating method have been investigated. At 12 K, nine distinct PL peaks were observed at 2.037, 2.592, 2.832, 3.027, 3.177, 3.216, 3.260, 3.303, and 3.354 eV. The deep-level emissions (2.037, 2.592, 2.832, and 3.027 eV) were attributed to native defects. The near-band-edge (NBE) emission peaks at 3.354, 3.303, 3.260, 3.216, and 3.177 eV were attributed to the emission of the neutral-donor-bound excitons (D0X), two-electron satellite (TES), free-to-neutral-acceptors (e,A0), donor-acceptor pairs (DAP), and second-order longitudinal optical (2LO) phonon replicas of the TES (TES-2LO), respectively. According to Haynes' empirical rule, we calculated the energy of a free exciton (FX) to be 3.374 eV. The thermal activation energy for D0X in the nanocrystalline ZnO thin film was found to be ~25 meV, corresponding to the thermal dissociation energy required for D0X transitions.

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Application of Wool Dyes for Hair Dyeing (양모용 염료의 염모제 적용성 연구)

  • Chae, Da Eun;Lee, Eunkyo;Kim, Yewon;Seo, Dongwan;Oh, Nahyun;Koh, Joonseok
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.27-37
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    • 2020
  • Low temperature dyeing properties of wool with reactive dyes and acid dyes were investigated for the feasibility study of their application to hair dyeing. The low temperature(30℃, 40℃) dyeing achieved light depth of shade in wool dyeing and reactive dyeing exhibited relatively higher color strength and chroma values than acid dyeing. Leveling agent slightly improved the levelness of the wool dyeing and the leveling properties of dyed wool at low temperature were good to excellent, irrespective of the dyes applied. Color loss during the repeated shampooing was in the range of 9.6~22.2% for reactive dyes and -7.4~31.5% for acid dyes and in some cases, the color fastness to shampooing was reasonable level. The overall experimental results showed that the application of low temperature wool reactive dyeing to hair dyeing is sufficiently feasible in terms of dyeability and color fastness to shampooing.

A Study on Piezoresistive Characteristics of Smart Nano Composites based on Carbon Nanotubes for a Novel Pressure Sensor (압력센서 개발을 위한 탄소 나노 튜브 기반 지능형 복합소재 전왜 특성 연구)

  • Kim, Sung Yong;Kim, Hyun Ho;Choi, Baek Gyu;Kang, In Hyuk;Lee, Ill Yeong;Kang, In Pil
    • Journal of Drive and Control
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    • v.13 no.1
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    • pp.43-48
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    • 2016
  • This paper presents a preliminary study on the pressure sensing characteristics of smart nano composites made of MWCNT (multi-walled carbon nanotube) to develop a novel pressure sensor. We fabricated the composite pressure sensor by using a solution casting process. Made of carbon smart nano composites, the sensor works by means of piezoresistivity under pressure. We built a signal processing system similar to a conventional strain gage system. The sensor voltage outputs during the experiment for the pressure sensor and the resistance changes of the MWCNT as well as the epoxy based on the smart nano composite under static pressure were fairly stable and showed quite consistent responses under lab level tests. We confirmed that the response time characteristics of MWCNT nano composites with epoxy were faster than the MWCNT/EPDM sensor under static loads.

Preparation of Porous Cobalt Thin Films by Using an Electrochemical Method (전기화학적 방법을 통한 다공성 코발트 박막 합성)

  • Ha, Seong-Hyeok;Shin, Heon-Cheol
    • Journal of the Korean institute of surface engineering
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    • v.53 no.6
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    • pp.312-321
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    • 2020
  • Morphology of porous cobalt electro-deposits was systematically investigated as functions of cobalt precursors in the plating bath and applied cathodic current density with a special focus on cobalt nano-rod formation. It was proved that the concentration of cobalt precursor plays little effect on the morphology of cobalt electro-deposits at relatively low plating current density while it significantly affects the morphology with increasing plating current density. Such a dependence was discussed in terms of the kinetics of two competitive reactions of cobalt reduction and hydrogen evolution. Cobalt nano-rod structure was created at specific ranges of cobalt precursor content and applied cathodic current density, and its diameter and length varied with plating time without notable formation of side branches which is usually found during dendrite formation. Specifically, the nano-rod length was preferentially increased in relative short plating time (<15 s), resulting in higher aspect ratio of nano-rod with plating time. Whereas, both the nano-rod length and diameter were increased nearly at the same level in a prolonged plating time, making the aspect ratio unchanged. From the analysis of crystal structure, it was confirmed that the cobalt nano-rod preferentially grew in the form of single crystal on a dense poly-crystalline cobalt thin film initially formed on the substrate.

Strong Red Photoluminescence from Nano-porous Silicon Formed on Fe-Contaminated Silicon Substrate

  • Kim, Dong-Lyeul;Lee, Dong-Yul;Bae, In-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.5
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    • pp.194-198
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    • 2004
  • The influences of the deep-level concentration of p-type Si substrates on the optical properties of nano-porous silicon (PS) are investigated by deep level transient spectroscopy (DLTS) and photoluminescence (PL). Utilizing a Si substrate with Fe contaminations significantly enhanced the PL intensity of PS. All the PS samples formed on Fe-contaminated silicon substrates had stronger PL yield than that of reference PS without any intentional Fe contamination but the emission peak is not significantly changed. For the PS 1000 sample with Fe contamination of 1,000 ppb, the maximum PL intensity showed about ten times stronger PL than that of the reference PS sample. From PL and DLTS results, the PL efficiency strongly depends on the Fe-related trap concentration in Si substrates.

