• Title/Summary/Keyword: Nano-crystals

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The Injection of PDLC Solution Mixture in a Reduced Pressure

  • Kim, Kang-Pil;Yang, Kee-Jeong;Kim, Dae-Hwan;Choi, Byeong-Dae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.524-526
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    • 2007
  • Polymer dispersed liquid crystal (PDLC) films consist of micro-droplets of liquid crystals dispersed in a polymer matrix. To make wide area PDLC filled devices, it is necessary to develop reliable method of vacuum injection of PDLC solution instead of the capillary injection. However, well-known 2-ethylhexylacrylate (EHA), main element of a prepolymer, exhibits the volatility problems, when the PDLC solution is placed under the low pressure. In this study, we developed the vacuum injection process to fill a wide area cell. Experimental results indicate that the $V_{90}$(turn-on voltage) of the PDLC cell made by a vacuum injection method are lower than that of the PDLC cell made by a capillary injection method.

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Colloidal Engineering for Nano-Bio Fusion Research (Nano-Bio 융합 연구를 위한 콜로이드 공학)

  • Moon, Jun Hyuk;Yi, Gi-Ra;Lee, Sang-Yup;So, Jae-Hyun;Kim, Young-Seok;Yoon, Yeo-Kyun;Cho, Young-Sang;Yang, Seung-Man
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.647-659
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    • 2008
  • Colloids are a heterogeneous system in which particles of a few nanometers to hundreds micrometers in size are finely dispersed in liquid medium, but show homogeneous properties in macroscopic scale. They have attracted much attention not only as model systems of natural atomic and molecular self-assembled structures but also as novel structural materials of practical applications in a wide range of areas. In particular, recent advances in colloidal science have focused on nano-bio materials and devices which are essential for drug discovery and delivery, diagnostics and biomedical applications. In this review, first we introduce nano-bio colloidal systems and surface modification of colloidal particles which creates various functional groups. Then, various methods of fabrication of colloidal particles using holographic lithography, microfluidics and virus templates are discussed in detail. Finally, various applications of colloids in metal inks, three-dimensional photonic crystals and two-dimensional nanopatterns are also reviewed as representative potential applications.

The Fluorescence Immunoassay of lung Cancer Serum Diomarkers using Quantum dots

  • Kang, Ji-Min;Ahn, Jin-Seok;Kim, Jin-Hoon;Kong, Won-Ho;Park, Keun-Chil;Kim, Won-Seog;Seo, Soo-Won
    • Journal of Biomedical Engineering Research
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    • v.30 no.2
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    • pp.122-128
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    • 2009
  • Cancer serum biomarkers have advanced our ability to more accurately predict tumor classification, prognostic/metastatic potential, and response potential to novel chemotherapies. Serum amyloid A (SAA) and Vascular endothelial growth factor (VEGF) have potential utility as a serum biomarker for lung cancer. Quantum dots, nanometer-sized crystals, have a high quantum yield, sensitivity, and pronounced photostability. The properties of quantum dots can be efficiently applied to the detection of serum biomarkers in immunoassays as fluorescent probe. We used quantum dots as fluorescent probes in immunoassays and attempted to detect serum amyloid A and vascular endothelial growth factor as serum biomarkers of lung cancer. This fluorescence immunoassay based on the properties of quantum dots is applicable to the detection of serum biomarkers for lung cancer. The fluorescence immunoassay with quantum dots should allow the efficient and specific detection of serum amyloid A (SAA) for the possible diagnosis of lung cancer.

Electro-Optic Characteristics according to Distance between Pixel Electrodes in Fringe In-plane field Switching mode (화소 전극 간 거리가 Fringe In-plane field Switching mode의 전기 광학 특성에 미치는 영향)

  • Kim, Min-Su;Park, Ji-Woong;Jung, Jun-Ho;Ha, Kyung-Su;Lim, Young-Jin;Lee, Myong-Hoon;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.337-338
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    • 2008
  • We have studied electro-optic characteristics of a high performance liquid crystal display using Fringe In-plane field Switching (FIS) mode. The strong electric fields cause more liquid crystals to reorient almost in plane above and between the pixel electrodes. As a result, the operation voltage is lower and transmittance is higher than those of Fringe Field Switching (FFS) and In-Plane Switching (IPS) modes. Apparently, the transmittance depends on voltage applied at the configurations of FIS mode which are proposed. Therefore, we have studied certain length of between electrodes for maximum transmittance and light intensity.

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Liquid Crystal-based Imaging of Enzymatic Reactions at Aqueous-liquid Crystal Interfaces Decorated with Oligopeptide Amphiphiles

  • Hu, Qiongzheng;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1262-1266
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    • 2010
  • In this study, we investigated the use of liquid crystals to selectively detect the activity of enzymes at interfaces decorated with oligopeptide-based membranes. We prepared a mixed monolayer of tetra(ethylene glycol)-terminated lipids and carboxylic acid-terminated lipids at the aqueous-liquid crystal (LC) interface. The 17 amino-acid oligopeptide SNFKTIYDEANQFATYK was then immobilized onto this mixed monolayer through N-hydroxysuccinimide-activation of the carboxylic acid groups. We examined the orientational behavior of nematic 4-cyano-4'-pentylbiphenyl (5CB) after conjugation of the 17 amino-acid oligopeptide with the mixed monolayer assembled at the interface. Immobilization of the oligopeptide caused orientational transitions in 5CB, with a change from homeotropic (perpendicular) to tilted alignment, which was primarily due to the reorganization of the monolayer. The orientation of the 5CB molecules returned to its homeotropic state after contacting the interface containing ${\alpha}$-chymotrypsin, which can cleave the immobilized oligopeptide. Control experiments confirmed that the enzymatic activity of ${\alpha}$-chymotrypsin triggered the ordering transitions in the LC. These results suggest that the LC can provide a facile method for selective detection of enzymatic activity.

