• Title/Summary/Keyword: Nano 입자

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Preparation of Poly(vinylpyrrolidone) Coated Iron Oxide Nanoparticles for Contrast Agent (조영제로 활용하기 위한 폴리(비닐피롤리돈)이 코팅된 산화철 나노 입자의 제조)

  • Lee Ha Young;Lim Nak Hyun;Seo Jin A;Khang Gilson;Kim Jungahn;Lee Hai Bang;Cho Sun Hang
    • Polymer(Korea)
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    • v.29 no.3
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    • pp.266-270
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    • 2005
  • Iron oxide nanoparticles were prepared by the thermal decomposition of iron pentacarbonyl (Fe(CO)$_5$) Poly(vinylpyrrolidone) (PVP) was used as surface-modifying agent to control the size of the iron oxide nanoparticles. The crystalline structure of PVP coated iron oxide nanoparticles was determined by XRD. The size of PVP coated iron oxide nanoparticles was determined by TEM and ELS. The particle sizes of PVP coated iron oxide nanoparticles were controlled by adjusting the molar ratio of PVP/Fe (CO)$_5$, solvent and molecular weight of PVP Particle sizes increased with increasing PVP content. Spherical $50\~100$ nm sized iron oxide nanoclusters were produced when dimethylformamide was used as a solvent. And well-defined 10 nm iron oxide nanoparticles were produced in Carbitol. The prepared PVP coated iron oxide nanoparticles exhibited a well-dispersed property in water. The results obtained in this study confirmed the feasibility of the PVP-coated iron oxide nanoparticles as a biomaterial for MRI contrast agent.

Enhanced nucleation density by heat treatment of nanodiamond seed particles (나노다이아몬드 seed 입자의 열처리에 의한 핵형성 밀도 향상)

  • Park, Jong Cheon;Jeong, Ok Geun;Son, Bit Na;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.6
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    • pp.291-295
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    • 2013
  • Surface chemical modification via air and hydrogen heat treatment was found to relieve the aggregation of nanodiamond (ND) seed particles and lead to a significantly enhanced nucleation density for ultrananocrystalline diamond (UNCD) film growth. After heat treatment in air and hydrogen, modification of surface functionalities and increase in the zeta potential were observed. Mean size of the ND aggregates was also dramatically reduced from ${\sim}2{\mu}m$ to ~55 nm. Si surface seeded with ND particles heat-treated at $600^{\circ}C$ in hydrogen produced a much higher nucleation density of ${\sim}2.7{\times}10^{11}cm^{-2}$ compared to untreated ND seeds.

Prediction of the Mechanical Erosion Rate Decrement for Carbon-Composite Nozzle by using the Nano-Size Additive Aluminum Particle (나노 알루미늄 입자 첨가 추진제에 의한 탄소복합재 노즐의 기계적 삭마 감소 특성 예측)

  • Tarey, Prashant;Kim, Jaiho;Levitas, Valeny I.;Ha, Dongsung;Park, Jae Hyun;Yang, Heesung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.6
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    • pp.42-53
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    • 2015
  • In this study, the influence of Al particle size, as an additive for solid propellant, on the mechanical erosion of the carbon-composite nozzle was evaluated. A new model which can predict the size and distribution of the agglomerated reaction product($Al(l)/Al_2O_3(l)$) was established, and the size of agglomerate were calculated according to the various initial size of Al in the solid propellant. With predicted results of the model, subsequently, the characteristics of mechanical erosion on the carbon-composite nozzle was estimated using a commercial CFD software, STAR CCM+. The result shows that the smaller the initial Al particles are, in the solid propellant, the lower is the mechanical erosion rate of the composite nozzle wall, especially for the nano-size Al particle.

Process Development of Self-Assembled Monolayers(SAMs) of Colloidal Particles (콜로이드 입자의 자기 배열성을 이용한 Monolayer 형성에 관한 연구)

  • Ko, Hwa-Young;Lee, Hae-Weon;Kim, Joo-Sun;Moon, Joo-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.981-987
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    • 2002
  • Monodispersed colloidal silica was prepared by Stober process. We have synthesized monodispersed colloidal silica of carious sizes (100 nm, 200 nm, 300 nm) by controlling volume ratios of TEOS(Tetraethylorthosilicate), $NH_4OH$, Ethanol and D. I. water. Shape and monodispersity of the synthesized colloidal particles were observed by Scanning Electron Microscopy(SEM) and laser light scattering particle analyzer. Self-assembled monolayer of monodispersed colloids was achieved by dipping Si substrate into a well-dispersed silica suspension. It was determined that uniformity and spatial extent of the self-assemble monolayer of monodispersed colloids are significantly influenced by the experimental parameters such as concentration, pH and surface tension of the colloidal suspension. We have observed a hexagonally well-ordered packing colloidal monolayer in a relatively large area (1.5 mm ${\times}$ 1.5 mm) as confirmed by SEM.

Preparation of Nickel Nanopowder using the Transferred Arc Plasma for MLCCs (이송식 아크 플라즈마를 이용한 MLCC용 니켈 나노분말의 합성)

  • Jung, Da-Woon;Oh, Seung-Min;Park, Dong-Wha
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.701-706
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    • 2008
  • Nano-sized nickel powders were prepared by evaporating the bulk nickel metarial using transferred arc thermal plasma. Nitrogen gases are easily dissociated to atomic nitrogen in thermal plasma and they are quickly dissolved in molten nickel. Super-saturated atomic nitrogen in molten nickel is recombined to nitrogen gas because of the relatively low temperature of nickel surface. Generally, the recombine reaction of atomic nitrogen is exothermic, so bulk nickel is quickly evaporated to nickel vapor due to the thermal energy of recombine reaction. The particle size of nickel powder was controlled by $N_2$ used as the diluting gas. It was observed that as the diluting gas flow rate was increase, the particle size was decreased and the particle size distribution was narrowed. The average particle size at 250 l/min of the diluting gas was 202 nm analyzed by means of the particle size analyzer (PSA).