• Title/Summary/Keyword: Nano 입자

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Study on Graphite/Polypropylene/Liquid Crystalline Polymer Composite for a Bipolar Plate of Polymer Electrolyte Membrane Fuel Cell (고분자 전해질막 수소 연료 전지 분리판 용 흑연/폴리프로필렌/액정고분자 복합 재료의 특성에 관한 연구)

  • Dhungana, Biraj;Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3627-3632
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    • 2015
  • We investigated mechanical, rheological and electrical properties of graphite/PP/LCP composites for a bipolar plate of the polymer electrolyte membrane fuel cell. The composites containing very low molecular weighted PP showed much higher electrical conductivity compared with other thermoplastics. This was attributed to the enhanced dispersion of graphite particles due to the low viscosity of the PP. The conductivity of the composites was increased in a great extent by incorporation of small amount of carbon nano tube (CNT). However, the acid treated CNT which contains oxygen atoms did not increase the conductivity of the composite. From this result, it is concluded that the CNT has higher affinity with non polar polymer. The composite with low molecular weighted PP provided good processability so that the composites can be processed by an injection molding while the mechanical strength is deficient compared to other polymers. In order to reinforce the low mechanical property, LCP/PP was used as a binder and the graphite/PP/LCP composite showed the higher conductivity and moderate mechanical strength maintaining suitable processability.

Numerical analysis on thermal-fluidic characteristics of the magnetic fluid in a cavity using GSMAC (GSMAC법을 이용한 밀폐된 정방형관내 자성유체의 열-유동 특성에 관한 해석적 연구)

  • Seo, Jae-Hyeong;Lee, Moo-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.997-1002
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    • 2013
  • The article is aiming to investigate the thermal-fluidic characteristics of magnetic fluid in a cavity using GSMAC (generalized-simplified marker and cell method). The transport equations of the magnetic fluid are including the continuity equation, momentum equation and energy equation for natural convection and Maxwell equation and magnetization equation of magnetite nano-sized particles motion. In addition, the heat transfer characteristics such as temperatures and Nusselt numbers and flow characteristics such as streamlines and isotherms of the magnetic fluid were analyzed with the intensity and direction of the magnetic fields. As a result, the thermal-fluidic characteristics of the magnetic fluid in a cavity were could be controlled by the intensity and direction of the magnetic fields.

Surface Coating of SiO2 on TiO2-natural Zeolite Composite Particles and Its Characterization (실리카 코팅된 TiO2-천연 제올라이트 복합입자 제조와 특성평가)

  • Lim, Hyung-Mi;Jung, Ji-Sook;Lee, Dong-Jin;Lee, Seung-Ho
    • Korean Journal of Materials Research
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    • v.16 no.11
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    • pp.692-697
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    • 2006
  • Deodorization of natural zeolites have been improved not only for polar but also for non-polar pollutants by sucessive ion exchanges of H and Ag ions starting from Korean natural zeolite with high adsorption capacity. The modified zeolites with $TiO_2$ coating on the surface revealed high deodorization and photocatalytic decomposition effects. Further modification was made with $10{\sim}20nm$ silica nano particles coating on the surface, the resulting composite particles of $SiO_2/TiO_2/modified$ natural zeolite revealed not only comparable deodorization but also better durability and resisatnce to color change compared to the $TiO_2$/modified natural zeolite without much compensation of photocatalytic decomposition effect, when the composite particles were exposed to the polypropylene non-woven fiber coated with organic binder. It is expected for the composite particle prepared here to be used as indoor building materials for indoor air quality control.

Biostability and Drug Delivery Efficiency of γ-Fe2O3 Nano-particles by Cytotoxicity Evaluation (세포독성 평가를 통한 γ-Fe2O3 나노입자의 생체안정성 및 약물전달효율)

