• Title/Summary/Keyword: Nano sheet

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Fabrication of Conductive Polymer Resistors Using Ink-jet Printing Technology (잉크젯 프린팅 기술을 이용한 전도성 폴리머 저항의 제작)

  • Lee, Sang-Ho;Kim, Myong-Ki;Shin, Kwon-Yong;Kang, Kyung-Tae;Park, Moon-Soo;Hwang, Jun-Young;Kang, Heui-Seok
    • Proceedings of the KIEE Conference
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    • 2007.11a
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    • pp.98-99
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    • 2007
  • This study has successfully demonstrated the direct fabrication of polymer resistors using ink-jet printing technology as an alternative patterning to traditional photolithography. The polymer resistors were fabricated just by two layer processes using a ink-jet printer (DMP-2800, Fujifilm Dimatix). First, resistive materials was patterned by a ink-jet printing with the desired width and length. Next, resistor fabrication was completed by printing metal contact pads on the both sides of the polymer resistor. We used poly (3,4-ethylene dioxythiophene) poly(styrenesulfonate)(PEDOT:PSS) for the resistor material and a nano-sized silver colloid for the metal contact pads. We characterized the electrical properties of PEDOT:PSS by measuring sheet resistance and specific resistance on a glass substrate. From analysis of the measured resistances, the electrical resistances of the polymer resistors linearly increased as a function of printed width and length of resistors. The accuracy of the fabricated polymer resistor showed about $0.6{\sim}2.5%$ error for the same dimensions.

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Preparation and Electrochemical Behaviors of Petal-like Nickel Cobaltite/Reduced Graphene Oxide Composites for Supercapacitor Electrodes

  • Kim, Jeonghyun;Park, Soo-Jin;Kim, Seok
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.324-330
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    • 2019
  • Petal-like nickel cobaltite ($NiCo_2O_4$)/reduced graphene oxide (rGO) composites with different $rGO-to-NiCo_2O_4$ weight ratios were synthesized using a simple hydrothermal method and subsequent thermal treatment. In the $NiCo_2O_4/rGO$ composite, the $NiCo_2O_4$ 3-dimensional nanomaterials contributed to the improvement of electrochemical properties of the final composite material by preventing the restacking of the rGO sheet and securing ion movement passages. The composite structure was examined by field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and Fourier-transform infrared (FT-IR) spectroscopy. The FE-SEM and TEM images showed that petal-like $NiCo_2O_4$ was supported on the rGO surface. Cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) were used for the electrochemical analysis of composites. Among the prepared composites, $0.075g\;rGO/NiCo_2O_4$ composite showed the highest specific capacitance of $1,755Fg^{-1}$ at a current density of $2Ag^{-1}$. The cycle performance and rate capability of the composite material were higher than those of using the single $NiCo_2O_4$ material. These nano-structured composites could be regarded as valuable electrode materials for supercapacitors that require superior performance.

Effects of binary conductive additives on electrochemical performance of a sheet-type composite cathode with different weight ratios of LiNi0.6Co0.2Mn0.2O2 in all-solid-state lithium batteries

  • Ann, Jiu;Choi, Sunho;Do, Jiyae;Lim, Seungwoo;Shin, Dongwook
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.413-418
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    • 2018
  • All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

Buckling and vibration of porous sandwich microactuator-microsensor with three-phase carbon nanotubes/fiber/polymer piezoelectric polymeric nanocomposite face sheets

  • Arani, Ali Ghorbanpour;Navi, Borhan Rousta;Mohammadimehr, Mehdi
    • Steel and Composite Structures
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    • v.41 no.6
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    • pp.805-820
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    • 2021
  • In this research, the buckling and free vibration of three-phase carbon nanotubes/ fiber/ polymer piezoelectric nanocomposite face sheet sandwich microbeam with microsensor and micro-actuator surrounded in elastic foundation based on modified couple stress theory (MCST) is investigated. Three types of porous materials are considered for sandwich core. Higher order (Reddy) and sinusoidal shear deformation beam theories are employed for the displacement fields. Sinusoidal surface stress effects are extracted for sinusoidal shear deformation beam theory. The equations of motion are derived by Hamilton's principle and then the natural frequency and critical buckling load are obtained by Navier's type solution. The determined results are in good agreement with other literatures. The detailed numerical investigation for various parameters is performed for this microsensor-microactuator. The results reveal that the microsensor-microactuator enhanced by increasing of Skempton coefficient, carbon nanotubes diameter length to thickness ratio, small scale factor, elastic foundation, surface stress constants and reduction in porous coefficient, micro-actuator voltage and CNT weight fraction. The valuable results can be expedient for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.

