• Title/Summary/Keyword: Nano plates

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Analyzing corrosion rates of TiO2 nanotubes/titanium separation passive layer under surface and crystallization changes

  • Torres, I. Zamudio;Dominguez, A. Sosa;Bueno, J.J. Perez;Meas, Y.;Lopez, M.L. Mendoza;Dector, A.
    • Advances in nano research
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    • v.10 no.3
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    • pp.211-219
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    • 2021
  • The evaluation of the corrosion resistance of titanium with a TiO2 nanotubes top layer was carried out (TiO2 NT). These nanostructures were evolved into anatase nanoparticles without heat treatment in an aqueous medium, which is a novel phenomenon. This work analyzes the layer between the nanotube bottom and the substrate, which is thin and still susceptible to corrosion. The bottom of TiO2 nanotubes having Fluor resulting from the synthesis process changed between amorphous to crystalline anatase with a crystallite size of about 4 nm, which influenced the corrosion rates. Four kinds of samples were evaluated. A) NT by Ti anodizing; B) NTSB for Ti plates, either modifying its surface or anodizing the modified surface; C) NT-480 for anodized Ti and heat-treated (480℃) for reaching the anatase phase; D) NTSB-480 for Ti plates, first, modifying its surface using sandblast, after that, anodizing the modified surface, and finally, heat-treated to 480℃ to compare with samples having induced crystallization and passivation. Four electrochemical techniques were used to evaluate the corrosion rates. The surfaces having TiO2 nanotubes with a sandblast pre-treatment had the highest resistance to corrosion.

TPS Analysis of Various Metal Plates for Belt Source Evaporation in AMOLED Manufacturing

  • Hwang, Chang-Hun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1603-1606
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    • 2007
  • The TPS (Temperature Programmed Sublimation) technology has been developed to monitor the plane evaporation of the organic films and introduced in SID2007, P53.[4] The Alq3 organic film is deposited on various metal surface such as Cu, Ti, Invar, STS to sublimate. The TPS signal confirms that the Alq3 film consists of nano scale film phase and bulk phase on all the metal plates. The sublimation temperature of the Alq3 film was much lower ($130^{\circ}C$) than the vapor temperature ($265^{\circ}$) of the Alq3 powder.

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Biaxial buckling analysis of sigmoid functionally graded material nano-scale plates using the nonlocal elaticity theory (비국소 탄성이론을 이용한 S형상 점진기능재료 나노-스케일 판의 이축 좌굴해석)

  • Lee, Won-Hong;Han, Sung-Cheon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.5930-5938
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    • 2013
  • The sigmoid functionally graded mateiral(S-FGM) theory is reformulated using the nonlocal elatictiry of Erigen. The equation of equilibrium of the nonlocal elasticity are derived. This theory has ability to capture the both small scale effects and sigmoid function in terms of the volume fraction of the constituents for material properties through the plate thickness. Navier's method has been used to solve the governing equations for all edges simply supported boundary conditions. Numerical solutions of biaxial buckling of nano-scale plates are presented using this theory to illustrate the effects of nonlocal theory and power law index of sigmoid function on buckling load. The relations between nonlocal and local theories are discussed by numerical results. Further, effects of (i) power law index, (ii) length, (iii) nonlocal parameter, (iv) aspect ratio and (v) mode number on nondimensional biaxial buckling load are studied. To validate the present solutions, the reference solutions are discussed.

Electrical Properties of Plate Typed Shunt Resistors with Low TCR Property (낮은 TCR 특성을 가지는 플레이트 션트저항의 전기적 특성)

  • Lim, Youngtaek;Kim, Eun-Min;Lee, Sang-Won;Ahn, Jeong-Rae;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.3
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    • pp.219-222
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    • 2019
  • In this study, we fabricated plate-type shunt resistors with thermal stability by parallelly connecting metal alloy plates with positive temperature coefficient of resistance (TCR) and carbon nanotube (CNT) plates with negative TCR. The metal alloy plates, which were prepared by alloying Cu and Mn with a composition of 91 wt% of Cu and 9 wt% of Mn, showed around $800ppm/^{\circ}C$ of TCR, and the CNT plates prepared from the CNT solution by using the vacuum filtration method showed around $-800ppm/^{\circ}C$ of TCR. The shunt resistor that was fabricated by stacking metal alloy plates and CNT plates in this work showed about $46.93ppm/^{\circ}C$ of TCR. Therefore, we conclude that a shunt resistor with low TCR can be realized by simply adjusting the TCR of the metal alloy only, because the TCR of the CNT plate has an identical value.

Thermal buckling of rectangular sandwich plates with advanced hybrid SMA/CNT/graphite/epoxy composite face sheets

  • Saeed Kamarian;Jung-Il Song
    • Advances in nano research
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    • v.14 no.3
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    • pp.261-271
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    • 2023
  • The present study follows three main goals. First, an analytical solution with high accuracy is developed to assess the effects of embedding pre-strained shape memory alloy (SMA) wires on the critical buckling temperatures of rectangular sandwich plates made of soft core and graphite fiber/epoxy (GF/EP) face sheets based on piecewise low-order shear deformation theory (PLSDT) using Brinson's model. As the second goal, this study compares the effects of SMAs on the thermal buckling of sandwich plates with those of carbon nanotubes (CNTs). The glass transition temperature is considered as a limiting factor. For each material, the effective ranges of operating temperature and thickness ratio are determined for real situations. The results indicate that depending on the geometric parameters and thermal conditions, one of the SMAs and CNTs may outperform the other. The third purpose is to study the thermal buckling of sandwich plates with advanced hybrid SMA/CNT/GF/EP composite face sheets. It is shown that in some circumstances, the co-incorporation of SMAs and CNTs leads to an astonishing enhancement in the critical buckling temperatures of sandwich plates.