  • Lee, Kwon-Jai;An, Jeung-Hee;Shin, Jae-Soo;Kim, Dong-Hee;Yoo, Hwa-Seung;Cho, Chong-Kwan
    • Korean Journal of Materials Research
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    • v.20 no.3
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    • pp.132-136
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    • 2010
  • This study examined the biostability and drug delivery efficiency of g-$Fe_2O_3$ magnetic nanoparticles (GMNs) by cytotoxicity tests using various tumor cell lines and normal cell lines. The GMNs, approximately 20 nm in diameter, were prepared using a chemical coprecipitation technique, and coated with two surfactants to obtain a water-based product. The particle size of the GMNs loaded on hangamdan drugs (HGMNs) measured 20-50 nm in diameter. The characteristics of the particles were examined by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-TEM) and Raman spectrometer. The Raman spectrum of the GMNs showed three broad bands at 274, 612 and $771\;cm^1$. A 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) assay showed that the GMNs were non-toxic against human brain cancer cells (SH-SY5Y, T98), human cervical cancer cells (Hela, Siha), human liver cancer cells (HepG2), breast cancer cells (MCF-7), colon cancer cells (CaCO2), human neural stem cells (F3), adult mencenchymal stem cells (B10), human kidney stem cells (HEK293 cell), human prostate cancer (Du 145, PC3) and normal human fibroblasts (HS 68) tested. However, HGMNs were cytotoxic at 69.99% against the DU145 prostate cancer cell, and at 34.37% in the Hela cell. These results indicate that the GMNs were biostable and the HGMNs served as effective drug delivery vehicles.

Analysis of Multi-layered Thin Film Using ATR FT-IR and pyro-GC/MS (ATR FT-IR과 pyro-GC/MS를 이용한 다층박막필름의 분석)

  • Park, Sung Il;Lee, Jung-Hyun;Lee, Myung Cheon
    • Journal of Adhesion and Interface
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    • v.20 no.3
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    • pp.102-109
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    • 2019
  • The material constitution of multi-layered thin film coated on the PET base film was analyzed using ATR FT-IR and pyro GC/MS combination. The cross section of the film was acquired by cracking the film after dipping in liquid nitrogen and was observed using optical microscope. Total thickness of the coated film was $70{\mu}m$ and three layers were observed. Since each layers were too thin to analyze directly except the surface layer, analyzable area of each layers were exposed by using a proper solvent and were investigated using ATR FT-IR and pyro GC/MS. Results shows that three layers were commonly consisted of urethane-acrylate copolymers. Also, inorganic and/or metal inclusions detected by XPS and SEM-EDAX were exhibited by nano size $SiO_2$ particles in layer(1) and aluminum flakes in layer(2).

Preparation of Hydrated Liquid Crystalline Vesicles Containing High Content of Ceramide using a Solubilizer (가용화제를 활용한 세라마이드 고함량의 수화 액정형 베시클 개발)

  • Park, Min Seon;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.541-546
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    • 2021
  • Hydrated liquid crystalline vesicles containing a high content of ceramide were prepared by constituting an optimal composition in which ceramides can be mutually self-associated with phospholipid and cholesterol. From the result of manufacturing various vesicles with different component composition, when the edge activator sodium deoxycholate (SDOC) and the solubilizer PEG-60 hydrogenated castor oil (HCO 60) were mixed to form vesicles, the smallest nano-sized particles were produced and the vesicle dispersion solution was weakly acidic and maintained the most stable state. In addition, it was confirmed through polarized light microscopy and thermal analysis that the addition of SDOC and HCO 60 had an effect on the inhibition of crystallinity of lipid components such as ceramide. The stability of the vesicle dispersion solution was maintained without change in appearance and viscosity even after long-term storage at high temperature for eight weeks.

Development of Stretchable Joint Motion Sensor for Rehabilitation based on Silver Nanoparticle Direct Printing (은 나노입자 프린팅 기반의 재활치료용 신축성 관절센서 개발)

  • Chae, Woen-Sik;Jung, Jae-Hu
    • Korean Journal of Applied Biomechanics
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    • v.31 no.3
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    • pp.183-188
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    • 2021
  • Objective: The purpose of this study was to develop a stretchable joint motion sensor that is based on silver nano-particle. Through this sensor, it can be utilized as an equipment for rehabilitation and analyze joint movement. Method: In this study, precursor solution was created, after that, nozel printer (Musashi, Image master 350PC) was used to print on a circuit board. Sourcemeter (Keithley, Keithley-2450) was used in order to evaluate changes of electric resistance as the sensor stretches. In addition, the sensor was attached on center of a knee joint to 2 male adults, and performed knee flexion-extension in order to evaluate accurate analysis; 3 infrared cameras (100 Hz, Motion Master 100, Visol Inc., Korea) were also used to analyze three dimensional movement. Descriptive statistics were suggested for comparing each accuracy of measurement variables of joint motions with the sensor and 3D motions. Results: The change of electric resistance of the sensor indicated multiple of 30 times from initial value in 50% of elongation and the value of electric resistance were distinctively classified by following 10%, 20%, 30%, 40% of elongation respectively. Through using the sensor and 3D camera to analyze movement variable, it showed a resistance of 99% in a knee joint extension, whereas, it indicated about 80% in flexion phase. Conclusion: In this research, the stretchable joint motion sensor was created based on silver nanoparticle that has high conductivity. If the sensor stretches, the distance between nanoparticles recede which lead gradual disconnection of an electric circuit and to have increment of electric resistance. Through evaluating angle of knee joints with observation of sensor's electric resistance, it showed similar a result and propensity from 3D motion analysis. However, unstable electric resistance of the stretchable sensor was observed when it stretches to maximum length, or went through numerous joint movements. Therefore, the sensor need complement that requires stability when it comes to measuring motions in any condition.