Deposition Technology of Copper Thin Films for Multi-level Metallizations (다층배선을 위한 구리박막 형성기술)

  • 조남인
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.3
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    • pp.1-6
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    • 2002
  • A low temperature process technology of copper thin films has been developed by a chemical vapor deposition technology for multi-level metallzations in ULSI fabrication. The copper films were deposited on TiN/Si substrates in helium atmosphere with the substrate temperature between $130^{\circ}C$ and $250^{\circ}C$. In order to get more reliable metallizations, effects on the post-annealing treatment to the electrical properties of the copper films have been investigated. The Cu films were annealed at the $5 \times10^{-6}$ Torr vacuum condition and the electrical resistivity and the nano-structures were measured for the Cu films. The electrical resistivity of Cu films shown to be reduced by the post-annealing. The electrical resistivity of 2.0 $\mu \Omega \cdot \textrm{cm}$ was obtained for the sample deposited at the substrate temperature of $180^{\circ}C$ after vacuum annealed at $300^{\circ}C$. The resistivity variations of the films was not exactly matched with the size of the nano-structures of the copper grains, but more depended on the contamination of the copper films.

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The Impact of Ethanol Contents on Combustion Performance and Nano-particle Emission Characteristics from Spark Ignition Direct Injection (SIDI) Engine (에탄올 함량비가 SIDI 엔진의 연소성능과 입자상물질 배출특성에 미치는 영향에 대한 연구)

  • Cho, Jaeho;Myung, Cha-Lee;Park, Simsoo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.343-344
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    • 2014
  • Ethanol as fuel of Spark Ignition Direct Injection (SIDI) engine has become a feasible alternative due to its better anti-knock characteristics and lower nano-particle emission level. There are a number of studies on the emission characteristics from SIDI engine fuelled with various ethanol contents. In general, increase of ethanol contents leaded to decrease of nano-particle discharge, but the other researches showed reversed result at a singular range of ethanol contents. This study focused on the engine combustion performance and nano-particle emission characteristics of SIDI engine fuelled with intermediate ethanol contents.

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The study about phase phase change material at nano-scale using c-AFM method (c-AFM 기술을 이용한 나노급 상변화 소자 특성 평가에 대한 연구)

  • Hong, Sung-Hoon;Lee, Heon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.57-57
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    • 2010
  • In this study, nano-sized phase change materials were evaluated using nanoimprint lithography and c-AFM technique. The 200nm in diameter phase change nano-pillar device of GeSbTe, AgInSbTe, InSe, GeTe, GeSb were successfully fabricated using nanoimprint lithography. And the electrical properties of the phase change nano-pillar device were evaluated using c-AFM with pulse generator and voltage source.

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Enhanced Inter-Symbol Interference Cancellation Scheme for Diffusion Based Molecular Communication using Maximum Likelihood Estimation

  • Raut, Prachi;Sarwade, Nisha
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.10
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    • pp.5035-5048
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    • 2016
  • Nano scale networks are futuristic networks deemed as enablers for the Internet of Nano Things, Body area nano networks, target tracking, anomaly/ abnormality detection at molecular level and neuronal therapy / drug delivery applications. Molecular communication is considered the most compatible communication technology for nano devices. However, connectivity in such networks is very low due to inter-symbol interference (ISI). Few research papers have addressed the issue of ISI mitigation in molecular communication. However, many of these methods are not adaptive to dynamic environmental conditions. This paper presents an enhancement over original Memory-1 ISI cancellation scheme using maximum likelihood estimation of a channel parameter (λ) to make it adaptable to variable channel conditions. Results of the Monte Carlo simulation show that, the connectivity (Pconn) improves by 28% for given simulation parameters and environmental conditions by using enhanced Memory-1 cancellation method. Moreover, this ISI mitigation method allows reduction in symbol time (Ts) up to 50 seconds i.e. an improvement of 75% is achieved.

Estimation of Insulation Life of PAI/Nano Silica Hybrid Coil by Accelerated Thermal Stress (가속된 열적 스트레스에 의한 PAI / Nano Silica 하이브리드 코일의 절연수명 추정)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.68 no.1
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    • pp.52-60
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    • 2019
  • In this paper, four types of insulation coils were fabricated by adding various kinds of glycols to improve the flexibility and adhesion of insulating coils in varnish dispersed with PAI / Nano Silica_15wt%. The applied voltage and frequency were 1.5 kV / 20 kHz for accelerated life evaluation. Through the 6th temperature stress level, the cause of the insulation breakdown of the coil was ignored and only the breakdown time was measured. The Arrhenius model was chosen based on the theoretical relationship between chemical reaction rate and temperature for estimating the insulation life of the coil due to accelerated thermal stress. Three types of distributions (Weibull, Lognormal, Exponential) were selected as the relationship between thermal stress model and distribution. The average insulation lifetime was estimated under the temperature stress of four types of insulation coils through the relationship between one kind of model and three kinds of distributions.