PDMS Stamp Fabrication for Photonic Crystal Waveguides (광자결정 도파로 성형용 PDMS 스탬프 제작)

  • Oh, Seung-Hun;Choi, Du-Seon;Kim, Chang-Seok;Jeong, Myung-Yung
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.4 s.193
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    • pp.153-158
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    • 2007
  • Recently nano imprint lithography to fabricate photonic crystal on polymer is preferred because of its simplicity and short process time and ease of precise manufacturing. But, the technique requires the precise mold as an imprinting tool for good replication. These molds are made of the silicon, nickel and quartz. But this is not desirable due to complex fabrication process, high cost. So, we describe a simple, precise and low cost method of fabricating PDMS stamp to make the photonic crystals. In order to fabricate the PDMS mold, we make the original pattern with designed hole array by finding the optimal electron beam writing condition. And then, we have tried to fabricate PDMS mold by the replica molding with ultrasonic vibration and pressure system. We have used the cleaning process to solve the detaching problem on the interface. Using these methods, we acquired the PDMS mold for photonic crystals with characteristics of a good replication. And the accuracy of replication shows below 1% in 440nm at diameter and in 610nm at lattice constant by dimensional analysis by SEM and AFM.

Durability Enhancement in Nano-Silica Admixed Reinforced Mortar

  • Saraswathy, Velu;Karthick, Subbiah;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.297-306
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    • 2014
  • Recently nano-materials are gaining more importance in the construction industry due to its enhanced energy efficiency, durability, economy, and sustainability. Nano-silica addition to cement based materials can control the degradation of the fundamental calcium-silicate-hydrate reaction of concrete caused by calcium leaching in water as well as block water penetration and therefore lead to improvements in durability. In this paper, the influence of synthesized nano silica from locally available rice husk on the mechanical properties and corrosion resistant properties of OPC (Ordinary Portland Cement) has been studied by conducting various experimental investigations. Micro structural properties have been assessed by conducting Scanning Electron Microscopy, Thermo gravimetry and Differential Thermal Analysis, X-Ray Diffraction analysis, and FTIR studies. The experimental results revealed that NS reacted with calcium hydroxide crystals in the cement paste and produces Calcium Silicate Hydrate gel which enhanced the strength and acts as a filler which filled the nano pores present in concrete. Hence the strength and corrosion resistant properties were enhanced than the control.

Electrochemical Factors Affecting the Magnetic Properties of Co based Magnetic Nanowires (Co계 자성합금 나노와이어의 특성에 영향을 미치는 전기화학적 변수)

  • Lee, Jong-Wook;Park, Ho-Dong;Lee, Kwan-Hyi;Kim, Gyeung-Ho;Jeung, Won-Young
    • Journal of the Korean Electrochemical Society
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    • v.8 no.3
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    • pp.125-129
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    • 2005
  • We have investigated the electrochemical factors affecting the magnetic properties of hard magnetic CoP nanowires and soft magnetic CoFe nanowires fabricated by ac electrodeposition into self-made AAO(anodic aluminum oxide) nano-templates. AAO template having nano scale pores of high aspect ratio has been prepared through 2-step anodizing of aluminum foil in sulfuric acid. Hard Magnetic properties of CoP nanowires were highly conditional on the applied ac potential which could be a decisive factor to make CoP nanowires made up of either pure hcp crystals or a mixture of hop crystals and fcc crystals. On the contrary to CoFe films, there was no anomalous codeposition in the electrodeposition of soft magnetic CoFe nanowires which exhibited their best saturation magnetization of 238 emu/g at the composition of $Co_{30}Fe_{70}$.

Charge Flow in KH2PO4 Lattice Structure by Using the Proton-Beam Irradiation

  • Han, Doug-Young;Han, Jun-Hee;Lee, Cheal-Eui;Kim, Se-Hun
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.2
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    • pp.111-118
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    • 2008
  • The mechanism of charge flow has been probed by measuring the $^{1}H$ chemical shift on a proton-irradiated ${KH_2}{PO_4}$ (KDP) single crystal. The proton irradiation caused the increase in $^{1}H$ chemical shift. It can be interpreted as the electronic charge transfer from the proton to oxygen atom, accompanied with the proton displacement along the hydrogen bond. For the high resolution $^{1}H$ chemical shift measurement, CRAMPS (Combined Rotation And Multiple Pulses) technique is utilized.

Nano-master fabrication for photonic crystal waveguides (광결정 도파로용 나노 마스터 제작)

  • 최춘기;한상필;정명영
    • Journal of the Korean Vacuum Society
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    • v.12 no.4
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    • pp.288-292
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    • 2003
  • The fabrication of silicon nano-master with pillar structures using E-beam lithography and ICP etching was investigated for application of 2-dimensional polymer photonic crystal waveguides with air hole structures. Pillar structures with square, hexagon, dodecagon and circle were successfully fabricated. The diameters and structures of fabricated pillars were measured by CD-SEM and SPM-AFM. It was found that the optimal dose for complete circle pillar structures was 432 $\mu$C/$\textrm{cm}^2$.