Fabrication of porous titanium oxide-manganese oxide ceramics with enhanced anti-static and mechanical properties (우수한 대전방지 및 기계적 성질을 가지는 다공성 산화티탄-산화망간 세라믹스 제조)

  • Yu, Dongsu;Hwang, Kwang-Taek;Kim, Jong-Young;Jung, Jong-Yeol;Baik, Seung-Woo;Shim, Wooyoung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.6
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    • pp.263-270
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    • 2018
  • Recently, porous ceramic materials with anti-static performance are urgently needed for semiconductor and OLED/LCD display manufacturing industry. In this work, we fabricated porous titanium manganese oxide ceramics having the surface resistivity of $10^8-10^{10}$ ohm and enhanced mechanical strength by partial sintering method using nanosized titanium oxide. By addition of nano-sized titanium oxide in the matrix, neck formation between grains was strengthened, which remarkably increased flexural strength up to 170 MPa (@porosity: 15 %), 110 MPa (@porosity: 31 %), compared to 80 MPa (@porosity: 26 %) for pristine titanium manganese oxide ceramics. We evaluated the performances of our ceramics as air-floating module for OLED flexible display manufacturing devices.

Application of Nanoparticles in Food Preservation and Food Processing

  • Prakash, J.;Vignesh, K.;Anusuya, T.;Kalaivani, T.;Ramachandran, C.;Sudha, Rani R.;Rubab, Momna;Khan, Imran;Elahi, Fazle;Oh, Deog-Hwan;DevanandVenkatasubbu, G.
    • Journal of Food Hygiene and Safety
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    • v.34 no.4
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    • pp.317-324
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    • 2019
  • This study focuses on the role of nanotechnology in the field of food industries. Bioactive components with antimicrobial activity against food pathogens are encapsulated into nanoparticles (NPs) to improve and extend their efficiency in food preservation. However, these NPs should be biocompatible and nontoxic for humans. Advancement in this field has resulted in the development of NPs for food packaging in some industries. The most commonly used group of NPs in the food industry is metal oxide. As metal oxide NPs such as zinc oxide and titanium dioxide exhibit antimicrobial activity in food materials, the NPs can be used for food preservation with enhanced functional properties. The application and effects of nanotechnology in correlation with the nutritional and sensory properties of foods were briefly discussed with a few insights into safety regulations on nano-based food formulation and preservation.

Fabrication of TiO2 Coated Si Nano Particle using Silicon Sawing Sludge (실리콘 절삭 슬러지를 이용한 TiO2 코팅 나노 실리콘 입자의 제조)

  • Seo, Dong Hyeok;Yim, Hyeon Min;Na, Ho Yoon;Kim, Won Jin;Kim, Ryun Na;Kim, Woo-Byoung
    • Journal of Powder Materials
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    • v.28 no.5
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    • pp.423-428
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    • 2021
  • Here, we report the development of a new and low-cost core-shell structure for lithium-ion battery anodes using silicon waste sludge and the Ti-ion complex. X-ray diffraction (XRD) confirmed the raw waste silicon sludge powder to be pure silicon without other metal impurities and the particle size distribution is measured to be from 200 nm to 3 ㎛ by dynamic light scattering (DLS). As a result of pulverization by a planetary mill, the size of the single crystal according to the Scherrer formula is calculated to be 12.1 nm, but the average particle size of the agglomerate is measured to be 123.6 nm. A Si/TiO2 core-shell structure is formed using simple Ti complex ions, and the ratio of TiO2 peaks increased with an increase in the amount of Ti ions. Transmission electron microscopy (TEM) observations revealed that TiO2 coating on Si nanoparticles results in a Si-TiO2 core-shell structure. This result is expected to improve the stability and cycle of lithium-ion batteries as anodes.