An innovative approach for analyzing free vibration in functionally graded carbon nanotube sandwich plates

  • Shahabeddin Hatami;Mohammad J. Zarei;Seyyed H. Asghari Pari
    • Advances in nano research
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    • v.17 no.1
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    • pp.19-32
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    • 2024
  • Functionally graded-carbon nanotube (FG-CNT) is expected to be a new generation of materials with a wide range of potential applications in technological fields such as aerospace, defense, energy, and structural industries. In this paper, an exact finite strip method for functionally graded-carbon nanotube sandwich plates is developed using first-order shear deformation theory to get the exact natural frequencies of the plates. The face sheets of the plates are made of FG-CNT with continuous and smooth grading based on the power law index. The equations of motion have been generated based on the Hamilton principle. By extracting the exact stiffness matrix for any strip of the sandwich plate as a non-algebraic function of natural frequencies, it is possible to calculate the exact free vibration frequencies. The accuracy and efficiency of the current method is established by comparing its findings to the results of the literature works. Examples are presented to prove the efficiency of the generated method to deal with various problems, such as the influence of the length-to-height ratio, the power law index, and a core-to-face sheet thickness of the single and multi-span sandwich plates with various boundary conditions on the natural frequencies. The exact results obtained from this analysis can check the validity and accuracy of other numerical methods.

An adaptive neuro-fuzzy approach using IoT data in predicting springback in ultra-thin stainless steel sheets with consideration of grain size

  • Jing Zhao;Lichun Wan;Mostafa Habibi;Ameni Brahmia
    • Advances in nano research
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    • v.17 no.2
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    • pp.109-124
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    • 2024
  • In the era of smart manufacturing, precise prediction of springback-a common issue in ultra-thin sheet metal forming- and forming limits are critical for ensuring high-quality production and minimizing waste. This paper presents a novel approach that leverages the Internet of Things (IoT) and Artificial Neural Networks (ANN) to enhance springback and forming limits prediction accuracy. By integrating IoT-enabled sensors and devices, real-time data on material properties, forming conditions, and environmental factors are collected and transmitted to a central processing unit. This data serves as the input for an ANN model, which is trained with crystal plasticity simulations and experimental data to predict springback with high precision. Our proposed system not only provides continuous monitoring and adaptive learning capabilities but also facilitates real-time decision-making in manufacturing processes. Experimental results demonstrate significant improvements in prediction accuracy compared to traditional methods, highlighting the potential of IoT and ANN integration in advancing smart manufacturing. This approach promises to revolutionize quality control and operational efficiency in the industry, paving the way for more intelligent and responsive manufacturing systems.

Fabrication of Supercapacitors using Silver Nano Paste and Gel Electrolyte (은 나노 페이스트와 젤 전해질을 이용한 슈퍼캐패시터 제작)

  • Yoon, Seong Man;Jang, Hyunjung;Kim, Dae Won;Jang, Yunseok;Jo, Jeongdai;Go, Jeung Sang
    • Clean Technology
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    • v.19 no.4
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    • pp.410-415
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    • 2013
  • The supercapacitors were fabricated using silver (Ag) nano paste and activated carbon paste on the polyimide (PI) film and 5% potassium polyacrylate (PAAK) was used for gel electrolyte. In this paper, the current collector film and the electrode film were fabricated using screen printing. The thickness of printed silver paste was $7.3{\mu}m$ and the sheet resistance has the range of $5-7m{\Omega}/square$. An activated carbon with a surface area of $1,968m^2/g$, an electronic conducting agent (SUPER P, TIMCAL) and poly (4-vinylphenol) were mixed in 2-(2-buthoxyethoxy) ethyl acetate (BCA) with a ratio of 7:1:3 to fabricate the electrode paste. To analyze electrochemical characteristics, cyclic voltammetry was performed to evaluate the stability of the devices under the voltage range of -0.5-0.5 V. The calculated specific capacitances were 44.04 and 8.62 F/g for 10 and 500 mV/s scan rates, respectively.