Nonlinear bending and post-buckling behaviors of FG small-scaled plates based on modified strain gradient theory using Ritz technique

  • Ghannadpour, S. Amir M.;Khajeh, Selma
    • Advances in nano research
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    • v.13 no.4
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    • pp.393-406
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    • 2022
  • In the present article, functionally graded small-scaled plates based on modified strain gradient theory (MSGT) are studied for analyzing the nonlinear bending and post-buckling responses. Von-Karman's assumptions are applied to incorporate geometric nonlinearity and the first-order shear deformation theory is used to model the plates. Modified strain gradient theory includes three length scale parameters and is reduced to the modified couple stress theory (MCST) and the classical theory (CT) if two or all three length scale parameters become zero, respectively. The Ritz method with Legendre polynomials are used to approximate the unknown displacement fields. The solution is found by the minimization of the total potential energy and the well-known Newton-Raphson technique is used to solve the nonlinear system of equations. In addition, numerical results for the functionally graded small-scaled plates are obtained and the effects of different boundary conditions, material gradient index, thickness to length scale parameter and length to thickness ratio of the plates on nonlinear bending and post-buckling responses are investigated and discussed.

Optical diffraction gratings embedded in BK-7 glasses by tightly focused femtosecond laser

  • Yoon, Ji Wook;Choi, Won Suk;Kim, Hoon Young;Cho, Sung-Hak
    • Laser Solutions
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    • v.17 no.2
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    • pp.19-25
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    • 2014
  • Optical embedded diffraction gratings with the bulk modification in BK-7 glass plates excited by tightly focused high-intensity femtosecond (130fs) Ti: sapphire laser (peak wavelength = 790nm) were demonstrated. The structural modifications with diameters ranging from 400nm to $4{\mu}m$ were photo-induced after plasma formation occurred upon irradiation with peak intensities of more than $1{\times}1013W/cm^2$. The graded refractive index profile was fabricated to be a symmetric around from the center of the point at which low-density plasma occurred. The maximum refractive index change was estimated to be $1.5{\times}10^{-2}$. The two optical embedded gratings in BK-7 glass plate were demonstrated with refractive index modification induced by the scanning of low-density plasma formation.

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Corrosion Behavior of Nanotube Formed on the Bone Plate of Ti-6Al-4V Alloy for Dental Use (치과용 Ti-6Al-4V 합금 골 고정판 표면에 형성된 나노튜브의 부식거동)

  • Kim, Won-Gi;Lee, Chung-Hwan;Chung, Chae-Heon;Choe, Han-Cheol
    • Journal of the Korean institute of surface engineering
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    • v.43 no.1
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    • pp.25-30
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    • 2010
  • Titanium and titanium alloys are widely used for orthopedic and dental implants for their superior mechanical properties, low modulus, excellent corrosion resistance and good biocompatibility. In this study, corrosion behaviors of nanotube formed on the bone plate of Ti-6Al-4V alloy for dental use have been investigated. $TiO_2$ nanotubes were formed on the dental bone plates by anodization in $H_3PO_4$ containing 0.6 wt % NaF solution at $25^{\circ}C$. Electrochemical experiments were performed using a conventional three-electrode configuration with a platinum counter electrode and a saturated calomel reference electrode. Anodization was carried out using a scanning potentiostat (EG&G Co, Model 263A USA), and all experiments were conducted at room temperature. The surface morphology was observed using field emission scanning electron microscopy (FE-SEM) and energy dispersive x-ray spectroscopy(EDS). The corrosion behavior of the dental bone plates was examined using potentiodynamic test(potential range of -1500~2000 mV) in a 0.9% NaCl solution by potentiostat (EG&G Co, PARSTAT 2273. USA). The inner diameter of nanotube was about 150~180 nm with wall thickness of about 20 nm. The interspace of nanotube to nanotube was 50 nm. The passive region of the nanotube formed bone plates showed the broad range compared to non-nanotube formed bone plates. The corrosion surface of sample was covered with corrosion products.

Self-assembly of Dumbbell-shaped Rod Amphiphiles Based on Dodeca-p-phenylene

  • Huang, Zhegang;Liu, Libin;Lee, Eun-Ji;Lee, Myong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.29 no.8
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    • pp.1485-1490
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    • 2008
  • Dumbbell-shaped aromatic amphiphilic molecules consisting of a dodeca-p-phenylene as a rigid segment and oligoether dendrons as a flexible chains were synthesized, characterized, and their aggregation behavior was investigated in the bulk and at the air-water interface. In contrast to the molecule 2 which shows a nematic liquid crystalline state, molecule 1 based on shorter dendritic chains was observed to self-assemble into a 3-D primitive orthorhombic supercrystal. And molecule 1 at the air-water interface was observed to reorganize from circular plates to ring structures by lateral compressions.