• 반도체디스플레이기술학회지
• /
• 제11권1호
• /
• pp.55-59
• /
• 2012

NOx is one of the toxin gases, which is mainly causing the optic-chemical smog phenomena, and decreasing in the function of nose and taste. Especially, NO is easily reacting with $O_3$, and then becoming the $NO_2$. $NO_2$ is mainly causing the acidulation rain. So, we should develop the NOx gas sensing system to detect NOx gas. In this paper, we present the microstructure and the NOx gas detecting properties of the nitrocellulose/MWCNT thin film coated by the air-spray on the glass substrate. The nitrocellulose/MWCNT-based gas sensors have been studied detecting NOx molecules of a ppm-level at the temperature range of $30{\sim}120^{\circ}C$. The resistance of the sensors decreases when the sensors are exposed to NOx gas. As a results, we obtained the nitrocellulose/MWCNT sensors with the sensitivity of 0.6%/sec under the 0.8 ppm of NOx gas concetration. Also, we get the activation energy of 0.202eV from the sensor for the 0.3 ppm of NOx gas concentration.

• 한국전기전자재료학회논문지
• /
• 제26권9호
• /
• pp.707-711
• /
• 2013

Carbon nanotubes(CNT) has strength and chemical stability, greatly conductivity characteristics. In particular, MWCNT (multi-walled carbon nanotubes) show rapidly resistance sensitive for changes in the ambient gas, and therefore they are ideal materials to gas sensor. So, we fabricated NOx gas sensors structured MOS-FET using MWCNT (multi-walled carbon nanotubes) material. We investigate the change resistance of NOx gas sensors based on MOS-FET with ultra lean NOx gas concentrations absorption. And NOx gas sensors show sensitivity on the change of gate-source voltage ($V_{gs}=0[V]$ or $V_{gs}=3.5[V]$). The gas sensors show the increase of sensitivity with increasing the temperature (largest value at $40^{\circ}C$). On the other hand, the sensitivity of sensors decreased with increasing of NOx gas concentration. In addition, We obtained the adsorption energy($U_a$), $U_a$ = 0.06714[eV] at the NOx gas concentration of 8[ppm], $U_a$ = 0.06769[eV] at 16[ppm], $U_a$ = 0.06847[eV] at 24[ppm] and $U_a$ = 0.06842[eV] at 32[ppm], of NOx gas molecules concentration on the MWCNT gas sensors surface with using the Arrhenius plots. As a result, the saturation phenomena is occurred by NOx gas injection of concentration for 32[ppm].

• 한국전기전자재료학회논문지
• /
• 제26권4호
• /
• pp.325-329
• /
• 2013

Carbon nanotubes(CNT) have excellent electrical, chemical stability and mechanical properties. These can be used in a variety of fields. MWCNT are extremely sensitive for minute changes in the ambient gas, namely, their sensing properties varies greatly with the absorption of gas such as NOx and $H_2$. We investigate the electrical properties of CNTs and make a NOx gas sensor based on Multi-walled carbon nanotubes (MWCNT) materials. We obtained the NOx gas sensor of MWCNT based on P-type Si wafer that has the resistivity of $1.667{\times}10^{-1}[{\Omega}{\cdot}cm]$. We knew that the sensitivity of sensor decreased with increasing of NOx gas concentration. And the sensitivity of sensor shows the largest value at $20^{\circ}C$. The sensitivity of sensor decrease with increasing the temperature. Also absorption energy of NOx gas molecule on the MWCNT surface decreases with increasing concentration of NOx gas.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회A
• /
• pp.1829-1832
• /
• 2008

This paper reports a novel gas sensing method by using a thermoelectric device, thermopile in this case, with an embedded tin oxide catalyst. By using a thin catalyst film, the response time and recovery time were remarkably improved. The fabricated gas sensor was characterized through detecting NOx gas with various concentrations.

• 대한기계학회논문집B
• /
• 제26권6호
• /
• pp.833-841
• /
• 2002

The present study examined the possibility of NOx reduction in the high temperature industrial furnaces, duct burner of gas turbine cogeneration and two-stage gas turbine combustor. The experimental study was carried out for the non-premixed flame of second stage combustor with the variations of oxygen concentration in the hot exhaust gas of first stage combustor. It also examined the flammability range, temperature and NOx, $CO_2$, $O_2$formation in the combustor with respect to oxygen concentration in which the fuel(natural gas) is supplying into the hot exhaust gas. The results show that the inner temperature of flame reaches 1,20$0^{\circ}C$ at EGR $O_2$23% and that 15ppm of NOx at EGR $O_2$15.5% increases up to 60ppm at EGR $O_2$23%. It is believed that Fenimore＇s prompt NOx mechanism is more influential on the NOx formation than Zeldovich＇s thermal NOx mechanism does.