Comparison of characteristics of silver-grid transparent conductive electrodes for display devices according to fabrication method (제조공법에 따른 디스플레이 소자용 silver-grid 투명전극층의 특성 비교)

  • Choi, Byoung Su;Choi, Seok Hwan;Ryu, Jeong Ho;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.2
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    • pp.75-79
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    • 2017
  • Honeycomb-shaped Ag-grid transparent conductive electrodes (TCEs) were fabricated using two different processes, high density plasma etching and lift-off, and the optical and electrical properties were compared according to the fabrication method. For the fabrication of the Ag-grid TCEs by plasma etching, etch characteristics of the Ag thin film in $10CF_4/5Ar$ inductively coupled plasma (ICP) discharges were studied. The Ag etch rate increased as the power increased at relatively low ICP source power or rf chuck power conditions, and then decreased at higher powers due to either decrease in $Ar^+$ ion energy or $Ar^+$ ion-assisted removal of the reactive F radicals. The Ag-grid TCEs fabricated by the $10CF_4/5Ar$ ICP etching process showed better grid pattern transfer efficiency without any distortion or breakage in the grid pattern and higher optical transmittance values of average 83.3 % (pixel size $30{\mu}m/line$ width $5{\mu}m$) and 71 % (pixel size $26{\mu}m/line$ width $8{\mu}m$) in the visible range of spectrum, respectively. On the other hand, the Ag-grid TCEs fabricated by the lift-off process showed lower sheet resistance values of $2.163{\Omega}/{\square}$ (pixel size $26{\mu}m/line$ width $18{\mu}m$) and $4.932{\Omega}/{\square}$ (pixel size $30{\mu}m/line$ width $5{\mu}m$), respectively.

Changes of the surface hardness and the light transmittance of PET film by ion implantations (이온 주입에 의한 PET막의 표면경도변화 및 광 투과도 변화)

  • 박재원;이재형;이재상;장동욱;최병호;한준희
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.241-246
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    • 2001
  • Single or dual ion implantations were performed onto the transparent polyethylene terephthalate(PET) sheet, and the surface hardness and the light transmittance in the visual-UV range were examined. Nanoindentation showed that the surface hardness was the highest at about 50 nm depth from the surface and was increased by about 3 times when nitrogen ions were implanted with energy and dose of 90 keV and $1\times10^{15}\textrm{/cm}^2$ respectively. When dual ions such as He+N and N+C ions were implanted into PET, the hardness was increased even more than the case only N ions were implanted. Especially, when PET were implanted with N+C dual ions, the surface hardness of PET increased 5 times more as compared to when implanted with N ions alone. The light at the 550 nm wavelength(visual range) transmitted more than 85%, which is close to that of as-received PET, and at the wavelength below 300 nm(UV range) the rays were absorbed more than 95% as traveling through the sheet. implying that there are processing parameters which the ion implanted PET maintains the transparency and absorbs the UV rays. It can be considered that the increase in the hardness of polymeric materials is attributed to not only cross linking but also forming hard inclusions such as hard C-N compounds, as evidenced by the formation of the highest hardness when both N and C ions are implanted onto PET.

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The Enhancement of Thermal Stability of Nickel Monosilicide by Ir and Co Insertion (Ir과 Co를 첨가한 니켈모노실리사이드의 고온 안정화 연구)

  • Yoon, Ki-Jeong;Song, Oh-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1056-1063
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    • 2006
  • Thermal evaporated 10 nm-Ni/l nm-Ir/(or polycrystalline)p-Si(100) and 10 nm-$Ni_{50}Co_{50}$/(or polycrystalline)p-Si(100) films were thermally annealed using rapid thermal annealing fur 40 sec at $300{\sim}1200^{\circ}C$. The annealed bilayer structure developed into Ni(Ir or Co)Si and resulting changes in sheet resistance, microstructure, phase and composition were investigated using a four-point probe, a scanning electron microscopy, a field ion beam, an X-ray diffractometer and an Auger electron spectroscope. The final thickness of Ir- and Co-inserted nickel silicides on single crystal silicon was approximately 20$\sim$40 nm and maintained its sheet resistance below 20 $\Omega$/sq. after the silicidation annealing at $1000^{\circ}C$. The ones on polysilicon had thickness of 20$\sim$55 nm and remained low resistance up to $850^{\circ}C$. A possible reason fur the improved thermal stability of the silicides formed on single crystal silicon substrate is the role of Ir and Co in preventing $NiSi_2$ transformation. Ir and Co also improved thermal stability of silicides formed on polysilicon substrate, but this enhancement was lessened due to the formation of high resistant phases and also a result of silicon mixing during high temperature diffusion. Ir-inserted nickel silicides showed surface roughness below 3 nm, which is appropriate for nano process. In conclusion, the proposed Ir- and Co- inserted nickel silicides may be superior over the conventional nickel monosilicides due to improved thermal stability.

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