• 한국에너지공학회:학술대회논문집
• /
• 한국에너지공학회 1999년도 춘계 학술발표회 논문집
• /
• pp.89-93
• /
• 1999

Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

• 한국연소학회지
• /
• 제9권1호
• /
• pp.11-17
• /
• 2004

The purposes of this study are to analyze nitrogen oxides(NOx) formation mechanism and to reduce abnormal NOx emissions in gas turbines. Industrial gas turbines emissions have potential to negative affect to the atmosphere in many different ways such as photochemical smog, acid rain and global warming. In conventional gas turbine combustors, one of the main pollutants such as nitrogen oxide(NOx) species, are principally formed from combustion process of fuel with oxygen in the primary combustion zone, and their emission levels are highly depend on peak temperatures in the combustor. In order to examine the characteristics and the effect of NOx formation, we used gas turbine of which commercial operating in Korea. From the examination, it has been found that NOx emissions are relatively high at low load(output) and during combustion mode change. Also, the effect of Air/Fuel ratio was considered. As the Air/Fuel ratio was increased in Lean-Lean mode, the NOx emission was decreased. The results of this study indicated that NOx emission levels are highly depend on peak temperature and pressure of combustion process in the combustor.

• 한국전기전자재료학회논문지
• /
• 제27권10호
• /
• pp.668-672
• /
• 2014

Carbon nanotubes(CNT) has chemical stability and great sensitivity characteristics. In particular, the gas sensor required characteristics such as rapid, selectivity and sensitivity sensor. Therefore, CNT are ideal materials to gas sensor. So, we fabricated the NOx gas sensors of MOS-FET type using the MWCNT (multi-walled carbon nanotube). The fabricated sensor was used to detect the NOx gas for the variation of $V_{gs}$(gate-source voltage) and electrode changed electrode spacing=30, 60, 90[${\mu}m$]. The gas sensor absorbed with the NOx gas molecules showed the decrease of resistance, and the sensitivity of sensor was increased by magnification of electrode spacing. Furthermore, when the voltage($V_{gs}$) was applied to the gas sensor, the decrease in resistance was increased. On the other hand, the sensor sensitivity for the injection of NOx gas was the highest value at the electrode spacing $90[{\mu}m]$. We also obtained the adsorption energy($U_a$) using the Arrhenius plots by the reduction of resistance due to the voltage variations. As a result, we obtained that the adsorption energy was increased with the increment of the applied voltages.

• 한국자동차공학회논문집
• /
• 제12권5호
• /
• pp.79-84
• /
• 2004

We evaluated the reduction performance of NOx storage catalyst and TWC for lean-burn natural gas engine by the model gas. The method of unsteady state reaction was used to compare with reduction performances of NOx storage catalyst and TWC. It was found that the effective parameter was rich spike duration, temperature of the model gas. In the presence of $CO_2$ and $H_2O$ in the reaction mixture was decreased the NOx reduction performance.

• 한국자동차공학회논문집
• /
• 제17권3호
• /
• pp.142-148
• /
• 2009

The direct injection(DI) diesel engine has become a prime candidate for future transportation needs because of its high thermal efficiency. However, nitrogen oxides(NOx) increase in the local high temperature regions and particulate matter (PM) increases in the diffusion flame region within diesel combustion. Therefore, the demand for developing a suitable after treatment device has been increased. NOx absorbing catalysts are based on the concept of NOx storage and release making it possible to reduce NOx emission in net oxidizing gas conditions. This De-NOx system, called the LNT(Lean NOx Trap) catalyst, absorbs NOx in lean exhaust gas conditions and release it in rich conditions. This technology can give high NOx conversion efficiency, but the right amount of reducing agent should be supplied into the catalytic converter at the right time. In this research, a performance characteristics of LNT with a hydrogen enriched gas as a reductant was examined and strategies of controlling the injection and rich exhaust gas condition were studied. The NOx reduction efficiency is closely connected to the injection timing and duration of reductant. LNT can reduce NOx efficiently with only 1 % fuel penalty.